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    • 3. 发明专利
    • Method for producing polybutylene terephthalate and apparatus for producing the same
    • 生产聚苯乙烯聚苯乙烯的方法及其制造方法
    • JP2006089761A
    • 2006-04-06
    • JP2005371283
    • 2005-12-26
    • Hitachi Ltd株式会社日立製作所
    • NAKAMOTO HIDEKAZUHARADA SUSUMUSASE YASUNARISUZUKI MICHIO
    • C08G63/78
    • PROBLEM TO BE SOLVED: To provide a method or apparatus for continuously producing polybutylene terephthalate in good profitability.
      SOLUTION: This method for continuously producing the polybutylene terephthalate, comprising feeding a mixture of an aromatic dicarboxylic acid or its derivative and a glycol compound as raw materials into the first reactor to produce the oligoester having an average polymerization degree of 3 to 7 at a temperature of 220 to 275 degree, producing a low polymer having an average polymerization degree of 20 to 40 at a temperature of 220 to 280 degree at a pressure of the atmospheric pressure to 133 Pa in the second reactor, and then polycondensing the low polymer at a temperature of 220 to 280 degree at a pressure of 220 to 13.3 Pa in the third reactor to produce the polybutylene terephthalate having an average polymerization degree 70 to 180 is characterized in that the third reactor is equipped with a rotatable stirring rotor having stirring blade blocks corresponding to the viscosity of a treating liquid therein, and does not have a rotation shaft in the center of the stirring blades.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种连续生产聚对苯二甲酸丁二醇酯具有良好盈利能力的方法或装置。 解决方案:用于连续制备聚对苯二甲酸丁二醇酯的方法,包括将芳族二羧酸或其衍生物和二醇化合物的混合物作为原料进料到第一反应器中以制备平均聚合度为3至7的低聚酯 在220〜275度的温度下,在第二反应器中,在大气压至133Pa的压力下,在220〜280℃的温度下制造平均聚合度为20〜40的低聚物,然后使低聚 聚合物在220〜280度的温度下在220〜13.3Pa的压力下进行,得到平均聚合度为70〜180的聚对苯二甲酸丁二醇酯,其特征在于,所述第三反应器具有可搅拌的可旋转搅拌转子 叶片块对应于其中的处理液体的粘度,并且在搅拌叶片的中心不具有旋转轴 秒。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • DEVICE AND METHOD FOR CONTINUOUS POLYCONDENSATION
    • JP2002121271A
    • 2002-04-23
    • JP2001248471
    • 2001-08-20
    • HITACHI LTD
    • NAKAMOTO HIDEKAZUHARADA SUSUMUSASE YASUNARISUZUKI MICHIO
    • B01J19/18B01F7/02C08G63/78C08G64/20C08G85/00
    • PROBLEM TO BE SOLVED: To provide a continuous polycondensation device and a continuous polycondensation method which can long maintain a liquid to be treated in a cylindrical container body in a thin film-like state under stirring blades having relatively simple structures to well refresh the surfaces of the liquid, thereby efficiently obtaining a polymerization reaction product having a good quality, and to provide a continuous polycondensation device and a continuous polycondensation method which can give the treated liquid having a wide viscosity range by a small stirring consumption power. SOLUTION: The continuous polycondensation device is manufactured by disposing a stirring rotor (4) rotated in the longitudinal direction of the horizontal cylindrical container body (1) in a state adjacent to the inside of the container body, connecting plural stirring blocks in the stirring rotor to form a stirring rotor optimal to the viscosity range of the treated liquid, attaching rotation-supporting shafts (3a, 3b) to both the ends of the stirring rotor through support members, and forming a structure where a member such as a shaft is not attached to the rotation center of the stirring rotor. Thereby, the liquid to be treated in the cylinder body is shaped into a thin film with the stirring blocks optimal to the viscosity range to obtain a wide evaporation surface area, thus enabling to obtain a sufficient surface-refreshing action and thereby efficiently produce a polymer having a good quality.
