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    • 1. 发明专利
    • Coating method, and coated object prepared by above method
    • 涂层方法和上述方法制备的涂层物体
    • JP2009034667A
    • 2009-02-19
    • JP2008175087
    • 2008-07-03
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TATE KAZUYUKINARITA TAKESHIKODAMA SATOSHIKUWANO KAZUYUKI
    • B05D1/36
    • PROBLEM TO BE SOLVED: To provide a coating method by which a laminated coating film can be obtained with its uppermost layer having a surface of slight unevenness even if at least the uppermost layer is cured by baking for the purpose of obtaining high durability thereof after laminating two or more species of paint by a wet-on-wet method. SOLUTION: The coating method for forming a laminated coating film comprising at least a lower layer and an uppermost layer formed on a substrate includes: a step of preparing thermally uncurable paint as at least a species of paint for forming the lower layer(s), and further preparing thermosetting paint for forming the uppermost layer; a step of forming an uncured laminated coating film by laminating the paint for the lower layer and the paint for the uppermost layer on the substrate using a wet-on-wet method; and a step of subjecting the uncured laminated coating film to a heat treatment at least to cure the paint for the uppermost layer. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了获得具有轻微不均匀性的表面的最上层,即使至少最上层通过烘烤固化以获得高耐久性,也可以获得层压涂膜的涂布方法 在通过湿法湿式方法层压两种或更多种涂料之后。 < P>解决方案:形成层叠涂膜的涂布方法至少包括形成在基材上的下层和最上层包括:制备至少一种用于形成下层的涂料的热不稳定涂料的步骤( 并进一步制备用于形成最上层的热固性涂料; 通过使用湿法湿法在基板上层压下层涂料和最上层涂料来形成未固化的层压涂膜的步骤; 以及对未固化的层叠涂膜进行热处理至少使第一层的涂料固化的工序。 版权所有(C)2009,JPO&INPIT
    • 2. 发明专利
    • Painting method and coated body obtained thereby
    • 绘画方法和涂层身体
    • JP2010036095A
    • 2010-02-18
    • JP2008201170
    • 2008-08-04
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • YOMO SHUJITATE KAZUYUKIKUWANO KAZUYUKIKODAMA SATOSHI
    • B05D1/36B32B27/00
    • PROBLEM TO BE SOLVED: To provide a coating method capable of obtaining a laminated coating film whose uppermost layer surface has scarce irregularities and excellent in adhesion to a base material even if three or more kinds of paints are laminated in a wet-on-wet condition and are baked.
      SOLUTION: The painting method that forms the laminated coating film having the lowermost layer formed on the base material, an intermediate layer of one or more layers formed on the lowermost layer, and the uppermost layer formed on the intermediate layer includes steps of preparing a thermosetting coating material as the lowermost layer coating material to form the lowermost layer, preparing a non-thermosetting coating material that never causes a hardening reaction by heat-treatment at least as one kind of the intermediate coating materials to form the intermediate layer, and preparing a thermosetting coating material as the uppermost layer coating material to form the uppermost layer, a step of forming unhardened laminated coating film by laminating the lowermost, intermediate, and uppermost layer coating materials on the base material in a wet-on-wet condition, and a step of hardening the lowermost and uppermost layer coating materials by performing heat-treatment of the unhardened laminated coating film.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:为了提供一种能够获得层压涂膜的涂布方法,即使将三层以上的涂料层叠在一起,也可以得到层压涂膜,其最上层表面具有稀少的不规则性和对基材的粘合性优异 - 烘烤条件,并烘烤。 < P>解决方案:形成具有形成在基材上的最下层的层压涂膜,最下层形成的一层或多层的中间层和形成在中间层上的最上层的涂布方法包括以下步骤: 制备作为最下层涂层材料的热固性涂层材料以形成最下层,制备不经由至少一种中间涂层材料热处理形成中间层的硬化反应的非热固性涂层材料, 并制备作为最上层涂层材料的热固性涂层材料以形成最上层;通过在湿润湿条件下将最低层,中间层和最上层涂层材料层叠在基材上形成未硬化层压涂膜的步骤 以及通过对未硬化物进行热处理来硬化最下层和最上层涂层材料的步骤 ned层压涂膜。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Coating method and coated article obtained by this method
