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1. 发明专利

JP2005120204A Treatment apparatus for waste plastic and treatment method using the apparatus 审中-公开
标题翻译：使用设备的废塑料和处理方法的处理设备
公开(公告)号：JP2005120204A
公开(公告)日：2005-05-12
申请号：JP2003356017
申请日：2003-10-16
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： TERAMAE NAOKI , DEN TAKEYOSHI , YAMAGATA KAZUNORI , NISHIMURA KENJI , MORI RYOHEI
IPC分类号： C08J11/18 , C10G1/10
CPC分类号： Y02W30/706
摘要： PROBLEM TO BE SOLVED: To carry out stabler operation without installing transportation means such as a valve, a pump, etc., between a melting and dechlorinating process and a reforming adjustment process. SOLUTION: The treatment apparatus for a waste plastic is equipped with a melting decomposition part 11 for retaining a waste plastic containing a chlorine component in heated oil, melting the waste plastic and removing the chlorine component contained in the waste plastic, a reforming adjustment part 12 for retaining the molten waste plastic in heated oil, thermally decomposing the molten waste plastic and reforming the waste plastic into heavy oil, a supply part 13 for supplying a waste plastic into the inside of a melting decomposition part, a discharge part 14 for discharging the heavy oil from the reforming adjustment part, a first heating means 16 for heating and keeping the oil stored in the melting decomposition part at temperature T 1 , a second heating means 17 for heating and keeping the oil stored in the reforming adjustment part at temperature T 2 equal to the temperature T 1 or higher than the temperature T 1 , a first stirring blade 18 for stirring the oil in the melting decomposition part and a second stirring blade 19 for stirring the oil in the reforming adjustment part so as not to cause a vertical convection. The lower part of the melting decomposition part is made to communicate with the lower part of the reforming adjustment part. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：在熔融和脱氯过程与重整调整过程之间不安装诸如阀门，泵等的输送装置，进行更稳定的操作。解决方案：废塑料处理装置配备有熔化分解部分11，用于将含有氯组分的废塑料保存在加热的油中，熔化废塑料并除去废塑料中包含的氯组分，重整调节部12，用于将熔融废塑料保持在加热的油中，热分解熔融废塑料并将废塑料重整成重油;供给部13，用于将废塑料供应到熔化分解部的内部;排出部14 用于从重整调节部排出重油的第一加热装置16，用于加热和保存熔化分解部分中存储的温度T 1 的第一加热装置16，用于加热和保持存储在重整调节部分中的温度T 2 等于温度T 1 或高于温度T 1 的油，第一搅拌叶片 18岁将熔化分解部分中的油转化为第二搅拌叶片19，用于搅拌重整调节部分中的油以不引起垂直对流。使熔融分解部的下部与重整调整部的下部连通。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2004089904A Organic acid isolation method 审中-公开
公开(公告)号：JP2004089904A
公开(公告)日：2004-03-25
申请号：JP2002256546
申请日：2002-09-02
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： HATAKEYAMA KO , SAITO NARIMASA , TERAMAE NAOKI , YAMAGATA KAZUNORI , YAMANO YUURIKEI , KIKUCHI TOSHIAKI
IPC分类号： B01D11/00 , B01J3/00 , B01J20/26 , B01J20/34 , B01J49/00 , C07C51/47 , C07C53/02 , C07C53/08
摘要： PROBLEM TO BE SOLVED: To easily isolate and recover an organic acid from an organic acid-adsorbed substance. SOLUTION: Carbon dioxide at a temperature of 20°C or higher and a pressure of 1 MPa or higher is brought into contact with an organic acid-adsorbed substance (an anion exchange resin) containing water content to shift the organic acid to the carbon dioxide and isolate the organic acid from the substance. COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2004083795A Method for converting waste plastic into fuel 审中-公开
公开(公告)号：JP2004083795A
公开(公告)日：2004-03-18
申请号：JP2002248976
申请日：2002-08-28
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , TERAMAE NAOKI , NISHIMURA KENJI , MORI RYOHEI , MORIKAWA KOSHI
IPC分类号： F23G7/12 , C08J11/12 , C10G1/10
CPC分类号： Y02W30/703
