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1. 发明专利

JPH02290935A PREFORM FOR FIBER REINFORCED METALLIC COMPOSITE 失效
公开(公告)号：JPH02290935A
公开(公告)日：1990-11-30
申请号：JP11186589
申请日：1989-04-28
申请人： MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI
IPC分类号： B22D19/14 , C22C47/08 , D06M11/00 , D06M11/73 , D06M15/00 , D06M101/00 , D06M101/40
摘要： PURPOSE:To improve the strength and elastic modulus of the preform by subjecting a formed body of which the soln. of a resin binder having prescribed concn. is impregnated into an aggregate to heating to a prescribed temp. and subjecting the binder to carbonizing or the like. CONSTITUTION:The soln. of a resin binder having 3 to 25wt.% concn. is impregnated into an aggregate of carbon fibers or ceramic fibers, which is thereafter formed. The formed body is heated to >=1000 deg.C and the above resin binder is carbonized or graphitized. By the above method, the preform for a fiber reinforced metallic composite having excellent strength and elastic modulus can be obtd.

2. 发明专利

JPH0222428A PRODUCTION OF PREFORMED BODY FOR METALLIC SHORT FIBER COMPOSITE MATERIAL 失效
公开(公告)号：JPH0222428A
公开(公告)日：1990-01-25
申请号：JP17352988
申请日：1988-07-12
申请人： NISSAN MOTOR , MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI , MATSUNAGA MASAHARU , OGASAWARA TOSHIO
IPC分类号： B22D19/14 , C22C47/08
摘要： PURPOSE:To produce a uniform preform having shape-holding property by pouring a mixed solution in which short fibers are uniformly dispersed in a low-viscosity solution into a mold, drying the above mixed solution, and pouring a high-concentration binder into the resulting formed body to infiltrate this formed body with the above binder. CONSTITUTION:A mixed solution in which short fibers are uniformly dispersed by using a solution having a viscosity as low as >=50cP is prepared. It is preferable to use fiber reinforcement, such as carbon fibers, as the above short fibers and also to regulate aspect ratio to

3. 发明专利

JPH05230195A VISCOELASTIC RESIN FOR VIBRATION DAMPER AND VIBRATION-DAMPING METAL LAMINATE PRODUCED BY USING THE SAME VIBRATION DAMPER 失效
公开(公告)号：JPH05230195A
公开(公告)日：1993-09-07
申请号：JP3783192
申请日：1992-02-25
申请人： MITSUBISHI CHEM IND
发明人： GOTO JUNICHI , MIKI YASUAKI , KOYA YOSHIHIRO
IPC分类号： B32B7/02 , B32B15/08 , B32B15/09 , B32B27/36 , C08G63/181 , C08G63/183 , C08L67/00 , C08L67/03 , F16F15/02
摘要： PURPOSE:To provide the subject resin composed of a polyethylene terephthalate- based copolymer synthesized from specified dicarboxylic acid components and diol components composed mainly of ethylene glycol and exhibiting a specified heat of fusion. CONSTITUTION:The objective resin is composed of a partially crystalline copolyester exhibiting 5 to 50J/g heat of fusion within a range of 100 to 250 deg.C and >0.1 dissipation factor at 50 to 130 deg.C. The above-mentioned copolyester is obtained by esterifying and/or transesterifying at 120 to 230 deg.C between (A) dicarbosylic acid components in which 60 to 90mol% of dicarboxylic acid residues is terephthalic acid and (B) diol components in which 75 to 100mol% is ethylene glycol and polycondensing the resultant material at 170 to 300 deg.C under high vacuum.

