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    • 10. 发明专利
    • PREPARATION OF HIGH CHLORIDE (100) FLAT PLATE-LIKE PARTICLE EMULSION
    • JPH11218865A
    • 1999-08-10
    • JP33257198
    • 1998-11-24
    • EASTMAN KODAK CO
    • MASKASKY JOE EDWARDSCACCIA VICTOR P
    • G03C1/015G03C1/005G03C1/035
    • PROBLEM TO BE SOLVED: To obtain 100} flat plate-like silver halide particles high in silver concentration in an emulsion at the time of completing a particle growth process and large in average particle diameter and high in average aspect ratio by growing the high chloride 100} flat plate-like particles from a particle nucleus host, and at that time allowing a secondary particle group to act as a silver halide source for growing the flat plate-like particles. SOLUTION: The silver halide emulsion containing a gelatin deflocculant and a specified aqueous dispersion medium and silver halide particle nuclei containing 1-10% of the total silver amount in the photographic emulsion and bromide for promoting growth of 100} flat plate-like particles is prepared in a reaction vessel. The secondary silver halide particle group is formed by adding halide ions containing chloride in an amount of >=50 mol.% of silver the emulsion while limiting the total volume to 0.7-2.0 l/mol of silver and finishing addition of the silver for forming the emulsion layer. The flat plate-like particles having the 100} principal faces are grown by raising the temperature of the dispersion medium and ripening the secondary particle group.