摘要： PROBLEM TO BE SOLVED: To provide a method for converting waste plastics into a fuel by thermal cracking, effective for preventing the clogging of a treating apparatus by the deposition of a crystalline organic material in a volatile component into gas, in a fuel conversion apparatus and enabling stable continuous operation. SOLUTION: Waste plastics are converted into a fuel by thermal cracking. The volatile component containing the crystalline organic material and generated by the thermal cracking is supplied to a 1st jet scrubber, sucked and mixed into a circulating oil at a temperature lower than the sublimation point of the crystalline organic material to cause the abrupt cooling and the deposition of the crystalline organic material and, at the same time, to condense an organic component (component A) having a boiling point higher than the circulating oil temperature to form the fuel, and the product is separated into the crystalline organic material, the liquefied organic component A and gas. COPYRIGHT: (C)2004,JPO

4. 发明专利

JP2005144768A Method and apparatus for treating waste plastic 审中-公开
标题翻译：用于处理废塑料的方法和装置
公开(公告)号：JP2005144768A
公开(公告)日：2005-06-09
申请号：JP2003383226
申请日：2003-11-13
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： TERAMAE NAOKI , DEN TAKEYOSHI , HATAKEYAMA KO , NISHIMURA KENJI , ONOE TAKESHI , MORI RYOHEI
IPC分类号： B03B5/28 , B03B7/00 , B29B17/00 , B29B17/04 , B29K23/00 , B29K27/00 , B29K67/00 , C08J11/12 , C10G1/10
CPC分类号： Y02W30/62 , Y02W30/625 , Y02W30/703
摘要： PROBLEM TO BE SOLVED: To reduce the treatment cost due to the material recycling of a waste plastic and the chemical recycling of a fractionated residual component.
SOLUTION: This waste plastic treatment method includes a process for extracting a part of a hydrocarbon polymer from the waste plastic, a desalting/liquefying process for immersing the waste plastic in an organic medium not only to perform desalting and the liquefaction of an ester polymer and the hydrocarbon polymer but also to float desalting residue and the non-liquefied waste plastic in the organic medium as the desalted waste plastic containing the residual component of the liquefied hydrocarbon polymer and sedimenting the liquefied ester polymer, a process for taking the desalted waste plastic out of an oil bath tank 12 to pyrolyze the same to form the oil vapor of the desalted waste plastic and the volatile component of the organic medium and a process for lowering the temperature of the oil vapor and that of the organic medium to separate the liquid organic medium and the oil vapor. A combustible gas can be also obtained by gasifying the liquid oil obtained by cooling the oil vapor or the liquefied oil of the ester polymer.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：减少由于废塑料的材料回收和分馏残留成分的化学循环造成的处理成本。解决方案：该废塑料处理方法包括从废塑料中提取一部分烃聚合物的方法，用于将废塑料浸入有机介质中的脱盐/液化方法，不仅可进行脱盐和液化酯聚合物和烃聚合物，还可以将脱盐残渣和非液化的废塑料在有机介质中作为含有液化烃聚合物的残留组分并沉淀液化酯聚合物的脱盐废塑料，将脱盐的方法将废塑料从油浴罐12中分解出来，以便将其脱盐以形成脱盐废塑料的油蒸气和有机介质的挥发性组分，以及降低油蒸气和有机介质的温度以分离的方法液体有机介质和油蒸气。通过将通过冷却油性蒸气或酯聚合物的液化油获得的液体油气化也可以获得可燃气体。版权所有（C）2005，JPO＆NCIPI

5. 发明专利

JP2005133038A Method and apparatus for desalination pyrolysis of waste plastics with supercrytical fluid 审中-公开
标题翻译：含超临界流体的废塑料脱盐热解方法与装置
公开(公告)号：JP2005133038A
公开(公告)日：2005-05-26
申请号：JP2003373379
申请日：2003-10-31
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , YAMANO YUURIKEI , SAITO NARIMASA , TERAMAE NAOKI , NISHIMURA KENJI
IPC分类号： C08J11/16 , B01J3/00 , B01J3/02 , C05C3/00 , C08J11/20 , C08J11/24 , C08J11/28 , C10L5/48
CPC分类号： Y02E50/30 , Y02P20/544 , Y02W30/705 , Y02W30/706
