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1. 发明专利

JPS61122201A Agent for compatting bursaphelencus lignocolus and method of preventing pine trees from withered 失效
标题翻译：用于补充白藜芦醇的药剂和从其中预防松果的方法
公开(公告)号：JPS61122201A
公开(公告)日：1986-06-10
申请号：JP24336684
申请日：1984-11-20
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： KUDAMATSU AKIO , WADA YUZURU , NISHI YASUSHI
IPC分类号： A01N25/00 , A01N27/00 , A01N37/06 , A01N57/10
摘要： PURPOSE: A combination of a chemical having activity of combatting a nematode in pine trees (Bursaphelencus lignocolus) and an attractant for the same is injected into trunks of pine trees to enables exact and advantageous control of the undesired nematode and further effective treatment for withering diseases.
CONSTITUTION: A chemical which can combat the pine-tree nematode such as organic phosphate esters, carbamates and pyrimidine derivatives is combined with an attractant for the nematode such as ppalmitoleic acid or beta-myrcene, preferably at a weight ratio of 1:0.01W10, preferably 0.02W0.5 to give the objective agent. The agent is preferably applied to pine trees by injection. The agent kills the undesired nematodes effectively to show good effect of preventing pine trees from being withered.
EFFECT: The agent has low toxicity to human and animals and causes no chemical injury to pine trees.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：将松树（Bursaphelencus lignocolus）线虫与其引诱剂相结合的化学物质的组合注入到松树树干中，以便对不期望的线虫进行准确和有利的控制，进一步有效治疗枯萎病。构成：可以对抗松树线虫如化学有机磷酸酯，氨基甲酸酯和嘧啶衍生物的化学物质与线虫的引诱剂如β-烯共聚甲酸或β-月桂烯组合，优选重量比为1：0.01-10 ，优选0.02-0.5，以得到目标试剂。该试剂优选通过注射施用于松树。该药物有效地杀死不需要的线虫，以显示出防止松树枯萎的良好效果。效果：该药对人体和动物毒性低，对松树无化学损伤。

2. 发明专利

JPS6160682A Tetrahydroquinolin-1-ylcarbonylimidazole derivative, its intermediate, its production, herbicide, agricultural and horticultural fungicide 失效
标题翻译：四氢喹啉-1-酮亚胺咪唑衍生物，其中间体，其生产，除草剂，农业和农药杀真菌剂
公开(公告)号：JPS6160682A
公开(公告)日：1986-03-28
申请号：JP17939984
申请日：1984-08-30
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： KURAHASHI YOSHIO , SHIOKAWA KOZO , GOSHIMA TOSHIO , TOSHIBE SHINZO , KAJI SHUZO , MORIYA KOUICHI , HAYAKAWA HIDENORI
IPC分类号： C07D401/06 , A01N47/38 , C07D215/08 , C07D215/12 , C07D215/16 , C07D215/18 , C07D215/20 , C07D215/26 , C07D215/28 , C07D215/36 , C07D215/48 , C07D221/10 , C07D221/16 , C07D521/00
CPC分类号： C07D231/12 , A01N47/38 , C07D215/08 , C07D215/12 , C07D215/18 , C07D215/20 , C07D215/26 , C07D215/28 , C07D215/36 , C07D215/48 , C07D221/10 , C07D221/16 , C07D233/56 , C07D249/08
摘要： NEW MATERIAL:A compound shown by the formula I [X is halogen, lower alkyl, nitro, cyano, trifluoromethyl, (halogen-substituted)lower alkoxy, (halogen- substituted)lower alkylthio, lower alkylsulfonyl, phenyl, (halogen-substituted) phenylthio, or (substituted)phenoxy; n is 1W3, X is except Cl when n is 1, and all X are not Cl when n is 2 or 3; 2X and C at the 7- and the 8-positions of tetrahydroquinoline rig in the formula may be bonded to form 5W6 ring].
EXAMPLE: 1-[7,8-Dimethyl-1(H),2,3,4-tetrahydroquinolin-1-ylcarbonyl]imidazole.
USE: A herbicide, agricultural and horticultural fungicide. having low toxicity and improved selectivity.
PREPARATION: A compound shown by the formula III is reacted with imidazole shown by the formula IV.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新材料：由式I表示的化合物[X是卤素，低级烷基，硝基，氰基，三氟甲基，（卤素取代的）低级烷氧基，（卤素取代的）低级烷硫基，低级烷基磺酰基，苯基，（卤素取代的）苯硫基或（取代的）苯氧基; n为1-3，当n为1时，除了Cl之外，当n为2或3时，X不为Cl; 2X和C在7-和8位的四氢喹啉钻机的配方中可以键合形成5-6环]。实施例：1- [7,8-二甲基-1（H），2,3,4-四氢喹啉-1-基羰基]咪唑。用途：除草剂，农业和园艺杀菌剂。毒性低，选择性好。制备：式III化合物与式IV所示的咪唑反应。