    • 这种方法获得的涂料方法和涂层物品
    • JP2009208017A
    • 2009-09-17
    • JP2008054675
    • 2008-03-05
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TATE KAZUYUKIMORI KANJINARITA TAKESHINISHIMURA AKIRAKUWANO KAZUYUKIKODAMA SATOSHI
    • B05D1/36B05D7/24
    • PROBLEM TO BE SOLVED: To provide a coating method which can surely obtain a laminated coat almost free from an unevenness in the surface of a top layer, even at least in a case of curing the top layer in order to secure high durability by laminating at least two coating materials in the wet-on-wet coating method, and to provide a coated article with excellent appearance quality obtained by the method. SOLUTION: This coating method is to form a laminated coat with at least, one lower layer formed on a base material and a top layer formed on the lower layer. In this method, the following processes are performed: (1) a process to prepare a curable coating material which forms a crosslinked structure through a chemical reaction, as a coating material for the top layer to form the top layer, and also, a coating material whose relative loss elastic modulus when starting gelation of the coating material for the top layer, is not more than 1s- 2 , as at least one of other coating materials for the lower layer to form the lower layer; (2) a process to form an uncured laminated coat by laminating the coating material for the lower layer and the coating material for the top layer in wet-on-wet coating manner; and (3) a process to cure at least, the coating material for the top layer by applying a curing treatment to the uncured laminated coat. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供一种能够确实获得顶层表面几乎没有凹凸的层叠涂层的涂布方法,即使至少在固化顶层的情况下,为了确保高耐久性 通过在湿式湿式涂布方法中层叠至少两种涂料,并提供通过该方法获得的具有优异外观质量的涂布制品。 解决方案:该涂布方法是形成层叠涂层,其中至少一个下层形成在基材上,顶层形成在下层上。 在该方法中,进行以下处理:(1)通过化学反应制备形成交联结构的可固化涂层材料的方法,作为用于顶层的涂层材料以形成顶层,以及涂层 作为用于顶层的涂层材料的起始凝胶化时的相对损耗弹性模量的材料不超过1s-SP2,作为用于形成下层的其它涂层材料中的至少一种 ; (2)通过以湿式湿式涂布方式层压下层用涂料和上层涂料,形成未固化层压涂层的方法; 和(3)通过对未固化的层压涂层进行固化处理,至少固化顶层的涂层材料的方法。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Coating method, and coated object prepared by the same
    • 涂料方法及其制备的涂料物品
    • JP2009034668A
    • 2009-02-19
    • JP2008175088
    • 2008-07-03
    • Toyota Central R&D Labs IncToyota Motor Corpトヨタ自動車株式会社株式会社豊田中央研究所
    • TATE KAZUYUKINARITA TAKESHIKODAMA SATOSHIKUWANO KAZUYUKI
    • B05D1/36
    • PROBLEM TO BE SOLVED: To provide a coating method by which a laminated coating film can be obtained with its uppermost layer having a surface of slight unevenness even if the uppermost layer and one or more of lower layer(s) are cured by baking after laminating two or more species of paint by a wet-on-wet method. SOLUTION: The coating method for forming a laminated coating film comprising at least a lower layer and an uppermost layer formed on a substrate includes: a step of preparing, as paint for forming the uppermost layer, thermosetting paint that has a curing temperature T T of ≥40°C and ≤200°C and does not generate a volatile matter upon being subjected to a heat treatment, and further preparing thermosetting paint for the lower layer, which has a curing temperature T U satisfying the following equation (1): T U ≤T T -30 (wherein T U is a curing temperature [°C] of the paint for the lower layer, and T T is a curing temperature [°C] of the paint for the uppermost layer) as at least one of the paint for forming the lower layer; a step of forming an uncured laminated coating film by laminating the paint for the lower layer and the paint for the uppermost layer on the substrate using a wet-on-wet method; a step of setting T L (a temperature [°C] for lower-temperature heating) and T H (a temperature [°C] for higher-temperature heating) so that T L and T H are each within respective specific temperature ranges; and a step of subjecting the uncured laminated film to a heat treatment at the temperature T L and at least curing the paint for the lower layer to form a laminated coating film where the paint for the uppermost layer is uncured, and further subjecting the resulting uncured laminated coating film where the uppermost layer is uncured to a heat treatment at the temperature T H to cure the paint for the uppermost layer. