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1. 发明专利

JP2014169449A Water- and oil-repellent composition 有权
标题翻译：水和油脂组合物
公开(公告)号：JP2014169449A
公开(公告)日：2014-09-18
申请号：JP2014095234
申请日：2014-05-02
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： MAEKAWA TAKASHIGE , SHIMADA MINAKO , SUGIMOTO SHUICHIRO , SEKI TAKASHI
IPC分类号： C09K3/18 , D06M15/277
CPC分类号： C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a water- and oil-repellent composition which can impart water and oil repellency to an article even if processed at a low temperature and can apply a water- and oil-repellent treatment providing a soft feeling.SOLUTION: There is provided a water- and oil-repellent composition which essentially contains a copolymer containing a polymerization unit of the following monomer (a) and a polymerization unit of the following monomer (b). Monomer (a): a monomer having a polyfluoroalkyl group in which a fine crystal derived from a polyfluoroalkyl group of a homopolymer of the monomer has no melting point or has a melting point of 50°C or less, Monomer (b): a monomer having an organic group other than the polyfluoroalkyl group in which a fine crystal derived from an organic group of a homopolymer has a melting point of 30°C or more.
摘要翻译：要解决的问题：提供一种拒水拒油剂组合物，即使在低温下加工也能赋予防水和防油性，并且可以应用提供柔软感觉的拒水拒油处理。解决方案：提供了拒水拒油组合物，其基本上含有含有下列单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物。单体（a）：具有多氟烷基的单体，其中来源于单体的均聚物的多氟烷基的微细结晶不具有熔点或熔点为50℃以下，单体（b）：单体具有来自均聚物的有机基团的微细晶体的熔点为30℃以上的多氟烷基以外的有机基团。

2. 发明专利

JP2013007044A Water and oil repellent composition 有权
标题翻译：水和油组合物
公开(公告)号：JP2013007044A
公开(公告)日：2013-01-10
申请号：JP2012180844
申请日：2012-08-17
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： MAEKAWA TAKASHIGE , SHIMADA MINAKO , SUGIMOTO SHUICHIRO , SEKI TAKASHI
IPC分类号： C09K3/18 , D06M15/277
CPC分类号： C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a water and oil repellent composition which can impart excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand.SOLUTION: The water and oil repellent composition includes as essential components a copolymer comprising a polymerization unit of the following monomers (a) and a polymerization unit of the following monomers (b). The monomer (a) includes a polyfluoroalkyl group, wherein the monomer including the polyfluoroalkyl group has no melting point for a fine crystal derived from the polyfluoroalkyl group of the homopolymer of the monomer, or has a melting point that is ≤50°C. The monomer (b) has an organic group other than the polyfluoroalkyl group, wherein the monomer having an organic group other than the polyfluoroalkyl group has a melting point that is higher than 30°C or higher for a fine crystal derived from the organic group of the homopolymer.
摘要翻译：解决问题的方案：即使在低温下进行加工也能够使物品具有优异的拒水拒油性的斥水斥油剂组合物，能够实现斥水斥油处理，柔软的手。解决方案：防水斥油剂组合物包括作为必要组分的包含以下单体（a）的聚合单元和以下单体（b）的聚合单元的共聚物。单体（a）包括多氟烷基，其中，包含多氟烷基的单体对于来自单体的均聚物的多氟烷基的微细结晶没有熔点，或者熔点为≤50℃。单体（b）具有除了多氟烷基以外的有机基团，其中，具有除了多氟烷基以外的有机基团的单体的熔点相对于来自有机基团的有机基团的微细晶体的熔点高于30℃以上均聚物。版权所有（C）2013，JPO＆INPIT

3. 发明专利

JP2008044876A Method for producing monooxyalkylenediol 审中-公开
标题翻译：生产单羟基乙烯醇的方法
公开(公告)号：JP2008044876A
公开(公告)日：2008-02-28
申请号：JP2006221115
申请日：2006-08-14
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： SHIMIZU TAMAKI , SEKI TAKASHI
IPC分类号： C07C41/16 , C07B61/00 , C07C43/178
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a monooxyalkylenediol, especially 4-oxa-1,7-heptanediol. SOLUTION: The method for producing a compound represented by formula: HO(CH 2 ) y O(CH 2 ) z OH [(y) and (z) are each independently an integer of 2 to 6] comprises reacting a compound represented by formula: HO(CH 2 ) y OH with a compound of represented by formula: X(CH 2 ) z OH (X is Cl or Br) in the presence of an alkali metal hydroxide. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一氧化亚烷基二醇，特别是4-氧杂-1,7-庚二醇的制备方法。＆lt; P＆gt;解决方案：由下式表示的化合物的方法：HO（CH 2 SBB）O（CH 2 SB 2）SB Z [OH] [（y）和（z）各自独立地为2〜6的整数]包括使式HO：CH（CH 2 SBR）在碱金属氢氧化物的存在下，使用式（X）表示的化合物：（S）SB（OH）版权所有（C）2008，JPO＆INPIT