3. 发明专利

JPS59196873A 1,3,5-triazine-trione compound, its preparation, and use as coccidiostat 失效
标题翻译： 1,3,5-三嗪化合物，其制备和用作COCCIDIOSTAT
公开(公告)号：JPS59196873A
公开(公告)日：1984-11-08
申请号：JP7872084
申请日：1984-04-20
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： AKUSERU HAABAAKOON , KUME TOYOHIKO
IPC分类号： A61K31/53 , A61P33/02 , C07D251/34
CPC分类号： C07D251/34
摘要： NEW MATERIAL:A 1-{4-[4-( fluoroalkylmethyl-thio-, -sulfinyl- or sulfonyl- )phenoxy]phenyl}-1,3,5-triazine-2,4,6(1H, 3H, 5H)-trione shown by the formula I (R
f is fluoroalkyl; X and Y may be the same or different, H, lower alkyl, lower alkoxy, or halogen; R is lower alkyl; n is 0W2) or its salt.
EXAMPLE: 1{3,5-Dichloro-4-[4-( β, β, β-trifluoroethylsulfonyl )-phenoxy]-phenyl}-3- methyl-1,3,5-triazine-2,4,6-(1H, 3H, 5H)trione.
USE: Useful as a coccidiostat for men and various kinds of animal species.
PREPARATION: A urea shown by the formula II is reacted with a carbonyl isocyanate shown by the formula III (R
2 is halogen, etc.) to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：1- {4- [4-（氟烷基甲基 - 硫 - ， - 亚磺酰基 - 或磺酰基）苯氧基]苯基} -1,3,5-三嗪-2,4,6（1H，3H，5H）（R f为氟烷基; X和Y可以相同或不同，H为低级烷基，低级烷氧基或卤素; R为低级烷基; n为0-2）或其盐。实施例：1 {3,5-二氯-4- [4-（β，β，β-三氟乙基磺酰基） - 苯氧基] - 苯基} -3-甲基-1,3,5-三嗪-2,4,6- 1H，3H，5H）三酮。用途：适用于男性和各种动物物种的球虫病。制备：式II所示的脲与式III所示的羰基异氰酸酯（R 2是卤素等）反应，得到式I所示的化合物。

4. 发明专利

JPS59148707A Insecticide composition for application in water or to water surface 失效
标题翻译：用于水或水表面的杀虫剂组合物
公开(公告)号：JPS59148707A
公开(公告)日：1984-08-25
申请号：JP1975983
申请日：1983-02-10
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： IWATANI KOUJI
IPC分类号： A01N57/16
摘要： PURPOSE: To provide an insecticidal composition for applying to the water surface or in water of a paddy field, effective to the vermin of paddy rice field, such as Lissorhoptrus ocyzophilus KUSHEL, and containing a mixture of 0,0- diethyl 0-quinoxalin-2-yl phosphorothioate and a carbamate insecticide as an active component.
CONSTITUTION: The objective insecticide contains a mixture of 0,0-diethyl 0- quinoxalin-2-yl phosphorothioate and a carbamate insecticide (preferably a mixture of 1pt.wt. of the above compound to about 0.1W5pts.wt., especially about 0.5W2pts.wt. of the carbamate insecticide) as an active component. The composition is applied in the form of granules by adding an adjuvant for agricultural chemicals. The content of the active compound in the agent is preferably 1W 20wt%, especially 2W10wt%. The carbamate insecticide is e.g. 0-cumenyl methylcarbamate, etc.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：提供一种适用于稻田水稻表面或水中的杀虫组合物，对水稻田的害虫如Lissorhoptrus ocyzophilus KUSHEL有效，并含有0-二乙基O-喹喔啉 - 2-氨基硫代磷酸酯和氨基甲酸酯杀虫剂作为活性成分。构成：目标杀虫剂含有0-二乙基O-喹喔啉-2-基硫代磷酸酯和氨基甲酸酯杀虫剂（优选上述化合物1重量％的混合物至约0.1-5pts.wt。，特别是约 0.5-2pts.wt。氨基甲酸酯杀虫剂）作为活性组分。通过添加农药的佐剂将组合物以颗粒的形式施用。活性化合物在试剂中的含量优选为1-20重量％，特别是2-10重量％。氨基甲酸酯杀虫剂是例如 0-枯烯甲基氨基甲酸盐等

