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1. 发明专利

JPH10316718A CINNAMIC-GROUP-CONTAINING POLYSILOXANE COPOLYMER AND ITS PRODUCTION 失效
公开(公告)号：JPH10316718A
公开(公告)日：1998-12-02
申请号：JP14112297
申请日：1997-05-16
申请人： MITSUBISHI CHEM CORP , SHISEIDO CO LTD
发明人： UMISHIO KENICHI , FUKUI HIROSHI , ONO KAZUHISA , AOYAMA MASATO , NARITA MACHIKO
IPC分类号： C09D167/00 , C08F22/02 , C08F30/08 , C08F290/12 , C09D183/04
摘要： PROBLEM TO BE SOLVED: To obtain a copolymer which when applied to the surface of a resinous or metallic article, can impart thereto staining resistance, water resistance, oil resistance and ultraviolet absorptivity by reacting a hydroxyl- or amino- containing polysiloxane copolymer with cinnamic acid or its derivative. SOLUTION: The copolymer is obtained by copolymerizing a polysiloxane- containing vinyl monomer with a hydroxy or amino (meth)acrylate. The final copolymer is a cinnamic-group-containing polysiloxane copolymer comprising repeating units of formula I and repeating units of formula II in a weight ratio of 5/95 to 95/5 and having a number-average molecular weight of 2,000-2,000,000. In the formulas, R and R are each H or methyl, R and R are each a 1-3 C alkyl or phenyl; n is 6-100; X is phenylene, a carbonyloxyalkylene or a carbonyloxyalkyleneoxyalkylene; Y is a carbonyloxyalkyleneoxy or the like; and Ar is phenol or the like.

2. 发明专利

JPH10316726A POLYSILOXANE COPOLYMER HAVING BENZOPHENONE GROUP OR BENZOTRIAZOLE GROUP 失效
公开(公告)号：JPH10316726A
公开(公告)日：1998-12-02
申请号：JP14112197
申请日：1997-05-16
申请人： MITSUBISHI CHEM CORP , SHISEIDO CO LTD
发明人： UMISHIO KENICHI , FUKUI HIROSHI , ONO KAZUHISA , AOYAMA MASATO , TANAKA TOSHIYUKI , YAMAOKA HIROAKI
IPC分类号： C08F290/06 , C08F226/06 , C09D155/00
摘要： PROBLEM TO BE SOLVED: To provide a novel stainproof ultraviolet-absorbing resin. SOLUTION: This resin is obtained by copolymerizing a polysilioxane- containing vinuyl monomer (A) of formula I:CH2 =R C-X(Si(R )2 O)n -Si(R )3 with an ultraviolet-absorbing-group-containing vinyl monomer (B) of formula II:CH2 = XR -Y [wherein R is hydrogen or methyl; R and R are each a 1-3C alkyl or phenyl; n is an integer of 6-100; X is phenyllene, a carbonyloxyalkylene or a carbonyloxyalkyleneoxyalkylene; and Y is a substituent having a characteristic grouyp being either a benzophenone group or a benzotriazle group] in an A/B weight ratio in the range of 10/90 to 90/10 and has a number-average molecular weight of 2,000-2,000,000.