4. 发明专利

JPH03275268A MANUFACTURE OF FIBER REINFORCED METAL STRIP 失效
公开(公告)号：JPH03275268A
公开(公告)日：1991-12-05
申请号：JP7627190
申请日：1990-03-26
申请人： MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI , MIYATA HIROSHI
IPC分类号： B22D18/02 , B22D17/22 , B22D19/14
摘要： PURPOSE:To manufacture a strip-state fiber reinforced metal material by pressurizing excess molten metal, which is caused to remain without being impregnated into a fiber preformed body with a pressurizing plunger and executing impregnation and forming treatment. CONSTITUTION:At the time of manufacturing the fiber reinforced metal strip with a molten metal 11 pressurized-impregnated by pouring the molten metal 11 into a metallic mold charged with the fiber preformed body 9, a feeder head part 13 is arranged and the volume thereof is changeable with the pressurizing plunger 7. Then, at the time of pressurizing the molten metal 11, the excess molten metal 11, which is caused to remain without being impregnated into the fiber preformed body 9, is pushed out to the feeder head part 13, and this feeder head part 13 is pressurized with the pressurizing plunger 7. By this method, defects of shrinkage hole and the non-impregnation of the molten metal to the fiber preformed body 9 are not developed, and the sound FRM can be manufactured with high productivity and low cost device.

5. 发明专利

JPH05294733A 失效
公开(公告)号：JPH05294733A
公开(公告)日：1993-11-09
申请号：JP1554891
申请日：1991-02-06
申请人： MITSUBISHI CHEM IND , OSAKA PREFECTURE
发明人： MIYAMOTO DAIKI , MORI MASAHIRO , KOYA YOSHIHIRO , KATAYAMA TOSHIAKI
IPC分类号： C04B35/584 , C04B35/58 , C04B35/80
摘要： PURPOSE:To obtain a silicon nitride-carbon fiber composite molded body excellent in crushing strength and a silicon nitride-carbon fiber composite sintered compact excellent in toughness by dispersing a specified amt. of short carbon fibers in a silicon nitride matrix. CONSTITUTION:Short carbon fibers are added to an aq. silicon nitride slurry by 0.1-30vol.% to prepare an aq. silicon nitride slurry contg. short carbon fibers. This slurry is molded by a slip casting method and the resulting molded body is sintered under pressure. The short carbon fibers have about. 50mum to 10mm average length and about 5-1,000 aspect ratio (length/diameter).

6. 发明专利

JPH0474835A MANUFACTURE OF FIBER REINFORCED METAL MATRIX COMPOSITE 失效
公开(公告)号：JPH0474835A
公开(公告)日：1992-03-10
申请号：JP18966890
申请日：1990-07-18
申请人： MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI , MIYATA HIROSHI
IPC分类号： C22C47/20
摘要： PURPOSE:To obtain a fiber reinforced metal matrix composite free from pores or the like, at the time of laminating prepreg sheets of inorganic long fibers and matrix metallic foils and executing hot pressing, by impregnating and interposing metallic powder having the m.p. higher than that of the matrix metal into the inorganic long fibers. CONSTITUTION:In the method for manufacturing a fiber reinforced metal matrix composite by laminating prescribed numbers of prepreg sheets of inorganic long fibers and matrix metallic foils, heating this laminate and thereafter executing pressurizing and forming by using a hot press, by impregnating and interposing metallic powder having the m.p. higher than that of the matrix metal into the inorganic long fibers as prepreg sheets to manufacture the fiber reinforced metal matrix composite. In this way, in the state where the metallic powder grains widen the distance between the reinforcing fibers, i.e., in the state similar to that where opening has been executed, the softened or partially dissolved matrix metallic foils are impregnated into the fibers, and next, the metallic powder grains are plastically deformed and fill pores, by which the fiber reinforced metal matrix composite having a dense structure can be obtd.

7. 发明专利

JPS59226141A MANUFACTURE OF MOLTEN ALUMINUM OR ALUMINUM ALLOY WITH HIGH VISCOSITY 失效
公开(公告)号：JPS59226141A
公开(公告)日：1984-12-19
申请号：JP9853183
申请日：1983-06-02
申请人： MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , YOSHIOKA FUMITAKA
IPC分类号： C22C1/00 , C22C1/02 , C22C1/10 , C22C47/08 , C22C1/09
摘要： PURPOSE:To increase the viscosity of molten Al (alloy) and to disperse efficiently an inorg. material in the molten metal by using Al (alloy) having Al oxide hydrate formed on the surface as a part of Al (alloy) to be melted. CONSTITUTION:Al (alloy) granules having Al oxide hydrate formed on the surfaces are prepd., and the granules and an Al (alloy) ingot are melted. At this time, the internal Al (alloy) of the Al (alloy) granules is melted, and the Al oxide hydrate shells are broken and dispersed uniformly in the resulting molten metal. Thus, molten Al with high viscosity is obtd., and an inorg. material is efficiently dispersed in the molten metal. By dispersing the inorg. material, an Al-inorg. material type composite material of high quality is obtd.

