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1. 发明专利

JP2005238139A Supporting method of metal oxide or metal on porous member 审中-公开
标题翻译：金属氧化物或金属在多孔成员上的支持方法
公开(公告)号：JP2005238139A
公开(公告)日：2005-09-08
申请号：JP2004052775
申请日：2004-02-27
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： HATAKEYAMA KO , YAMANO YUURIKEI , NISHIMURA KENJI , DEN TAKEYOSHI , OTA KAZUAKI , SAITO NARIMASA
IPC分类号： B01J37/02 , B01J23/50
摘要： PROBLEM TO BE SOLVED: To efficiently support a metal on the surface of a porous member without firing the porous member.
SOLUTION: The supporting method of a metal oxide or a metal on a porous member involves steps of setting a porous member 13 in a reaction vessel 11; introducing carbon dioxide to the reaction vessel and making carbon dioxide in the supercritical state; introducing a metal complex 17 to the reaction vessel and supporting the metal complex on the surface of the porous member by dissolving the metal complex in the carbon dioxide in the supercritical state; and introducing an oxidizing agent or a reducing agent to the reaction vessel in which carbon dioxide is in the supercritical state and supporting a metal oxide or a metal on the surface of the porous member by decomposing the metal complex deposited on the surface of the porous member. The porous member and the metal complex may be installed in non-contact state in the reaction vessel and in the inside of the reaction vessel, carbon dioxide may be made to be in the supercritical state and the metal complex may be dissolved in the carbon dioxide in the supercritical state to support the metal complex 17 of the surface of the porous member.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了有效地支撑多孔构件的表面上的金属而不烧制多孔构件。解决方案：多孔构件上的金属氧化物或金属的支撑方法包括将多孔构件13设置在反应容器11中的步骤; 将二氧化碳引入反应容器并使二氧化碳处于超临界状态; 将金属络合物17引入反应容器中，通过将金属络合物溶解在超临界状态的二氧化碳中，将金属络合物负载在多孔构件的表面上; 在二氧化碳处于超临界状态的反应容器中引入氧化剂或还原剂，并通过分解沉积在多孔构件的表面上的金属络合物，在多孔构件的表面上负载金属氧化物或金属。多孔构件和金属络合物可以以非接触状态安装在反应容器中，并且在反应容器的内部，可以使二氧化碳处于超临界状态，金属络合物可溶于二氧化碳在超临界状态下，以支撑多孔构件的表面的金属络合物17。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2005133038A Method and apparatus for desalination pyrolysis of waste plastics with supercrytical fluid 审中-公开
标题翻译：含超临界流体的废塑料脱盐热解方法与装置
公开(公告)号：JP2005133038A
公开(公告)日：2005-05-26
申请号：JP2003373379
申请日：2003-10-31
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： DEN TAKEYOSHI , YAMANO YUURIKEI , SAITO NARIMASA , TERAMAE NAOKI , NISHIMURA KENJI
IPC分类号： C08J11/16 , B01J3/00 , B01J3/02 , C05C3/00 , C08J11/20 , C08J11/24 , C08J11/28 , C10L5/48
CPC分类号： Y02E50/30 , Y02P20/544 , Y02W30/705 , Y02W30/706
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for desalination pyrolysis that have excellent desalination effect and excellent pyrolytic effect of waste plastics. SOLUTION: In the processing method where resin-containing waste is pyrolyzed and the vaporized chlorine is separated and the pyrolitic product is recovered, fluids other than water are brought into contact with the resin-including waste in the supercritical state under high pressure, and the resin-including waste is pyrolyzed. In a preferred embodiment, supercrytical fluids other than water are used as a heat medium and brought into contact with the resin-including waste under high pressure and pyrolyze the resin-including waste. Then, the pyrolitic products are cooled down, the pressure is decreased and the vaporized chlorine is separated and recycled as a fertilizer. In the meantime, the extracted products and the desalination residue in the pyrolysis tank are recovered as a fuel. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供脱盐热解方法和设备，其具有优异的脱盐效果和优异的废塑料热解效果。解决方案：在含有树脂的废物被热分解并蒸发的氯分离并回收热解产物的处理方法中，除了水之外的其他流体在高压下在超临界状态下与含树脂的废物接触，含有树脂的废物被热解。在优选的实施方式中，使用除水以外的超强流体作为热介质，并在高压下与包含树脂的废物接触并使包含树脂的废物热解。然后，将热解产物冷却，降低压力，蒸发的氯被分离并作为肥料再循环。同时，将热解槽中的提取物和脱盐残渣作为燃料回收。版权所有（C）2005，JPO＆NCIPI