3. 发明专利

JPH111420A COSMETIC 失效
公开(公告)号：JPH111420A
公开(公告)日：1999-01-06
申请号：JP16663697
申请日：1997-06-09
申请人： SHISEIDO CO LTD , MITSUBISHI CHEM CORP
发明人： UMISHIO KENICHI , FUKUI HIROSHI , ONO KAZUHISA , AOYAMA MASATO , TANAKA TOSHIYUKI , YAMAOKA HIROAKI
IPC分类号： A61K8/72 , A61K8/00 , A61K8/89 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q1/12 , A61Q3/02 , A61Q5/00 , A61Q17/04 , C08L83/06 , C08L83/08 , A61K7/42 , A61K7/00 , A61K7/027 , A61K7/035 , A61K7/043 , A61K7/06
摘要： PROBLEM TO BE SOLVED: To obtain a cosmetic excellent in durability of makeup, capable of continuing inhibitory effects on ultraviolet rays, having improved touch. SOLUTION: This cosmetic comprises a polysiloxane-based copolymer containing a benzophenone group or a benzotriazole group having 2,000-2,000,000 number-average molecular weight obtained by copolymerizing a polysiloxane- containing vinyl-based monomer (A) of formula I: CH2 =CR -X-(Si(R )2 O)n -Si(R )2 (in the formula, R is a hydrogen atom or a methyl group; R and R are each a 1-3C alkyl or a phenyl group and may be the same or different; (n) is an integer of 6-100; X is a phenylene group of a carbonyl oxyalkylene group of the formula COOCm H2m ((m) is an integer of 1-5), etc.) with an ultraviolet ray absorbing group-containing vinyl-based monomer (B) of formula II: CH2 CR -Y (in the formula, R is a hydrogen atom or a methyl group; Y is a benzophenone group or a benzotriazole group) in the ratio of the components A to B in the range of 10:90 to 90:10.

4. 发明专利

JPH111421A COSMETIC 失效
公开(公告)号：JPH111421A
公开(公告)日：1999-01-06
申请号：JP16663797
申请日：1997-06-09
申请人： SHISEIDO CO LTD , MITSUBISHI CHEM CORP
发明人： UMISHIO KENICHI , FUKUI HIROSHI , ONO KAZUHISA , AOYAMA MASATO , NARITA MACHIKO
IPC分类号： A61K8/72 , A61K8/00 , A61K8/89 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q1/12 , A61Q3/02 , A61Q17/04 , A61Q19/00 , C08L83/07 , C08L83/08 , A61K7/42 , A61K7/00 , A61K7/025 , A61K7/035 , A61K7/043 , A61K7/48
摘要： PROBLEM TO BE SOLVED: To obtain a cosmetic excellent in durability of makeup, capable of continuing inhibitory effects on ultraviolet rays, having improved touch, by including a cinnamic group-containing polysiloxane-based copolymer of a specific structure. SOLUTION: This cosmetic comprises generally 0.1-80 wt.% based on the total of the cosmetic of a cinnamic group-containing polysiloxane-based copolymer containing a repeating unit of formula I (R is H or methyl; R and R are each a 1-3C alkyl or a phenyl; (n) is 6-100; X is phenylene, etc.) and a repeating unit of formula II [R is H or methyl; Y is a carbonyloxyalkylene group of the COOCm H2m O ((m) is 1-5) in the weight ratio of the part of formula I to the part of formula II of 5:95 to 95:5 and having 2,000-2,000,000 number- average molecular weight.

5. 发明专利

JP2013168805A Invisible information embedding apparatus, invisible information embedding method, and invisible information embedding program 有权
标题翻译：无形信息嵌入式设备，可信信息嵌入方法和可信信息嵌入式程序
公开(公告)号：JP2013168805A
公开(公告)日：2013-08-29
申请号：JP2012030971
申请日：2012-02-15
申请人： Shiseido Co Ltd , 株式会社資生堂 , Ritsumeikan , 学校法人立命館
发明人： SAKUMA KENICHI , HANYU NAOTO , DOSEKI TAKAKUNI , KITAMURA KAZUMA , FUKUI HIROSHI
IPC分类号： H04N1/387 , G06T1/00
摘要： PROBLEM TO BE SOLVED: To embed high-accuracy invisible information with degraded visibility into an image.SOLUTION: An invisible information embedding apparatus which embeds invisible information at a predetermined position of an acquired image comprises: image analysis means which acquires object information and positional information included in the image; embedding-target image determination means which determines whether the image is an image to be embedded, from the object information obtained by the image analysis means; invisible information setting means which sets the contour shape of the invisible information to be synthesized into the image; invisible information generation means which generates invisible information using the contour shape associated with the setting information obtained by the invisible information setting means; and image synthesis means which, on the basis of a determination result obtained by the embedding-target image determination means, embeds at the predetermined position of the image the invisible information obtained by the invisible information generation means, thereby synthesizing the image.
摘要翻译：要解决的问题：将具有劣化可见性的高精度隐形信息嵌入到图像中。解决方案：将不可见信息嵌入所获取图像的预定位置的不可见信息嵌入装置包括：图像分析装置，其获取对象信息和位置信息包含在图像中; 嵌入目标图像确定装置，根据由图像分析装置获得的对象信息确定图像是否是要被嵌入的图像; 隐形信息设定单元，将要合成的不可见信息的轮廓形状设定为图像; 不可见信息生成单元，其使用与由所述不可见信息设定单元获取的设定信息相关联的轮廓形状生成不可见信息; 以及图像合成装置，其基于由所述嵌入目标图像确定装置获得的确定结果嵌入所述图像的预定位置，由所述不可见信息生成装置获得的所述不可见信息，从而合成所述图像。