4. 发明专利

JP2006274237A Fluorinated elastomer latex, its production method, fluorinated elastomer and fluororubber molded product 有权
标题翻译：氟化弹性体LATEX，其生产方法，氟化弹性体和氟橡胶模制产品
公开(公告)号：JP2006274237A
公开(公告)日：2006-10-12
申请号：JP2005291572
申请日：2005-10-04
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： FUNAKI CHU , SEKI TAKASHI , OHARU KAZUYA , KAMIYA HIROKI
IPC分类号： C08F2/26 , C08F14/18 , C08F16/24
CPC分类号： C08F214/265 , C08F214/262 , C08K5/09 , C08L27/12
摘要： PROBLEM TO BE SOLVED: To provide a fluorinated elastomer latex stabilized by a specific fluorinated emulsifier, its production method, a fluorinated elastomer and a fluororubber molded product.
SOLUTION: A fluorinated elastomer latex comprises an aqueous medium, a fluorinated elastomer dispersed in the aqueous medium in an amount of 10-60% by mass and a fluorinated emulsifier represented by formula (1): C
2 F
5 O(CF
2 CF
2 O)
m CF
2 COOA, wherein A is a hydrogen atom, an alkali metal or NH
4 , and m is an integer of 1-3.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供通过特定的含氟乳化剂稳定的含氟弹性体胶乳，其制备方法，氟化弹性体和氟橡胶模制产品。解决方案：氟化弹性体胶乳包含水性介质，分散在水性介质中的含氟弹性体，其量为10-60质量％，由式（1）表示的含氟乳化剂：C < SB>˚F 5 O（CF 2 CF 2 O）米 CF 2 COOA，其中A为氢原子，碱金属或NH 4 SB，m为1-3的整数。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2004359616A Method for producing polyfluoroalkyl ester of (meth)acrylic acid 审中-公开
标题翻译：（甲基）丙烯酸的聚氟代醇酯的制备方法
公开(公告)号：JP2004359616A
公开(公告)日：2004-12-24
申请号：JP2003160885
申请日：2003-06-05
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： FURUTA SHOJI , HOSHINO YASUTERU , SEKI TAKASHI
IPC分类号： B01D3/14 , C07C17/383 , C07C67/10 , C07C67/54 , C07C67/56 , C07C69/003 , C07C69/653 , C08G63/682 , C08G63/78 , C08G63/90
CPC分类号： C07C67/10 , C07C17/383 , C07C67/56 , C07C21/18 , C07C69/653
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a polyfluoroalkyl ester of (meth)acrylic acid in high purity and high yield.
SOLUTION: The method for producing the polyfluoroalkyl ester of (meth)acrylic acid comprises (1) taking out a crude liquid from a reaction mixture obtained by reacting C
n F
2n+1 (CH
2 )
m I (n is 2-7; and m is 1-4) with a metal salt of (meth)acrylic acid in tert-butanol, and containing the polyfluoroalkyl ester of (meth)acrylic acid by a solid-liquid separation, (2) separating the crude liquid to a compound group A having the low boiling points, and a compound group B comprising the eater and compounds having the boiling points higher than that of the ester by distillation, and (3) purifying the ester from the compound group B by distillation.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供以高纯度和高产率制备（甲基）丙烯酸的多氟烷基酯的方法。解决方案：（甲基）丙烯酸的多氟烷基酯的制造方法包括：（1）从通过使C（S）（甲基）丙烯酸的金属盐在叔丁醇中与（甲基）丙烯酸的金属盐与（甲基）丙烯酸的金属盐反应， - 丁醇，并且通过固液分离含有（甲基）丙烯酸的多氟烷基酯，（2）将粗液体分离成具有低沸点的化合物基团A和包含食料的化合物组B和具有通过蒸馏使沸点高于酯的沸点，（3）通过蒸馏从化合物组B中纯化酯。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2003335773A Fluorine-containing compound, method for producing the same, fluorine-containing polymer and water- and oil- repellent agent composition 审中-公开
标题翻译：含氟化合物，其生产方法，含氟聚合物和水和油剂组合物
公开(公告)号：JP2003335773A
公开(公告)日：2003-11-28
申请号：JP2002144612
申请日：2002-05-20
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： SEKI TAKASHI , SHIMADA SANNASHI , OHARU KAZUYA , MAEKAWA TAKASHIGE
IPC分类号： C07D317/42 , C08F20/28 , C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a new fluorine-containing compound, a fluorine-containing polymer having excellent solubility in a solvent, and a water- and oil-repellent agent composition hardly providing load on the environment, and having excellent water- and oil-repellency.
SOLUTION: The fluorine-containing compound is represented by formula 1 or 2 (Z is HO-or CH
2 =CR
1 COO-; R
1 is a hydrogen atom or a methyl group). The fluorine-containing polymer is obtained by polymerizing the fluorine- containing compound. The water- and oil-repellent agent composition contains the fluorine-containing polymer.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：为了提供新的含氟化合物，在溶剂中具有优异的溶解性的含氟聚合物和难以对环境施加负载的拒水拒油剂组合物，并且具有优异的水 - 和防油性。解决方案：含氟化合物由式1或2表示（Z为HO-或CH 2 = CR 1 COO-; R 1 是氢原子或甲基）。通过聚合含氟化合物得到含氟聚合物。拒水拒油剂组合物含有含氟聚合物。版权所有（C）2004，JPO

