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    • 1. 发明专利
    • SILVER HALIDE PHOTOGRAPHIC SENSITIVE MATERIAL
    • JPH01193735A
    • 1989-08-03
    • JP1777388
    • 1988-01-28
    • FUJI PHOTO FILM CO LTD
    • OKADA MASAHIROONO SHIGERUKUWABARA KENICHI
    • G03C1/825G03C1/83
    • PURPOSE:To obtain a hydrophilic colloid layer by a novel water soluble dye which does not exert harmful influence on photographic characteristics by incorporating at least one kind of specific dye compds. into said layer. CONSTITUTION:At least one kind of the dye compds. expressed by the formula I is incorporated into the above-mentioned layer. In the formula I, R1 denotes an aryl group, cyano group, etc.; R2 denotes a hydrogen atom or alkyl group; Q denotes an aryl group; X denotes a bond or bivalent combination group; Y denotes a sulfo group or carboxyl group; L1-L3 denote a methine group; n denotes 0 or 1; m denotes 1 or 2; p denotes 0-4; q denotes 1-3; R3, R4 may be the same or different and denote a hydrogen atom, halogen atom, alkyl group, sulfo group, etc.; R5, R6 may be the same or different and denote a hydrogen atom, alkyl group, sulfonyl group, etc.; at least either of R5, R6 has a sulfo group as a substituent. The hydrophilic colloid layer contg. the novel water soluble dye which does not exert the harmful influence on the photographic characteristics is thereby obtd.
    • 2. 发明专利
    • SILVER HALIDE PHOTOGRAPHIC SENSITIVE MATERIAL
    • JPS62235939A
    • 1987-10-16
    • JP7953286
    • 1986-04-07
    • FUJI PHOTO FILM CO LTD
    • TAKAHASHI TOSHIROKUWABARA KENICHIKAMEOKA KIMITAKAOKADA MASAHIRO
    • G03C1/005G03C1/035G03C1/06G03C1/46
    • PURPOSE:To obtain the titled material having improved quality of negative character and lessening a tape sticking mark and a pinhole by equipping a layer contg. a specific amount of a rodium salt with the titled material, and by making the higher sensitivity of an under layer of the emulsion layer than that of the uppermost layer of the emulsion layer, and by incorporating a hydra zine derivative and a dyestuff compd. to the titled material. CONSTITUTION:The photographic sensitive material for the daylight room comprises >=2 layers having different sensitivities composed of the silver chloride particle contg. 1X10 -1X10 mol of the rodium salt (for example, (NH3)RhCl6) per 1mol of silver, or the silver chlorobromide particle contg. >=80mol% silver chloride. The sensitivity of the lowest layer of the emulsion is higher than that of the uppermost layer of the emulsion. One or more of the emulsion layers or the another hydrophilic colloidal layers contain a hydrazine derivative (for example, a compd. shown by formula I) and the dyestuff compd. having 400-550nm lambdamax. wavelength (for example, a compd. shown by formula II). Thus, the photographic sensitive material for the light place which can be handled at the safe-light and has the quality of negative image charactor, and is lessened the tape sticking mark and the pinhole is obtd.