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1. 发明专利

JP2003335773A Fluorine-containing compound, method for producing the same, fluorine-containing polymer and water- and oil- repellent agent composition 审中-公开
标题翻译：含氟化合物，其生产方法，含氟聚合物和水和油剂组合物
公开(公告)号：JP2003335773A
公开(公告)日：2003-11-28
申请号：JP2002144612
申请日：2002-05-20
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： SEKI TAKASHI , SHIMADA SANNASHI , OHARU KAZUYA , MAEKAWA TAKASHIGE
IPC分类号： C07D317/42 , C08F20/28 , C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a new fluorine-containing compound, a fluorine-containing polymer having excellent solubility in a solvent, and a water- and oil-repellent agent composition hardly providing load on the environment, and having excellent water- and oil-repellency.
SOLUTION: The fluorine-containing compound is represented by formula 1 or 2 (Z is HO-or CH
2 =CR
1 COO-; R
1 is a hydrogen atom or a methyl group). The fluorine-containing polymer is obtained by polymerizing the fluorine- containing compound. The water- and oil-repellent agent composition contains the fluorine-containing polymer.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：为了提供新的含氟化合物，在溶剂中具有优异的溶解性的含氟聚合物和难以对环境施加负载的拒水拒油剂组合物，并且具有优异的水 - 和防油性。解决方案：含氟化合物由式1或2表示（Z为HO-或CH 2 = CR 1 COO-; R 1 是氢原子或甲基）。通过聚合含氟化合物得到含氟聚合物。拒水拒油剂组合物含有含氟聚合物。版权所有（C）2004，JPO

2. 发明专利

JP2007291373A Liquid repellent composition, method for liquid repellent- finishing and article having liquid-repellent film 有权
标题翻译：液体组合物，液体回收方法和具有液体膜的物品
公开(公告)号：JP2007291373A
公开(公告)日：2007-11-08
申请号：JP2007089445
申请日：2007-03-29
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： FURUTA SHOJI , SHIMADA SANNASHI , KANEKO KYOICHI , SUGIYAMA KAZUNORI
IPC分类号： C09K3/18 , C09D7/12 , C09D157/08 , D06M15/277
摘要： PROBLEM TO BE SOLVED: To provide a liquid repellent composition having excellent liquid repellency and durability and to provide an article having a liquid-repellent film using the liquid repellent composition. SOLUTION: The liquid repellent composition is characterized in that the composition comprises a copolymer (I) having 65-95 mass% of a constituent unit (a) äwith the proviso that the constituent unit (a) is [a 1 ]} and 1-30 mass% of a constituent unit (b) and a copolymer (II) having 25-80 mass% of the constituent unit (a) äwith the proviso that the constituent unit (a) is [a 2 ]} and 1-50 mass% of a constituent unit (c) in (10/90) to (95/5) (mass ratio) of the copolymer (I)/copolymer (II). Furthermore, the composition has [a 1 ]-[a 2 ]≥10 (mass%). COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的疏液性和耐久性的疏液性组合物，并提供使用该防液剂组合物的具有拒水性膜的制品。该防液剂组合物的特征在于，该组合物包含具有65-95质量％的构成单元（a）的共聚物（I），条件是构成单元（a）为[a 1）和构成单元（b）的1-30质量％和构成单元（a）的25〜80质量％的共聚物（II），条件是构成单元（a）为共聚物（I）/共聚物（I）的（10/90）〜（95/5）（质量比）中的构成单元（c）的1-50质量％ II）。此外，该组合物具有≥10（质量％）的[a SB SB] 2 [SB] 2 。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2004161838A Water- and oil-repellent composition and method for manufacturing copolymer 审中-公开
标题翻译：水和油组合物和制备共聚物的方法
公开(公告)号：JP2004161838A
公开(公告)日：2004-06-10
申请号：JP2002327775
申请日：2002-11-12
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： ISEMURA TSUGUHIDE , SATO TOMOKO , SUGIMOTO SHUICHIRO , SHIMADA SANNASHI , OHARU KAZUYA
IPC分类号： G01N30/26 , B01D15/08 , B01J20/286 , C08F2/00 , C08F14/06 , C08F14/08 , C08F20/18 , C08F220/24 , C09K3/18 , G01N30/34 , G01N30/74 , G01N30/88
摘要： PROBLEM TO BE SOLVED: To provide a copolymer which exhibits high water- and oil-repellent performance, contains units of a polymer of an R
f -containing monomer and units of a polymer of a fluorine-free monomer, and has a wide composition distribution, its manufacturing method, and a method for analysis of the composition distribution.
SOLUTION: The water- and oil-repellent composition comprises essentially a copolymer which contains units of a polymer of an R
f -containing (meth)acrylate monomer A and units of a polymer of a fluorine-free monomer B, and of which the composition distribution D defined by D=x
F /x
A satisfies inequality 3.0>D>1.2. The copolymer is obtained by initiating the polymerization of a monomer composition containing a monomer A (or monomer B) in a larger amount, and continuously adding thereto a monomer composition containing the other monomer B (or monomer A) in a larger amount.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：为了提供具有高拒水拒油性能的共聚物，其含有含有含单体的单体，含氟单体的聚合物单元并且具有宽的组成分布，其制造方法和分析组成分布的方法。防水防油组合物基本上包含含有含有（甲基）丙烯酸（甲基）丙烯酸酯单体A的聚合物单元的共聚物和氟的聚合物单元不饱和单体B，其中由D = x / x SB确定的组分分布D满足不等式3.0> D> 1.2。该共聚物是通过引发含有大量单体A（或单体B）的单体组合物的聚合而获得的，并且将含有其它单体B（或单体A）的单体组合物连续加入到大量中。版权所有（C）2004，JPO