5. 发明专利

JPS59101453A 2,2-dichloro-3,3-dimethylcyclopropylmethyl carbamate derivative and agricultural fungicide 失效
标题翻译： 2,2-二氯-3,3-二甲基环戊基甲基碳酸酯衍生物和农业杀真菌剂
公开(公告)号：JPS59101453A
公开(公告)日：1984-06-12
申请号：JP21123982
申请日：1982-12-03
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： YAMADA YASUO , SAITOU JIYUNICHI , TOSHIBE SHINZOU , SAKAWA SHINJI
IPC分类号： A01N47/12 , C07C67/00 , C07C239/00 , C07C271/28 , C07C325/00 , C07C333/02
摘要： NEW MATERIAL:The compound of formula I (X is O or S; R
1 and R
2 are H or methyl; R
3 is H, lower alkyl or (substituted) phenyl, etc.).
EXAMPLE: 2,2-Dichloro-3,3-dimethylcyclopropylmethyl N-methyl carbamate.
USE: Agricultural fungicide. It has extremely excellent effect especially against rice blast, is low toxic to warm-blooded animals, and exhibits no phytotoxicity to the crops at an ordinary concentration for application.
PROCESS: The compound of formula I can be prepared by reacting the compound of formula II with the compound of formula III preferably in a solvent (e.g. hexane). The reaction can be carried out in the presence of an acid acceptor (e.g. TEA) under wide temperature condition, preferably at 0W100°C.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：式I化合物（X为O或S; R 1和R 2为H或甲基; R 3为H，低级烷基或（取代的）苯基等）。实施例：氨基甲酸N-甲酯2,2-二氯-3,3-二甲基环丙基甲基酯。用途：农药。特别是对稻瘟病具有极好的效果，对温血动物毒性低，对于作物的施用而言，对植物无植物毒性。方法：式I化合物可以通过使式II化合物与式III化合物优选在溶剂（例如己烷）中反应来制备。该反应可以在宽温度条件下，优选在0-100℃，在酸受体（例如TEA）的存在下进行。