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for desalination pyrolysis that have excellent desalination effect and excellent pyrolytic effect of waste plastics. SOLUTION: In the processing method where resin-containing waste is pyrolyzed and the vaporized chlorine is separated and the pyrolitic product is recovered, fluids other than water are brought into contact with the resin-including waste in the supercritical state under high pressure, and the resin-including waste is pyrolyzed. In a preferred embodiment, supercrytical fluids other than water are used as a heat medium and brought into contact with the resin-including waste under high pressure and pyrolyze the resin-including waste. Then, the pyrolitic products are cooled down, the pressure is decreased and the vaporized chlorine is separated and recycled as a fertilizer. In the meantime, the extracted products and the desalination residue in the pyrolysis tank are recovered as a fuel. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供脱盐热解方法和设备，其具有优异的脱盐效果和优异的废塑料热解效果。解决方案：在含有树脂的废物被热分解并蒸发的氯分离并回收热解产物的处理方法中，除了水之外的其他流体在高压下在超临界状态下与含树脂的废物接触，含有树脂的废物被热解。在优选的实施方式中，使用除水以外的超强流体作为热介质，并在高压下与包含树脂的废物接触并使包含树脂的废物热解。然后，将热解产物冷却，降低压力，蒸发的氯被分离并作为肥料再循环。同时，将热解槽中的提取物和脱盐残渣作为燃料回收。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2005132930A Method and apparatus for producing powdery refuse derived fuel 审中-公开
标题翻译：生产粉尘排放燃料的方法和装置
公开(公告)号：JP2005132930A
公开(公告)日：2005-05-26
申请号：JP2003369592
申请日：2003-10-29
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , TERAMAE NAOKI , YAMAGATA KAZUNORI , HATAKEYAMA KO , NISHIMURA KENJI , MORI RYOHEI
IPC分类号： B09B3/00 , C08J11/12 , C10L5/48
CPC分类号： Y02E50/30 , Y02W30/703
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for easily producing a refuse derived fuel having a low chlorine content and being as fine as about several tens μm. SOLUTION: The method and the apparatus for producing the powder refuse derived fuel comprise a heat decomposition tank for resin-containing wastes, a decomposition oil tank that holds a decomposed oil discharged from the heat decomposition tank, an atomizing means that atomizes the decomposed oil fed from the decomposition tank with an inert gas, a means that feeds the inert gas into the atomizing means, a water tank provided with the atomizing means, and a separation tank connected with the water tank and are characterized in that the decomposed oil formed by the heat decomposition of the resin wastes is led to the atomizing means and is atomized toward the cistern to be cooled by contact with the inert gas or cooling water, and the cooling water is led to the separation tank to separate and recover a solid powder therefrom. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种容易地生产具有低氯含量且细至约几十μm的垃圾衍生燃料的方法和设备。解决方案：用于生产粉末垃圾衍生燃料的方法和设备包括：含树脂废物的热分解罐，保存从热分解罐排出的分解油的分解油罐;雾化装置，由惰性气体从分解罐供给的分解油，将惰性气体进料到雾化装置中的装置，设有雾化装置的水箱和与水箱连接的分离罐，其特征在于分解的油通过树脂废物的热分解形成的雾化装置被雾化并通过与惰性气体或冷却水接触而被冷却，并将冷却水分离并回收固体粉末。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2005162881A Method for treating waste plastic and plant therefor 审中-公开
标题翻译：处理废塑料及其植物的方法
公开(公告)号：JP2005162881A
公开(公告)日：2005-06-23
申请号：JP2003403952
申请日：2003-12-03
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , TERAMAE NAOKI , YAMAGATA KAZUNORI , HATAKEYAMA KO , NISHIMURA KENJI , ONOE TAKESHI
IPC分类号： C08J11/12 , C10G1/10
CPC分类号： Y02W30/703