4. 发明专利

JP2004250379A Fluorine-containing compound, method for producing the same, fluoropolymer and water-repellent/oil-repellent composition 审中-公开
公开(公告)号：JP2004250379A
公开(公告)日：2004-09-09
申请号：JP2003042573
申请日：2003-02-20
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： HOSHINO YASUTERU , SHIMADA SANNASHI , MAEKAWA TAKASHIGE
IPC分类号： C07C69/653 , C07C67/08 , C07C67/14 , C08F20/22 , C09K3/18 , D06M15/277
摘要： PROBLEM TO BE SOLVED: To obtain a highly polymerizable fluorine-containing compound, to provide a method for producing the same, to obtain a highly water-repellent/oil-repellent fluoropolymer composed of polymerization units based on the fluorine-containing compound, and a water repellent/oil repellent composition containing the fluoropolymer.
SOLUTION: The fluorine-containing compound is represented by the formula: CR
f1 R
f2 R
f3 -(CH
2 )
n OCOC(R
1 )=CH
2 ( R
f1 to R
f3 are each a 1-20C R
f group, or the like; R
1 is H or methyl; and (n) is 1 or 2 ). This compound is obtained by reaction between a fluoroalcohol of the formula:CR
f1 R
f2 R
f3 -(CH
2 )
n OH and a compound of the formula:CH
2 =C(R
2 )COOH or CH
2 =C(R
3 )COX.
COPYRIGHT: (C)2004,JPO&NCIPI

5. 发明专利

JP2004043402A Unsaturated fluorocompound and method for producing the same 审中-公开
公开(公告)号：JP2004043402A
公开(公告)日：2004-02-12
申请号：JP2002205608
申请日：2002-07-15
申请人： Asahi Glass Co Ltd , 旭硝子株式会社
发明人： FURUKAWA YUTAKA , SHIMADA SANNASHI , HOSHINO YASUTERU
IPC分类号： C07C67/14 , C07C69/653 , C08F14/18
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a new unsaturated fluorocompound, and to provide a method for producing the same.
SOLUTION: The unsaturated fluorocompound is represented by the formula: R
1 CY
1 HCY
2 Y
3 OQ
1 OC(O)CA
1 =CH
2 or R
2 [CZ
4 HCZ
5 Z
6 OQ
2 OC(O)CA
3 =CH
2 ]
2 ( wherein, R
1 is a monovalent fluororganic group, or the like; R
2 is a bivalent fluororganic group, or the like; Y
1 to Y
3 and Z
1 to Z
6 are each a fluorine atom; Q
1 and Q
2 are each an alkylene group, or the like; and A
1 to A
3 are each H, or the like ). The method for producing this unsaturated fluorocompound having a group:CX
1 HX
2 X
3 OQOC(O)CA=CH
2 ( wherein, X
1 to X
3 are each a fluorine atom; Q is an alkylene group, or the like; and A is H, or the like ) comprises carrying out a reaction between a compound having a group:CX
1 HX
2 X
3 OQOH and a compound of the formula:CH
2 =CYC(O)Z.
COPYRIGHT: (C)2004,JPO

6. 发明专利

JP2003246757A FLUORINE-CONTAINING DIENE COMPOUND, METHOD FOR PRODUCING THE SAME AND POLYMER 审中-公开
公开(公告)号：JP2003246757A
公开(公告)日：2003-09-02
申请号：JP2002046013
申请日：2002-02-22
申请人： ASAHI GLASS CO LTD
发明人： HOSHINO YASUTERU , MAEKAWA TAKASHIGE , FURUTA SHOJI , SHIMADA SANNASHI
IPC分类号： C07C21/19 , C07C17/25 , C08F36/16 , C09K3/18
摘要： PROBLEM TO BE SOLVED: To provide a new compound and a polymer excellent in water and oil repellency. SOLUTION: There is provided a fluorine-containing diene compound represented by R f CH=CFCH=CH 2 wherein R f denotes a 1-12C polyfluoroalkyl group and a polymer obtained from the compound. A compound represented by R f CH 2 CF 2 CH 2 CH 2 X wherein X denotes hydrogen is subjected to a de-HX reaction and a de-HF reaction in the presence of a basic compound to obtain the fluorine-containing compound. COPYRIGHT: (C)2003,JPO

7. 发明专利

JP2003221406A AQUEOUS DISPERSION 审中-公开
公开(公告)号：JP2003221406A
公开(公告)日：2003-08-05
申请号：JP2002023343
申请日：2002-01-31
申请人： ASAHI GLASS CO LTD
发明人： MAEKAWA TAKASHIGE , SHIMADA SANNASHI , SEKI TAKASHI , HOSHINO YASUTERU
IPC分类号： C08F2/24 , C08F36/04 , C08K5/00 , C09D133/06 , C09D133/16 , C09K3/18 , D06M15/21 , D06M15/256 , D06M15/263 , D06M15/277
摘要： PROBLEM TO BE SOLVED: To provide an aqueous dispersion having an excellent water and oil repellency to the surface of an article with its good durability, easy to use and is eco-friendly by reducing the used amount of organic solvents. SOLUTION: The aqueous dispersion contains a polymer (a) having a repeat unit (A) composed of straight-chain bonded four carbon atoms, having one double bond at the 2-position and bonding a polyfluoroalkyl group with an optional carbon atom and (B) a surfactant having a hydrophile-lipophile balance of ≥10. COPYRIGHT: (C)2003,JPO

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