6. 发明专利

JP2002302412A COLOR-DEVELOPABLE LIQUID COMPOSITION 失效
公开(公告)号：JP2002302412A
公开(公告)日：2002-10-18
申请号：JP2001102732
申请日：2001-03-30
申请人： SHISEIDO CO LTD
发明人： FUKUI HIROSHI , MORI YUICHIRO , YOSHIMURA MASANORI , MATSUSHITA YASUSHI , SAKIGUCHI TAKAYUKI
IPC分类号： A61K8/19 , A61K8/00 , A61K8/30 , A61K8/34 , A61K8/55 , A61K8/58 , A61K8/89 , A61K8/891 , A61Q13/00 , C08L83/04 , A61K7/00 , A61K7/46
摘要： PROBLEM TO BE SOLVED: To obtain a composition capable of color development without the need of using any coloring matter. SOLUTION: This liquid composition consists of a liquid with separated two phases, wherein the refractive indexes of the respective two liquid phases coincide with each other within a wavelength range of 400-800 nm, and it is characteristic that the above two phases are dispersedly mixed together to effect color development.

7. 发明专利

JP2000038308A ROOTING PROMOTER 失效
公开(公告)号：JP2000038308A
公开(公告)日：2000-02-08
申请号：JP22364598
申请日：1998-07-23
申请人： SHISEIDO CO LTD
发明人： YOKOYAMA MINEYUKI , FUKUI HIROSHI
IPC分类号： A01N43/40 , A01N59/00 , A01N63/00 , A01N63/02
摘要： PROBLEM TO BE SOLVED: To obtain a rooting promoter having strong rooting promotion activity. SOLUTION: This rooting promoter comprises an active oxygen generating component and/or a calcium ionophore as an active ingredient. In this case the active oxygen generating component is hydrogen peroxide and/or methyl viologen and the calcium ionophore is A23187.

8. 发明专利

JP2000016919A COMPOSITION FOR EXTERNAL USE 失效
公开(公告)号：JP2000016919A
公开(公告)日：2000-01-18
申请号：JP12315199
申请日：1999-04-28
申请人： SHISEIDO CO LTD
发明人： KUROSAWA MARI , FUKUI HIROSHI
IPC分类号： A61K8/00 , A61K8/25 , A61K8/34 , A61K8/73 , A61K8/89 , A61K8/891 , A61K8/92 , A61Q1/00 , A61Q1/02 , C08B1/00 , C08B31/00 , C08B37/00 , C08B37/02 , C08B37/04 , C08B37/08 , C08B37/12 , C08K3/36 , C08L1/08 , C08L3/04 , C08L5/00 , C08L83/04 , A61K7/02
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition capable of smoothing the skin through covering unevennesses developed on the skin due to various causes and thereby capable of remedying the skin as if the unevennesses were absent visually by including a silicone-modified polysaccharide compound, a low- viscosity silicone oil and/or a powder ingredient. SOLUTION: This composition for external use is obtained by including (A) a silicone-modified polysaccharide compound (e.g. silicone-modified pullulan), (B) a low-viscosity silicone oil and/or (C) a powder ingredient pref. 1.3-1.5 in refractive index such as silicon dioxide powder, silicone resin powder, silicone rubber powder or silicone resin-coated rubber powder; wherein it is preferable that the amount of the ingredients A and B to be formulated is >=70.0 wt.% based on the weight corresponding to the value obtained by deducting the weight of the ingredient C (when volatile ingredient(s) is formulated in this composition, the weight of the ingredient C plus the volatile ingredient(s)) from the weight of the whole composition, and the refractive index of >=90 wt.% of the ingredient C to be formulated is 1.3-1.5.