摘要： PROBLEM TO BE SOLVED: To provide a method for effectively treating waste plastics without producing chlorine or the like. SOLUTION: The method for treating waste plastics comprises the step of charging the waste plastics 11 into a cylindrical oven body 12 packed with granular or lumpy CaCO 3 13, the step of pyrolyzing the waste plastics at 320-660°C in the oven body to produce oil vapor and concurrently adsorbing an acid gas produced during the pyrolysis onto the surface of the CaCO 3 13, and the step of extracting the oil vapor from the oven body and cooling the oil vapor to room temperature to obtain a liquid oil, and preferably furthermore, the step of dechlorinating chlorine-based polymers in the waste plastics. In this method, it is more preferable that the oven body is packed with metallic or ceramic balls 23 together with the CaCO 3 13. It is preferable that the treatment plant has the following construction: Partition plates 22 for hindering the movement of the CaCO 3 in the oven body are set in the oven body and there are provided a plurality of scraping plates 24 for scraping up the balls together with the CaCO 3 by turning them on the circumferential wall inside the oven body. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种有效处理废塑料而不产生氯等的方法。解决方案：处理废塑料的方法包括将废塑料11装入装有颗粒状或块状的CaCO 3 SB 13的圆筒形炉体12中，将废塑料热解的步骤 320-660℃，以产生油蒸气，同时将热解过程中产生的酸性气体吸附到CaCO 3 SB 13的表面上，以及从烘箱中提取油蒸气的步骤将油蒸气冷却至室温，得到液体油，此外，优选在废塑料中脱氯氯系聚合物的工序。在该方法中，更优选地，炉体与CaCO 3 SB 13一起被填充有金属或陶瓷球23。优选的是，处理装置具有以下结构：用于阻止炉体中CaCO 3 SB 3的运动的隔板22设置在炉体中，并且设置有多个刮板24 通过将它们转动在炉体内的周壁上，将其与CaCO 3 一起刮除。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2005120205A Method and apparatus for heat-reaction of waste plastic 审中-公开
标题翻译：废塑料加热反应的方法与装置
公开(公告)号：JP2005120205A
公开(公告)日：2005-05-12
申请号：JP2003356018
申请日：2003-10-16
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , TERAMAE NAOKI , HATAKEYAMA KO , NISHIMURA KENJI , MORI RYOHEI
IPC分类号： C08J11/10 , C10G1/10
CPC分类号： Y02W30/702
摘要： PROBLEM TO BE SOLVED: To provide a method and apparatus for heat-reaction of waste plastics which is capable of perfectly eliminating the blockage in a heat exchanger or the like on an external circular heating, of excluding an agitator in an oil bath which has been installed so far, and of reducing the volume of an oil bath. SOLUTION: The method for heat-reaction of waste plastics comprises a process of staying a waste plastics involving a chlorine component-containing plastics in the oil in an oil bath kept warm at a temperature T 1 of 320-400°C and of melting the waste plastics and removing a chlorine component in the waste plastics and a process, the external circular heating, of discharging the molten waste plastics from the oil bath and of heating still more at the outside of the oil bath the molten waste plastics up to a temperature of T 2 higher by 1-30°C than the temperature T 1 and of returning to the inside of the oil bath the molten waste plastics heated at the outside of the oil bath, being improved in and characterized by pulverizing the solid matter contained in the molten waste plastics at the external circular heating process. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种废塑料的热反应方法和装置，其能够在外部循环加热中完全消除热交换器等中的堵塞，排除油浴中的搅拌器到目前为止已经安装，并且减少了油浴的体积。解决方案：废塑料的热反应方法包括将含有氯成分的塑料的废塑料在油中保持在温度T 1℃保温的油浴中的方法， 320-400℃，并且将废塑料熔化并除去废塑料中的氯组分，以及外部循环加热，将来自油浴的熔融废塑料排出并在将熔融废塑料润湿至T 2 的温度比温度T 1 高1-30℃，并返回到油浴的内部在油浴外加热的熔融废塑料，在外部圆形加热过程中被改进并表征为粉碎熔融废塑料中所含的固体物质。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005105223A Apparatus for treating waste plastic 审中-公开
标题翻译：用于处理废塑料的设备
公开(公告)号：JP2005105223A
公开(公告)日：2005-04-21
申请号：JP2003343943
申请日：2003-10-02
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： TERAMAE NAOKI , DEN TAKEYOSHI , HATAKEYAMA KO , NISHIMURA KENJI , MORI RYOHEI , MURAYAMA SATOSHI
IPC分类号： C08J11/20 , C10G1/10
CPC分类号： Y02W30/706
