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    • 19. 发明专利
    • CLEANING METHOD OF SEMICONDUCTOR
    • JP2000269177A
    • 2000-09-29
    • JP7474999
    • 1999-03-19
    • MATSUSHITA ELECTRIC IND CO LTD
    • HARADA YOSHIHISANIWA MASAAKI
    • B08B3/08H01L21/304
    • PROBLEM TO BE SOLVED: To reduce iron concentration and carbon contamination of a substance surface and thereby to improve reliability, in SC-1 cleaning used for cleaning of a semiconductor substrate. SOLUTION: This method comprises a process of cleaning the surface of a semiconductor substrate by a semiconductor surface treating agent, of which the constituents are alkali, hydrogen peroxide and water and a process of rinsing the surface of the semiconductor substrate with ultrapure water after the cleaning, and a cleaning chemical to which a complexing agent containing one or more phosphonic acid group or salts thereof in the molecule is added in the range of 2.1E-5 to 4.2E-5 wt.% is used for at least one of the semiconductor surface treating agent and the ultrapure water for rinsing. According to this constitution, an improvement in reliability can be expected from the effect of removal of iron by the complexing agent, and moreover, lowering of the reliability due to carbon contamination is lessened. Therefore a cumulative fraction defective is made small, and improvement in the reliability can be realized in particular. Furthermore, reliability is improved, with regard to other chemicals and complexing agents, by providing the concentration of the complexing agent to be set within the range of 0.9-1.8 times that at the saturation temperature thereof.
    • 20. 发明专利
    • SURFACE TREATMENT METHOD FOR SILICON
    • JPH11224872A
    • 1999-08-17
    • JP2337998
    • 1998-02-04
    • MATSUSHITA ELECTRIC IND CO LTD
    • HARADA YOSHIHISA
    • H01L21/302H01L21/304H01L21/3065
    • PROBLEM TO BE SOLVED: To surely and efficiently form a clean surface of silicon. SOLUTION: A silicon clean surface is formed by vacuum heating a silicon substrate 5, where an oxidized film 4 provided with a film thickness of 1 nm or larger and 2 nm or smaller is present on the surface. Since the silicon clean surface is formed by vacuum heating the silicon substrate 5, where the oxidized film 4 provided with a film thickness of 1 nm or lager is present on the surface, the physical or chemical bonding to an active silicon surface and carbon in gas is restrained and carbon 3 is almost all removed. Also since the time required for reaction for sublimating the oxidized film 4 increases along with the increase of an oxidized film thickness, when the oxidized film 4 become thick, it takes more than the required time for oxidized film removal reaction in a vacuum and becomes inefficient. However, since the film thickness of the oxidized film 4 is set to be 1 nm or larger and 2 nm or smaller, the carbon is sufficiently removed and processing time is shortened. Thus, a clean silicon surface for not generating Si-C bonding is formed surely and efficiently.