6. 发明专利

JPS59101443A Substituted benzyl-cycloalkenylurea derivative, its intermediate, its preparation, and fungicide for agriculture and horticulture 失效
标题翻译：取代的苄基环烯基衍生物，其中间体，其制备和农药和杀真菌剂
公开(公告)号：JPS59101443A
公开(公告)日：1984-06-12
申请号：JP21124182
申请日：1982-12-03
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： YAMADA YASUO , SAITOU JIYUNICHI , TAMURA TATSUO , SAKAWA SHINJI
IPC分类号： A01N47/32 , C07C67/00 , C07C209/00 , C07C209/08 , C07C211/25 , C07C211/40 , C07C273/18 , C07C275/26 , C07C275/28 , C07C275/30 , C07C275/32 , C07C275/34 , C07C325/00 , C07C335/14 , C07C335/16 , C07C335/18
CPC分类号： C07C335/14 , A01N47/32 , C07C275/28 , C07C275/30 , C07C275/32 , C07C335/16 , C07C2601/10 , C07C2601/14 , C07C2601/16
摘要： NEW MATERIAL:A substituted benzyl-cycloalkenylurea derivative shown by the formula I (X is halogen atom or lower alkyl; Y is O, or S; R
1 is 5W7C cycloalkenyl; R
2 is lower alkyl, 5W8C cycloalkyl, benzyl, or phenyl which may be replaced with at least one selected from a group consisting of hydroxyl group and lower alkoxy group).
EXAMPLE: 1-(4-Bromobenzyl)-1-(2-cyclopentenyl)-3-phenylurea.
USE: Useful as a fungicide for agriculture and horticulture. Having high controlling effect especially on sheath blight of rice plant caused by Relliculariasasakii and bacterial wilt of various kinds of vegetables caused by Rhizoctonia Solani.
PROCESS: A substituted benzyl-cycloalkenyl-amine shown by the formula II obtained from a compound shown by the formula IV and a compound shown by the formula V is reacted with a compound shown by the formula III, to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：由式I表示的取代的苄基 - 环烯基脲衍生物（X是卤素原子或低级烷基; Y是O或S; R 1是5-7C环烯基; R 2是低级烷基， 8C环烷基，苄基或可以被选自羟基和低级烷氧基中的至少一种取代的苯基）。实施例：1-（4-溴苄基）-1-（2-环戊烯基）-3-苯基脲。用途：用作农业和园艺杀菌剂。具有很高的控制效果，特别是对由稻瘟菌引起的稻瘟病和由丝核菌引起的各种蔬菜的细菌性枯萎。方法：由式IV所示的化合物得到的由式II表示的取代的苄基 - 环烯基 - 胺和式Ⅴ所示化合物与式Ⅲ化合物反应，得到式一世。

7. 发明专利

JPS58192809A Herbicide 失效
标题翻译：除草剂
公开(公告)号：JPS58192809A
公开(公告)日：1983-11-10
申请号：JP7034982
申请日：1982-04-28
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： AYA MASAHIRO , YASUI KAZUTOMI , KAJI SHIYUUZOU
IPC分类号： A01N47/34 , A01N33/22 , A01N47/36
摘要： PURPOSE: A herbicide having improved safety and prolonged effect, and a wide herbicidal spectrum, containing a substituted phenylsulfonylurea derivative and 2,4-dichlorophenyl 3-methoxy-4-nitrophenyl ether as active ingredients.
CONSTITUTION: A herbicide containing a compound[e.g., N-2-biphenylylsulfonyl, N-(4-methoxy-6-methyl-pyrimidine-2-yl)urea]shown by the formula I [X is O or single bond; Y is H or Cl; R is group shown by the formula II or formula III(R
1 and R
2 are methyl or methoxy)] and a compound shown by the formula IVin a weight ratio of 1:(14W2). The herbicide shows such an excellent synergistic effect as each of the components is not expected to have, and can destroy various kinds of troublesome weeds with a small amount of application. It has low toxicity to warm-blooded animals, no phytotoxicity to cultivated plants, and effective as a soil treatment especially for weeds in paddy fields before germination, and a foliar treatment also used for soil treatment.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：具有改善安全性和延长效果的除草剂，以及含有取代苯基磺酰脲衍生物和2,4-二氯苯基3-甲氧基-4-硝基苯基醚作为活性成分的宽除草光谱。构成：式I [X是O或单键]所示的含有化合物[例如N-2-联苯基磺酰基，N-（4-甲氧基-6-甲基 - 嘧啶-2-基）脲] Y是H或Cl; R为式II或式III所示的基团（R 1和R 2为甲基或甲氧基）]和式IV所示的化合物，其重量比为1：（14-2）。除草剂显示出这样的优异的协同效果，因为每种组分都不会预期具有并且可以以少量的应用破坏各种麻烦的杂草。对温血动物毒性低，对栽培植物无植物毒性，特别是作为土壤处理，特别是萌发前稻田杂草，也用于土壤处理的叶面处理。