摘要： PROBLEM TO BE SOLVED: To provide an apparatus for treating waste plastics in which production of crystalline organic materials such as terephthalic acid or benzoic acid due to excessive decomposition is prevented, resulting in prevention of choking and corrosion of the apparatus, easy temperature control and reduction of treatment cost. SOLUTION: The treatment apparatus comprises an oil-bath 13 which stores waste plastics 11 containing a chlorine-based polymer, an ester-based polymer and a hydrocarbon-based polymer and an oil maintained at 280-320°C, and a mixing impeller 14 provided in the oil-bath which agitates the oil in the oil-bath so that vertical convection current may not be produced. A removing port 13a is provided in the upper part of the oil-bath, from which are removed desalinization residues 26 that surface in the oil, waste plastics 27 that are not liquified, and a liquified oil 18 of the hydrocarbon-based polymer. An oil outlet 13b is provided in the lower part of the oil-bath, from which is discharged liquified oil 17 of the ester-based polymer that sediments in the oil. The desalinization residues and the like are thermally decomposed in the furnace body 33 of a heating furnace at 400-550°C to produce oil steam. A condensation tank 16 which surrounds the oil-bath and stores oil 38 reduces the temperature of the oil steam to 300-400°C, and maintains the oil in the oil-bath at 280-320°C. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种处理废塑料的装置，其中防止由于过度分解而生产结晶有机材料如对苯二甲酸或苯甲酸，从而防止装置的阻塞和腐蚀，容易的温度控制和减少治疗费用。解决方案：处理装置包括储存含有氯基聚合物，酯基聚合物和烃基聚合物的废塑料11和保持在280-320℃的油的油浴13，设置在油浴中的混合叶轮14，其搅动油浴中的油，使得不会产生垂直对流。在油浴的上部设置有去除口13a，从油面上除去在油中表面的脱盐残渣26，未液化的废塑料27和烃基聚合物的液化油18。出油口13b设置在油浴的下部，从油中排出沉淀在油中的酯基聚合物的液化油17。脱盐残渣等在加热炉的炉体33中在400-550℃下热分解，生成油蒸气。包围油浴并储存油38的冷凝罐16将油蒸汽的温度降低到300-400℃，并将油浴中的油保持在280-320℃。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2005104095A Method of and device for treating waste plastic 审中-公开
标题翻译：用于处理废塑料的方法和装置
公开(公告)号：JP2005104095A
公开(公告)日：2005-04-21
申请号：JP2003343942
申请日：2003-10-02
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： TERAMAE NAOKI , DEN TAKEYOSHI , YAMAGATA KAZUNORI , NISHIMURA KENJI , MORI RYOHEI , MURAYAMA SATOSHI
IPC分类号： B01D5/00 , B29B17/00 , C08J11/12 , C10G1/10
CPC分类号： Y02A20/128 , Y02W30/62 , Y02W30/703
摘要： PROBLEM TO BE SOLVED: To prevent the clogging and corrosion of a waste plastic-treating device while facilitating a temperature control and reducing a treatment expense by liquefying and extracting the ester-based polymers in a relatively low temperature, low viscosity oil bath to prevent the generation of crystalline organic materials such as terephthalic acid or benzoic acid by excess decomposition. SOLUTION: The oil temperature in an oil bath 32 is kept within the range of 280-320°C by a heating means 33, and the agitating blades 34 are installed in the oil bath 32 to agitate the oil so as not to vertically convect. The oil bath has a means 96 for suppressing the elevation of a settled liquefied oil 94 in its lower part, an outlet 32a for taking out a floating residue 43, non-liquefied waste plastics 44 and a liquefying oil 46 in its upper part, and an oil discharge opening 32b in its lower part. Further, a specific gravity sensor 86 for sensing the specific gravity of the oil in the bath is installed at a prescribed distance above the inside bottom face of the bath, and based on the detection output of the sensor, a controller 92 controls the opening/closing of the oil discharge opening 32b. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了防止废塑料处理装置的堵塞和腐蚀，同时促进温度控制并通过在相对低温，低粘度的油浴中液化和萃取酯基聚合物来降低处理费用以防止通过过量分解产生结晶有机材料如对苯二甲酸或苯甲酸。解决方案：通过加热装置33将油浴32中的油温保持在280-320℃的范围内，并且将搅拌叶片34安装在油浴32中以搅拌油以不垂直对流油浴具有用于抑制其下部的沉降液化油94的升高的装置96，用于在其上部取出漂浮残渣43，非液化废塑料44和液化油46的出口32a，以及在其下部具有排油口32b。此外，用于感测浴中的油的比重的比重传感器86安装在浴槽内底面上规定的距离处，并且基于传感器的检测输出，控制器92控制开/ 关闭排油口32b。版权所有（C）2005，JPO＆NCIPI

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