3. 发明专利

JP2005239915A Method for producing polymer microparticle having hydrophilicity and apparatus for producing the same 审中-公开
标题翻译：生产具有亲水性的聚合物微球的方法及其制造方法
公开(公告)号：JP2005239915A
公开(公告)日：2005-09-08
申请号：JP2004052776
申请日：2004-02-27
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： HATAKEYAMA KO , YAMANO YUURIKEI , NISHIMURA KENJI , SAITO NARIMASA , MORI RYOHEI , DEN TAKEYOSHI
IPC分类号： C08J3/12
CPC分类号： Y02P20/544
摘要： PROBLEM TO BE SOLVED: To shorten a production step of a polymer microparticle having hydrophilicity compared to conventional processes.
SOLUTION: This method for producing the polymer microparticle having hydrophilicity comprises a step to dissolve or soften by melting an organic polymer by bringing the organic polymer into contact with carbon dioxide in a supercritical state in a first reactor 11, spouting the dissolved or melt-softened organic polymer with carbon dioxide from the first reactor 11 into a second reactor 21 whose pressure and temperature are lower than those of the first reactor 11 to obtain a jet stream where the organic polymer particle is micronized, and a process to apply ozone gas to the jet stream comprising the polymer microparticle and carbon dioxide in the second reactor 21 to react the microparticle with ozone to impart hydrophilic groups on the surface of the microparticle. The apparatus 10 is equipped with the pressure-resistant first reactor 11 where carbon dioxide is made into the supercritical state and the organic polymer is dissolved or melt-softened, and the second reactor 21 equipped with a spouting nozzle 22 for spouting the organic polymer with carbon dioxide to make the organic polymer particle micronized.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：与常规方法相比，缩短具有亲水性的聚合物微粒的制造步骤。解决方案：这种具有亲水性的聚合物微粒的制造方法包括通过在第一反应器11中使有机聚合物与超临界状态的二氧化碳接触而将有机聚合物熔融而溶解或软化的步骤，喷射溶解或将来自第一反应器11的二氧化碳的熔融软化的有机聚合物加入到其压力和温度低于第一反应器11的第二反应器21中的第二反应器21中，以获得其中有机聚合物颗粒被微粉化的喷射流，以及施加臭氧的方法在包含第二反应器21中的聚合物微粒和二氧化碳的射流中产生气体，使微粒与臭氧反应，从而在微粒表面赋予亲水基团。装置10配备有耐压第一反应器11，其中二氧化碳被制成超临界状态并且有机聚合物溶解或熔融软化，第二反应器21装备有用于喷射有机聚合物的喷射嘴22，二氧化碳使有机聚合物颗粒微粉化。版权所有（C）2005，JPO＆NCIPI

4. 发明专利

JP2005138063A Washing method by supercritical carbon dioxide and ozone 审中-公开
标题翻译：超级二氧化碳和臭氧的洗涤方法
公开(公告)号：JP2005138063A
公开(公告)日：2005-06-02
申请号：JP2003379325
申请日：2003-11-10
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： HATAKEYAMA KO , DEN TAKEYOSHI , NISHIMURA KENJI , SAITO NARIMASA , SHINOHARA KATSUNORI
IPC分类号： G03F7/42 , B08B7/00 , H01L21/304
摘要： PROBLEM TO BE SOLVED: To separate and remove not only low molecular organic matter but also polymer organic matter from a treatment object, and to reuse carbon dioxide used for washing the treatment object.
SOLUTION: In the subject washing method, the treatment object polluted with the organic matter on its surface is put into a washing tank 11, then the tank 11 is sealed. Next, liquid carbon dioxide or gaseous carbon dioxide and ozone are supplied to the tank 11. One of pressure or temperature inside the tank 11, or both of them are raised, and liquid carbon dioxide or gaseous carbon dioxide is changed into supercritical carbon dioxide state, or supercritical carbon dioxide is supplied to the tank 11, thus, the organic matter is decomposed by ozone, then extracted by supercritical carbon dioxide.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：不仅分离和去除来自处理对象的低分子有机物质，而且分离聚合物有机物质，并重新利用用于洗涤处理物体的二氧化碳。解决方案：在受试者洗涤方法中，将其表面上的有机物质污染的处理对象放入洗涤槽11中，然后将罐11密封。接下来，将液体二氧化碳或气态二氧化碳和臭氧供应到罐11.罐11内或其两者中的一个压力或温度升高，液态二氧化碳或气态二氧化碳变为超临界二氧化碳状态或超临界二氧化碳供给到罐11中，有机物被臭氧分解，然后用超临界二氧化碳萃取。版权所有（C）2005，JPO＆NCIPI

