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    • 62. 发明专利
    • METHOD OF DEHYDRATING AND CONCENTRATING AQUEOUS CARRAGEENAN SOLUTION
    • JPS63196601A
    • 1988-08-15
    • JP2776387
    • 1987-02-09
    • MITSUBISHI RAYON CO
    • HOSOKAWA HIROSHIAOKI KUNIHIROMINAMI SHUNSUKE
    • C08B37/00C08B37/12
    • PURPOSE:To dehydrate and concentrate an aqueous carrageenan solution without deteriorating it with superior power consumption efficiency, by providing two cation exchange membranes between an anode and a cathode and further a hydrophilic porous membrane between these cation exchange membranes, introducing successively from the anode side an alkaline electrolyte solution, an aqueous carragenan solution, etc., and applying a voltage between the electrodes. CONSTITUTION:Two alkali-resistant and heat-resistant cation exchange membranes (e.g. perfluorocarbonsulfonic acid membranes) having a cation transference number of 0.95 or more, and an electroendosmosis constant of 20mol. H2O/F or less are provided between an anode and a cathode in an electroendosmosis apparatus or the like, and a hydrophilic microporous membrane having an average pore diameter of 50Angstrom -5mu through which carrageenan cannot permeate but water and ions can permeate is provided between the two membranes. An alkaline electrolyte solution is introduced at least into the anode side, and an aqueous carrageenan solution having a concentration of 0.01-10wt.% is introduced in between the cation exchange membrane on the anode side and the hydrophilic microporous membrane. Then, a voltage is applied between the electrodes so that the DC voltage applied to the aqueous carrageenan solution may be 1-1,000V, and water is removed from between the microporous membrane and the cation exchange membrane on the cathode side to dehydrate and concentrate the aqueous carrageenan solution.
    • 64. 发明专利
    • Carbon fiber, method for producing the same, carbon nanofiber assembly and precursor fiber
    • 碳纤维,其制造方法,碳纳米纤维集合体和前体纤维
    • JP2006152512A
    • 2006-06-15
    • JP2004348680
    • 2004-12-01
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HOSOKAWA HIROSHIFUJII YASUYUKIKOTANI TOMOYUKIKOBAYASHI TAKAYUKIMANABE TORU
    • D01F9/22C01B31/02D01F6/54
    • PROBLEM TO BE SOLVED: To provide a technique for producing a carbon nanofiber having ≤100 nm diameter in a high yield.
      SOLUTION: The carbon fiber comprising a carbon nanofiber having ≤100 nm diameter amounting to ≥10% by mass based on the total of the carbon fiber is obtained by firing a precursor fiber in which an island-like independent phase is dotted in a cross section perpendicular to a fiber axis direction in a matrix phase, the island-like independent phase has a phase separation structure forming a streak-like phase in the fiber axis direction, the main component of the matrix phase is composed of a thermally decomposable polymer containing 5-70% by mass of an inorganic fine particle and/or heat-resistant polymer and the main component of the island-like independent phase is composed of a polymer to be carbonized by heating. The carbon nanofiber assembly is obtained by grinding the carbon fiber.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供以高产率制造直径≤100nm的碳纳米纤维的技术。 解决方案:通过烧结其中岛状独立相点缀的前体纤维,可以获得包含相对于碳纤维总量为≥10质量%的具有≤100nm直径的碳纳米纤维的碳纤维 在矩阵相位中垂直于纤维轴方向的横截面,岛状独立相具有在纤维轴方向上形成条纹状相的相分离结构,基质相的主要成分由热分解 含有5-70质量%无机细颗粒和/或耐热聚合物的聚合物和岛状独立相的主要成分由通过加热碳化的聚合物组成。 通过研磨碳纤维获得碳纳米纤维组件。 版权所有(C)2006,JPO&NCIPI
    • 66. 发明专利
    • Carbon fiber, carbon nanofiber obtained from the same and method of production for carbon fiber and precursor fiber for the same
    • 碳纤维,从其获得的碳纳米纤维和碳纤维的生产方法及其相同的前身纤维
    • JP2003336130A
    • 2003-11-28
    • JP2002186613
    • 2002-06-26
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HOSOKAWA HIROSHIMANABE TORUKOSHIRAI ATSUNORIFUJII YASUYUKI
    • C01B31/02D01F6/54D01F9/22
    • PROBLEM TO BE SOLVED: To provide carbon fibers comprising aggregates of filament carbon nanofibers and carbon nanofibers obtained from the carbon fibers and to provide a technology producing the aggregates with high quality and high yield in an industrial scale.
      SOLUTION: The carbon fibers comprise the aggregates of filament carbon nanofibers and carbon nanofibers are obtained by grinding the same. The precursor fibers for the carbon fibers that are fibers of blended polymers and the morphology of the fiber has a stream-like phase separation structures along the fiber axis and the vertical section of the fiber axis has a phase separation structure in which island like isolated phases are scattered in a matrix phase, and the matrix phase polymer comprises a thermally decomposable polymer and the island like isolated phase mainly comprises a polyacrylonitrile based polymer.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供碳纤维,其包含由碳纤维获得的长丝碳纳米纤维和碳纳米纤维的聚集体,并且以工业规模提供以高质量和高产率生产聚集体的技术。 解决方案:碳纤维包括长丝碳纳米纤维的聚集体,并且通过研磨碳纳米纤维来获得碳纳米纤维。 作为共混聚合物的纤维的碳纤维的前体纤维和纤维的形态具有沿着纤维轴线的流状相分离结构,并且纤维轴的垂直截面具有相分离结构,其中岛状分离相 分散在基质相中,基质相聚合物包含可热分解的聚合物,岛状分离相主要包含聚丙烯腈基聚合物。 版权所有(C)2004,JPO
    • 68. 发明专利
    • ANTIMICROBIAL TEXTILE PRODUCT
    • JP2000314035A
    • 2000-11-14
    • JP12302299
    • 1999-04-28
    • MITSUBISHI RAYON CO
    • TAKEUCHI SATORUKODERA YOSHINOBUHOSOKAWA HIROSHIKUWAKI HIDEO
    • D06M15/03D01F6/18D01F11/06D06M101/00D06M101/16D06M101/18D06M101/28
    • PROBLEM TO BE SOLVED: To obtain an antimicrobial textile product capable of avoiding deterioration of antimicrobial and deodorizing properties due to various treatments received by the textile product under use environments, excellent in degree of whiteness and color developing clarity and useful for clothes, etc., by including acrylic fibers containing a prescribed amount of a nonelutable antimicrobial agent in a specific mixing ratio. SOLUTION: This antimicrobial textile product comprises acrylic fibers containing 0.05-2.0 wt.% of a nonelutable antimocrobial agent such as a natural antimicrobial agent, e.g. chitosan which is basic polysaccharides prepared by removing calcium carbonate and proteins from a chitinous material forming the outer skeleton of crustaceans such as a crab or a lobster or a shrimp, heating the resultant chitin with a concentrated alkali and deacetylating the chitin in 20-60 wt.% mixing ratio. Furthermore, the bacteriostatic activity value of the antimicrobial textile product is >=2.2. A method for including an acidic aqueous solution of chitosan in a washed yarn prepared by washing a solvent contained in a coagulated yarn in a wet production process for the acrylic fibers, then neutralizing the resultant yarn and washing the chitosan is preferred as the method for including the nonelutable antimicrobial agent.