7. 发明专利

JP2007106958A Fluorine-based surfactant 审中-公开
标题翻译：基于氟的表面活性剂
公开(公告)号：JP2007106958A
公开(公告)日：2007-04-26
申请号：JP2005301751
申请日：2005-10-17
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： MORISAWA YOSHITOMI , SEKI TAKASHI
IPC分类号： C09K3/00 , B01F17/42 , C07C235/10 , C07C235/12
摘要： PROBLEM TO BE SOLVED: To obtain a new fluorine-based surfactant that has excellent surface tension reduction ability and dynamic surface tension reduction ability. SOLUTION: The fluorine-based surfactant comprises a compound represented by formula CF 3 CF 2 OCF 2 CF 2 OCF 2 CON(R)Z (R is selected from a hydrogen atom, an alkyl group or a hydroxyalkyl group; Z is a quaternary ammonium halogen salt, betaine, an amine oxide and a carboxylate and is a monofunctional group obtained by removing one hydrogen atom among one or more hydrogen atoms from a compound essentially containing one or more hydrogen atoms bonded to a carbon atom; R and Z may be mutually bonded to from a bifunctional group and the bifunctional group is selected from a quaternary ammonium halogen salt, betaine, amine oxide and an amino acid salt and is a bifunctional group obtained by removing two hydrogen atoms among two or more hydrogen atoms from a compound essentially containing two or more hydrogen atoms bonded to a carbon atom). COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：获得具有优异的表面张力降低能力和动态表面张力降低能力的新的氟基表面活性剂。解决方案：氟系表面活性剂包括由式CF 3，CF 2，SB 2，CF 2， Z（R）选自氢原子，烷基或羟烷基; Z是季铵卤素盐，甜菜碱，氧化胺和羧酸盐，和是通过从基本上含有一个或多个与碳原子键合的氢原子的化合物的一个或多个氢原子中除去一个氢原子获得的单官能团; R和Z可以相互键合到双官能团上，并且选择双官能团来自季铵卤素盐，甜菜碱，氧化胺和氨基酸盐，并且是通过从基本上含有两个或更多个键合到碳原子的氢原子的化合物的化合物中除去两个或更多个氢原子中的两个氢原子获得的双官能团）。版权所有（C）2007，JPO＆INPIT