5. 发明专利

JP2004089904A Organic acid isolation method 审中-公开
公开(公告)号：JP2004089904A
公开(公告)日：2004-03-25
申请号：JP2002256546
申请日：2002-09-02
申请人： Mitsubishi Materials Corp , 三菱マテリアル株式会社
发明人： HATAKEYAMA KO , SAITO NARIMASA , TERAMAE NAOKI , YAMAGATA KAZUNORI , YAMANO YUURIKEI , KIKUCHI TOSHIAKI
IPC分类号： B01D11/00 , B01J3/00 , B01J20/26 , B01J20/34 , B01J49/00 , C07C51/47 , C07C53/02 , C07C53/08
摘要： PROBLEM TO BE SOLVED: To easily isolate and recover an organic acid from an organic acid-adsorbed substance. SOLUTION: Carbon dioxide at a temperature of 20°C or higher and a pressure of 1 MPa or higher is brought into contact with an organic acid-adsorbed substance (an anion exchange resin) containing water content to shift the organic acid to the carbon dioxide and isolate the organic acid from the substance. COPYRIGHT: (C)2004,JPO

6. 发明专利

JP2000266895A WASHING DEVICE OF MIXER FOR SOLIDIFICATION MATERIAL FOR SOLIDIFYING RADIOACTIVE WASTE 失效
公开(公告)号：JP2000266895A
公开(公告)日：2000-09-29
申请号：JP7197199
申请日：1999-03-17
申请人： MITSUBISHI MATERIALS CORP
发明人： TANAKA RYOJI , SAITO NARIMASA , ITO ISAO
IPC分类号： B01F15/00 , G21F9/28 , G21F9/30
摘要： PROBLEM TO BE SOLVED: To almost uniformly wash inside of a mixer by supplying a spray hole with washing water through a washing water supply pipe in a state a stirring vane is rotated and discharging washing water in spray from the spray hole by the use of the hydraulic pressure of washing water and centrifugal force due to rotation of washing shaft. SOLUTION: Water, cement and aggregate are stored in a mixing tank 12, a rotation shaft 14 is inserted from below the mixing tank into the mixing tank by penetrating the bottom wall 23b of the mixing tank and the rotation shaft is rotationally driven by a motor 13. Stirring vanes are radially fixed to the rotation shaft inserted in the mixing tank and with these stirring vanes, water, cement and aggregate are stirred and solidification material is produced. The upper end of the washing shaft 42 placed in one with the rotation shaft extends to near the upper end of the mixing tank and a plurality of spray holes 42d are placed in the upper part of the washing shaft above the solidifying material. The lower end of washing water supply pipe 43 inserted from the upper surface of the mixing tank into the tank is held rotatably at the upper end of the washing shaft and is constituted so as to supply the spray holes with washing water.

7. 发明专利

JP2002346304A METHOD OF REMOVING ORGANIC SUBSTANCE 审中-公开
公开(公告)号：JP2002346304A
公开(公告)日：2002-12-03
申请号：JP2002000747
申请日：2002-01-07
申请人： MITSUBISHI MATERIALS CORP
发明人： TANAKA AKIRA , SHINOHARA KATSUNORI , ARIMA YUSUKE , HATAKEYAMA KO , SAITO NARIMASA , DEN TAKEYOSHI , NISHIMURA KENJI , YAMANO YUURIKEI
IPC分类号： B08B3/08 , B01D11/00 , B01J3/00 , B08B3/10
摘要： PROBLEM TO BE SOLVED: To provide an organic substance removing method capable of highly efficiently discharging and removing an organic substance bonded to and infiltrated into a porous member in a short time by a simple process. SOLUTION: A fluid penetration process for holding the porous member W having the organic substance in a bonded and infiltrated state in a supercritical or subcritical fluid for a definite time in a washing container 5 and a pressure reducing process for discharging a fluid from the washing container 5 to rapidly lower the internal pressure of the washing container 5 to a pressure not more than supercritical or subcritical pressure are respectively performed at least once.

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