8. 发明专利

JPH02205640A PREFORMED BODY FOR FIBER-REINFORCED METAL MATRIX COMPOSITE 失效
公开(公告)号：JPH02205640A
公开(公告)日：1990-08-15
申请号：JP2728489
申请日：1989-02-06
申请人： MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI
IPC分类号： C04B35/80 , C22C47/08 , D04H1/4209
摘要： PURPOSE:To obtain a fiber preformed body for producing fiber-reinforced metal matrix composite having three-dimensionally isotropic property by impregnating a bundle of ceramic fibers with a binder, solidifying the binder, and then cutting the solidified bundle into a state of short fibers of specific shape. CONSTITUTION:Ceramic fibers, such as carbon fibers, alumina fibers, and silicon carbide fibers, are formed into a bundle, usually, of 10-1000 pieces, which is impregnated with a resin binder, such as polystyrene and polyvinyl alcohol, of 10-20% concentration and the resultant material is hardened. The above hardened connected fiber bundle is cut into a short-fiber state, by which the maximum length of the fiber is regulated to

9. 发明专利

JPH01321069A PRODUCTION OF CARBON FIBER REINFORCED METAL COMPOSITE 失效
公开(公告)号：JPH01321069A
公开(公告)日：1989-12-27
申请号：JP15569088
申请日：1988-06-23
申请人： HONDA MOTOR CO LTD , MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI , HATA SUENOBU
IPC分类号： B22D19/14 , C22C47/00 , C22C47/08 , C22C47/12
摘要： PURPOSE:To prevent damage of fiber and to obtain a carbon fiber reinforced metal composite material having sufficient strength by arranging a partition wall having different material as composite matrix material so that fiber aggregated part becomes discontinuation with the matrix after casting, on the surface of the fiber aggregated part. CONSTITUTION:The fiber is not particularly limited, but pitch series carbon fiber of coal series or oil series is used. Further, shape of the partition wall arranged on the surface of the fiber formed body may be cylindrical shape, etc., to be possible to restrain change toward vertical direction to the max. stress direction loaded on the composite part at the time of cooling. If the deformation in this direction can be restrained, it becomes difficult-to-buckling and the damage of the fiber does not occur. Generally, the material of this partition wall is used with iron, ceramic, etc.

10. 发明专利

JPH01192858A PRODUCTION OF FIBER PREFORM 失效
公开(公告)号：JPH01192858A
公开(公告)日：1989-08-02
申请号：JP1042288
申请日：1988-01-20
申请人： HONDA MOTOR CO LTD , MITSUBISHI CHEM IND
发明人： KOYA YOSHIHIRO , KATAYAMA TOSHIAKI , HATA SUENOBU , OTA TORU , NISHIMOTO TOYOKO
IPC分类号： B22D19/14 , D04H1/58
摘要： PURPOSE:To obtain a fiber preform giving high interfacial strength between carbon fiber and matrix in a carbon fiber reinforced metal material (C.F.R.M.), giving excellent fiber reserving properties to the C.F.R.M., by using a mixture of a solvent, resin component and carbon powder as a binder. CONSTITUTION:(A) A resin component (e.g., phenolic resin) is blended with (B) carbon powder (e.g., graphite of 0.1-1mum particle diameter) in the weight ratio of the component B to the component A of 0.1-2 and (C) a solvent (e.g., methyl alcohol) to give a molded article of carbon fiber. Then the shaped body is dried, cured and calcined to afford the aimed fiber preform.

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