8. 发明专利

JP2006036986A Fluorine-containing polymer latex, method for producing the same and fluorine-containing polymer 审中-公开
标题翻译：含氟聚合物胶乳，其制备方法和含氟聚合物
公开(公告)号：JP2006036986A
公开(公告)日：2006-02-09
申请号：JP2004220860
申请日：2004-07-28
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： FUNAKI CHU , SEKI TAKASHI , OHARU KAZUYA , KAMIYA HIROKI
IPC分类号： C08L27/12 , C08F214/18 , C08K5/095
CPC分类号： C08F14/18 , C08K5/095 , C08L27/18 , C08L71/02 , C08F2/22 , C08L2666/04
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a fluorine-containing polymer latex, excellent in the productivity of the fluorine-containing polymer latex and also in the storage stability of the obtained fluorine-containing polymer latex, and the fluorine-containing polymer latex. SOLUTION: The method for producing the fluorine-containing polymer latex is characterized by performing an emulsion polymerization of a fluorine-containing monomer in an aqueous medium containing 0.001-10.0 mass% fluorine-containing surfactant expressed by the formula (1): F(CF 2 ) n O(CF 2 CF 2 O) m CF 2 COOA [wherein, A is H, an alkali metal or NH 4 ; (n) is 3-10 integer; and (m) is 0 or 1-3 integer] to obtain the fluorine-containing polymer latex. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：解决问题的方法：提供含氟聚合物胶乳的生产率优异的含氟聚合物胶乳的制造方法以及所得含氟聚合物胶乳的储存稳定性，以及氟含聚合物胶乳。解决方案：含氟聚合物胶乳的制造方法的特征在于，在含有式（1）表示的含有0.001〜10.0质量％含氟表面活性剂的水性介质中进行含氟单体的乳液聚合： F（CF 2 ）名词 O（CF 2 CF 2 O）米 CF 2 COOA [其中，A为H，碱金属或NH 4 SB; （n）为3-10整数; 和（m）为0或1-3个整数]，得到含氟聚合物胶乳。版权所有（C）2006，JPO＆NCIPI

9. 发明专利

JP2010001499A Water and oil repellent composition 有权
标题翻译：水和油组合物
公开(公告)号：JP2010001499A
公开(公告)日：2010-01-07
申请号：JP2009233709
申请日：2009-10-07
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： MAEKAWA TAKASHIGE , SHIMADA MINAKO , SUGIMOTO SHUICHIRO , SEKI TAKASHI
IPC分类号： C09K3/18
CPC分类号： C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a water and oil repellent composition which can impart an excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand.
SOLUTION: The water and oil repellent composition has as essential components a copolymer comprising a polymerization unit of the following monomers (a) and a polymerization unit of the following monomers (b) in which the monomer (a) is a monomer such as a (meth)acrylate having perfluoroalkyl group having 6 carbon atoms, and the monomer (b) is a monomer such as (meth)acrylate having a linear hydrocarbon group having 14 or more carbon atoms.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决问题：即使在低温下进行加工，也可以提供能够赋予物体优异的拒水防油性的斥水斥油剂组合物，能够实现防油斥斥处理，柔软的手。解决方案：防水斥油剂组合物具有作为主要组分的共聚物，其包含以下单体（a）的聚合单元和以下单体（b）的聚合单元，其中单体（a）为单体作为具有6个碳原子的全氟烷基的（甲基）丙烯酸酯，单体（b）是具有碳原子数为14以上的直链状烃基的（甲基）丙烯酸酯等单体。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2007332068A New fluoroadamantane derivative and method for producing the same 审中-公开
标题翻译：新的氟代丹参酮衍生物及其生产方法
公开(公告)号：JP2007332068A
公开(公告)日：2007-12-27
申请号：JP2006164865
申请日：2006-06-14
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： OU JIYOSHIYOU , MURATA KOICHI , SEKI TAKASHI , SHIMIZU TAMAKI , YAMASHITA HIROMASA
IPC分类号： C07C31/27 , C07B61/00 , C07C29/38 , C07C62/06 , C07C67/03 , C07C69/757
摘要： PROBLEM TO BE SOLVED: To obtain a new fluoroadamantane derivative and to provide a method for producing the same.
SOLUTION: The method for producing a compound represented by formula (5) comprises reacting a compound represented by formula (6) with a compound represented by formula (R
FA C(O))
2 O and then with a compound represented by formula (R
FB CH
2 OH). The method for producing a compound represented by formula (1) comprises reacting a compound represented by formula (31) with a protonic nucleophilic species to give a compound represented by formula (2) and then reacting the compound represented by formula (2) with a basic compound represented by formula R-CHO in the presence of a basic compound.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：获得新的氟金刚烷衍生物并提供其制备方法。解决方案：由式（5）表示的化合物的制备方法包括使由式（6）表示的化合物与式（R“SP”C（O））表示的化合物 2 O，然后与由式（R 2 SP 2 CH 2 CH 2）表示的化合物反应。制备由式（1）表示的化合物的方法包括使式（31）表示的化合物与质子亲核物质反应，得到由式（2）表示的化合物，然后使由式（2）表示的化合物与在碱性化合物存在下由式R-CHO表示的碱性化合物。版权所有（C）2008，JPO＆INPIT

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