9. 发明专利

JPH1160439A COSMETIC 失效
公开(公告)号：JPH1160439A
公开(公告)日：1999-03-02
申请号：JP22758697
申请日：1997-08-09
申请人： SHISEIDO CO LTD
发明人： NISHIHAMA SHUJI , SUHARA TSUNEO , FUKUI HIROSHI
IPC分类号： A61K8/55 , A61K8/00 , A61K8/58 , A61K8/89 , A61K8/891 , A61K8/92 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q17/04 , C08L83/05 , A61K7/00 , A61K7/027 , A61K7/032 , A61K7/035 , A61K7/42
摘要： PROBLEM TO BE SOLVED: To prepare a cosmetic excellent in make-up preservation and the prevention effect of secondary adhesion, and excellent use feeling such as hardly causing creaky feeling, good in spreading, hardly causing sticky feeling and having smooth feeling by including a specific treated powder and oil. SOLUTION: This cosmetic contains (A) a treated powder obtained by coating (i) the surface of a powder with (ii) a silicone compound having an Si-H group, and further adding (iii) a compound capable of reacting with Si-H group and having >=100 μmol/g density to the unreacted parts of the Si-H group of the component (ii), (B) an oil component, and optionally (C) water, a surfactant, a film-forming agent or the like. A compound containing one or more parts of the Si-H group, of formula I [R to R are each H or a 1-10C hydrocarbon (substituted with a halogen), with the proviso that R to R are not simultaneously H; (a) is >=1; (b) is 0 or >=1; (c) is 0 or 2, with the proviso that 3 to R are each H, a halogen, OH, amino or the like) is preferably used as the component (iii).

10. 发明专利

JPH111411A SILICA/ZINC OXIDE COMPLEX, ITS PRODUCTION AND COSMETIC FORMULATED WITH THE SAME 失效
公开(公告)号：JPH111411A
公开(公告)日：1999-01-06
申请号：JP16960897
申请日：1997-06-10
申请人： SHISEIDO CO LTD
发明人： NISHIHAMA SHUJI , FUKUI HIROSHI
IPC分类号： A61K8/19 , A61K8/00 , A61K8/18 , A61K8/25 , A61K8/27 , A61Q1/00 , A61Q1/02 , A61Q1/12 , A61Q17/04 , A61Q19/00 , C09C3/06 , A61K7/00 , A61K7/02 , A61K7/035 , A61K7/42 , A61K7/48
摘要： PROBLEM TO BE SOLVED: To obtain the subject complex useful for cosmetics, having sebum solidifying and absorbing effects, transparency and soft focusing properties, by sticking fine zinc oxide particles to the surface of silica. SOLUTION: A silica sol dispersion is mixed with a zinc salt (preferably zinc chloride) to give a gel composition, which is formulated with a weakly acidic strong base (preferably sodium carbonate) to give a silica/weakly acidic zinc salt complex. The complex is dehydrated by heating or mixed with a strong base and adjusted to pH >=8 and the prepared gel composition is dried so that fine zinc oxide particles are stuck to the surface of silica gel to give the objective complex. A complex in which fine zinc oxide particles are observed in a dotted state on an electron microscope photograph in an SEM image or 80 Kα observation image is preferable as the complex. The amount of the complex added to a cosmetic is generally 0.1-98 wt.%, preferably 0.5-80 wt.%.

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