    • 7. 发明专利
    • HEATING/MIXING VESSEL
    • JP2000084387A
    • 2000-03-28
    • JP26431598
    • 1998-09-18
    • HITACHI LTD
    • SUZUKI MICHIOSASE YASUNARIHARADA SUSUMUODA CHIKAONAKAMOTO HIDEKAZU
    • B01F5/00B01F15/06F28D7/10
    • PROBLEM TO BE SOLVED: To improve the efficiency of heat transfer in a heat transfer pipe and to attain the mixing effect on fluid to be heated by providing a heat exchanger structured by attaching a cylindrical baffle plate to the tip of a supporting rigid body attached to the surface in contact with liquid in the side of the fluid to be heated of a body part rigid body to have some distance from the body part rigid body and to surround the body part rigid body. SOLUTION: The cylindrical tube plate type heat exchanger, in which the heated fluid having higher temp. than that of the fluid to be heated flows outside of plural heat transfer tubes 5, is provided in a heating/mixing vessel 1. In the heat exchanger, the cylindrical baffle plate 3 is attached with the supporting rigid body 4 to have some distance from the body wall 6 of the heat exchanger and to surround the body wall 6. As a result, the efficiency of heat transfer in the heat transfer tubes 5 is increased by the circulation flow due to the heat convection of the fluid to be heated and the fluid to be heated is efficiently heated, vaporized and chemically reacted by mixing/heating to obtain the mixing effect of the fluid to be treated inside of the heating/mixing vessel 1.
    • 9. 发明专利
    • APPARATUS AND METHOD FOR CONTINUOUS POLYCONDENSATION
    • JPH10259242A
    • 1998-09-29
    • JP6609297
    • 1997-03-19
    • HITACHI LTD
    • NAKAMOTO HIDEKAZUHARADA SUSUMUSASE YASUNARISUZUKI MICHIO
    • B01F7/04C08G63/183C08G63/78C08G85/00
    • PROBLEM TO BE SOLVED: To provide an apparatus and method for continuous polycondensation, covering a wide range of viscosity of a liquid to be treated and consuming less power for agitation, which satisfactorily renews liquid surfaces while keeping thin films of the liquid in the apparatus body for an extended period by the aid of an agitating blade of relatively simple structure, to efficiently produce a polymer of high quality. SOLUTION: This apparatus is equipped with a horizontal, cylindrical vessel body 1 and agitating rotor 4 arranged in the longitudinal direction to rotate in the vicinity of the inner wall of the body 1, wherein two or more agitating blocks, optimized for a viscosity range of a liquid to be treated, are connected to each other in the agitating rotor 4 to form the agitating rotor 4, and shafts 3a and 3b to rotate the agitating rotor 4 are provided at both ends of the agitating rotor 4 via support members 2a and 2b, so as to dispense with a shaft or the like in the center of rotation of the agitating rotor 4. The liquid to be treated in the body 1 is made into thin films by the agitating blocks, optimized for a viscosity range of the liquid, to provide a wide evaporation surfaces, thereby securing a sufficient surface-renewal effect and efficiently producing a polymer of high quality.
    • 10. 发明专利
    • APPARATUS AND METHOD FOR CONTINUOUS POLYCONDENSATION
    • JPH09169852A
    • 1997-06-30
    • JP33218695
    • 1995-12-20
    • HITACHI LTD
    • ODA CHIKAONAKAMOTO HIDEKAZUSAKAGUCHI KAZUOSASE YASUNARISUZUKI MICHIO
    • C08G63/183C08G63/78C08G64/20C08G85/00
    • PROBLEM TO BE SOLVED: To provide an apparatus for continuous polycondensation by which a good-quality polymer can be obtained at good efficiency as a result of the uniform agitation and surface refreshment of the solution to be treated in the body, realized by an impeller having a relatively simple structure, and to provide a method for continuos polycondensation performed therewith 1. SOLUTION: A rotary shaft 2 is provided in the longitudinal direction in the inside of the body 1 of a vertical cylindrical container, and the inside of the body is partitioned with annular members into a plurality of sections, each of which formes a doughnut-like agitation chamber 6. The sides of two adjoining agitation chambers are connected to each other through a connecting pipe 5. Agitating members 7A and 7B for scraping up the liquid in each chamber on the outside wall side and scraping down the liquid on the inside wall side is attached to a rotary axis 2, and a clearance through which volatile matter passes is provided between the inside of the doughnut-like agitation chamber 7 and the rotary shaft 2. Because the liquid can be agitated in the body under the conditions of nearly perfect self-cleaning and is subjected to surface refreshment, a polymer free from deterioration due to excessively long stay and having good quality can be produced at good efficiency.