8. 发明专利

JPS58183688A Oxadiazole derivative, its preparation and herbicide 失效
标题翻译： OXADIAZOLE DERIVATIVE，其制备和除草剂
公开(公告)号：JPS58183688A
公开(公告)日：1983-10-26
申请号：JP6470082
申请日：1982-04-20
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： AYA MASAHIRO , SAITOU JIYUNICHI , KUME TOYOHIKO , YASUI KAZUTOMI
IPC分类号： A01N43/82 , A01N43/836 , C07D413/12
CPC分类号： C07D413/12 , A01N43/82
摘要： NEW MATERIAL:The compound of formula I (R is lower alkyl, lower alkoxy- lower alkyl, aralkyl, or aryloxyalkyl).
EXAMPLE: 3-Methyl-5-{1-[4-( 5-trifluoromethyl-2-pyridyloxy )phenoxy]ethyl}-1, 2, 4- oxadiazole.
USE: Herbicide exhibiting excellent herbicidal activity especially to gramineous weeds, and suppressing the sprouting of hardly controllable perennial gramineous weeds for a long period.
PROCESS: The objective compound of formula I can be prepared by reacting the compound of formula II (M is H or alkali metal) with the compound of formula III(X is halogen) in a solvent such as water, hexane, methanol, etc. in the presence of an acid acceptor (e.g. alkali metal hydroxide, etc.) at 0W100°C.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：新材料：式Ⅰ化合物（R为低级烷基，低级烷氧基 - 低级烷基，芳烷基或芳氧基烷基）。实施例：3-甲基-5- {1- [4-（5-三氟甲基-2-吡啶氧基）苯氧基]乙基} -1,4-恶二唑。用途：除草剂具有优异的除草活性，特别是对禾本科杂草，并且长期抑制几乎可控的多年生禾本科杂草的发芽。方法：式I的目的化合物可以通过使式II化合物（M为H或碱金属）与式III化合物（X为卤素）在溶剂如水，己烷，甲醇等中反应来制备。在0-100℃下在酸受体（例如碱金属氢氧化物等）存在下进行。

9. 发明专利

JPS5745194A Organic phosphoric ester, its preparation and insecticide, acaricide or nematocide containing the same 失效
标题翻译：有机磷酸酯，其制备和杀虫剂，含有它们的杀虫剂或杀虫剂
公开(公告)号：JPS5745194A
公开(公告)日：1982-03-13
申请号：JP11985580
申请日：1980-09-01
申请人： Nippon Tokushu Noyaku Seizo Kk
发明人： SAITOU JIYUNICHI , KUDAMATSU AKIO , SHIOKAWA KOUZOU , TSUBOI SHINICHI
IPC分类号： A01N57/14 , C07F9/18
摘要： NEW MATERIAL:Organic phosphoric esters of formula I (R, R' are 1W6C alkyl; X is halogen, 1W6C alkyl, 1W6C alkoxy; Y is halogen; m is 0W2; n is 0, 1).
EXAMPLE: O-Ethyl-S-(2-methoxycarbonyloxy)ethyl-O-2,4-dichlorophenyl phosphorothiolate.
USE: Insecticide, acaricide, nematocide: they are effective against insect pests of Mandibulate and Suctoria and of parasite on plants, but cause no injury to crops.
PREPARATION: The reaction of a compound of formula II (M is alkali metal, ammonium) with another compound of formula III (Hal is halogen) gives the compound of formula I. The reaction is conducted in a solvent such as hexane, preferably at 0W100°C.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：新材料：式I的有机磷酸酯（R，R'是1-6C烷基; X是卤素，1-6C烷基，1-6C烷氧基; Y是卤素; m是0-2; n是0,1）。实施例：O-乙基-S-（2-甲氧基羰基氧基）乙基-O-2,4-二氯苯基硫代磷酸酯。用途：杀虫剂，杀螨剂，杀线虫剂：它们有效抵抗植物上的下颌和番茄虫和寄生虫的害虫，但不会对作物造成伤害。制备：式II化合物（M为碱金属，铵）与另一种式III化合物（Hal为卤素）的反应得到式Ⅰ化合物。反应在溶剂如己烷，优选0 -100摄氏度

10. 发明专利

JPH0144163B2 失效
公开(公告)号：JPH0144163B2
公开(公告)日：1989-09-26
申请号：JP20553482
申请日：1982-11-25
申请人： NIPPON KAARITSUTO KK , NIPPON TOKUSHU NOYAKU SEIZO KK
发明人： TAKEMATSU TETSUO , TAKEUCHI YASUTOMO , AOKI AKIHIKO , NARA YASUYUKI , KURITA JUN , MORYA KOICHI
IPC分类号： A01N47/36 , A01N37/02

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