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    • 5. 发明专利
    • Metal nanoparticle, method for producing the same, and conductive ink
    • 金属纳米材料,其制造方法和导电墨水
    • JP2013185213A
    • 2013-09-19
    • JP2012051636
    • 2012-03-08
    • Tokyo Institute Of Technology国立大学法人東京工業大学Showa Denko Kk昭和電工株式会社
    • WADA YUJICHIN SATOSHIMOCHIZUKI MASARUUCHIDA HIROSHISHINOZAKI KENJITOMITA HIROYUKI
    • B22F1/02B22F1/00B22F9/24C09D11/00H01B1/00H01B1/22H01B5/00H01B13/00
    • PROBLEM TO BE SOLVED: To provide a method for easily producing a metal nanoparticle which is not easily oxidized even when having a relatively low silver content, the metal nanoparticle obtainable by the production method, and a conductive ink using the metal nanoparticle.SOLUTION: A core particle of a first metal is produced by heating a core-forming solution including a first metal precursor and an organic solvent. By adding a second metal precursor, wherein the second metal has lower ionization tendency than the first metal, to the solution including the core particle of the first metal and heating the solution, displacement plating is performed on a surface layer of the core particle with the second metal, thereby allowing the second metal particle having a smaller diameter than the core particle to precipitate on the surface of the core particle. Also, a layer of the first metal in which the second metal particle is enclosed is produced by reducing the first metal ion produced by the displacement plating. Thus the metal nanoparticle is obtained by forming a shell covering the surface of the core particle.
    • 要解决的问题:提供一种易于制造金属纳米颗粒的方法,其即使在银含量较低时也不容易氧化,可以通过制备方法得到的金属纳米颗粒和使用金属纳米颗粒的导电油墨。 通过加热包含第一金属前体和有机溶剂的芯形成溶液来制造第一金属的核心颗粒。 通过添加第二金属前体,其中第二金属比第一金属具有更低的离子化倾向,向包含第一金属的芯颗粒的溶液中加热溶液,在芯颗粒的表面层上进行置换镀 从而允许具有比核心颗粒小的直径的第二金属颗粒在核心颗粒的表面上沉淀。 此外,通过还原由位移镀产生的第一金属离子,产生其中封入第二金属颗粒的第一金属层。 因此,通过形成覆盖芯颗粒的表面的壳来获得金属纳米颗粒。