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种涂覆方法,其中即使最上层和一个或多个下层被固化,也可以通过其最下层和一个或多个下层被固化而形成具有轻微不均匀表面的最上层的层压涂膜 通过湿法湿法层压两种或更多种油漆后进行烘烤。 < P>解决方案:形成层叠涂膜的涂布方法至少包括形成在基材上的下层和最上层包括:制备作为形成最上层的涂料的热固性涂料,其具有固化温度 T T 为≥40℃,≤200℃,经受热处理后不产生挥发性物质,并进一步制备下层的热固性涂料,其具有固化温度T 满足以下等式(1)的 U :其中T U 是 用于下层的涂料的固化温度[℃],T T 是最上层涂料的固化温度[℃]),至少一种用于形成 下层 通过使用湿法湿法在基板上层压下层涂料和最上层涂料来形成未固化的层压涂膜的步骤; 设定T L (较低温度加热的温度[℃])和T H (高温加热的温度[℃])的步骤如此 该T L 和T H 分别在各自的特定温度范围内; 以及将未固化的层压膜在温度T L 下进行热处理的步骤,并且至少固化下层的涂料以形成层压涂膜,其中最上层的涂料未固化 并且进一步对所得到的未固化最上层的未固化层压涂膜进行在温度T H 下的热处理,以固化最上层的涂料。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Coating evaluation method
    • 涂料评价方法
    • JP2006061800A
    • 2006-03-09
    • JP2004246027
    • 2004-08-26
    • Daihatsu Motor Co LtdKansai Paint Co LtdToyota Motor Corpダイハツ工業株式会社トヨタ自動車株式会社関西ペイント株式会社
    • TANAHASHI AKIRAWAKUTA MITSUHIROKODAMA SATOSHIHIRAMATSU YASUHIROKADOWAKI KOJIROENDO MITSUGI
    • B05D3/00B05D1/36B05D7/14B05D7/24G01N5/00G01N17/00G01N33/32
    • PROBLEM TO BE SOLVED: To provide a coating evaluation method, even if a member coated with a first water-based coating in the wetting state is coated with a second water-based coating, capable of preventing generation of a mixing layer between these and ensuring good finishing.
      SOLUTION: In the coating method of the 3-coat 1-bake system, an intermediate coating step is managed by evaluating the quality of coating of an intermediate water-based coating by a water elution ratio calculated by the following method: (1) the intermediate water-based coating is film-formed to form a first coating film and a weight W1 after primary heating is measured; (2) the first coating film after primary heating is secondarily heated and a weight W2 is measured; (3) the intermediate water-based coating is film-formed to form a second coating film and after primary heating, a weight W3 is measured; (4) the second coating film after primary heating is immersed in water and is secondarily heated and a weight W4 is measured; (5) a solid content weight is calculated by WS=W3×W2/W1; (6) a water elution weight is calculated by WP=W3×W2/W1-W4; and (7) a water elution ratio is calculated by WP/WS×100(%).
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供涂层评价方法,即使涂覆有处于润湿状态的第一水性涂层的部件涂覆有第二水性涂料,能够防止在第二水性涂料之间产生混合层 这些并确保良好的整理。 解决方案:在3层1-烘烤系统的涂布方法中,通过以下方法计算的水洗脱比率评价中间水性涂料的涂布质量来管理中间涂布步骤:( 1)中间水性涂料成膜以形成第一涂膜,并测量一次加热后的重量W1; (2)一次加热后的第一涂膜二次加热,测定重量W2; (3)中间水性涂料成膜形成第二涂膜,一次加热后,测定重量W3; (4)将一次加热后的第二涂膜浸入水中,二次加热,测定重量W4; (5)通过WS = W3×W2 / W1计算固体成分重量; (6)通过WP = W3×W2 / W1-W4计算水洗重量; 和(7)通过WP / WS×100(%)计算水洗脱比。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Electrodeposition method using lead-free cation electrodeposition coating material
    • 使用无铅电沉积涂料的电沉积方法
    • JP2003277682A
    • 2003-10-02
    • JP2002086381
    • 2002-03-26
    • Nippon Paint Co LtdToyota Motor Corpトヨタ自動車株式会社日本ペイント株式会社
    • UCHITOI SATORUKOJIMA YOSHIOYAMADA MITSUOYOKOI SEIJIKODAMA SATOSHI
    • C09D163/00C09D5/44C09D163/02C09D163/04C09D175/04C25D13/06C25D13/22
    • C09D5/4473C25D13/22
    • PROBLEM TO BE SOLVED: To provide an electrodeposition method using a lead-free cation electrodeposition coating material not forming pinholes and craters in the coating film even when using a zinc steel plate as the material to be coated, excellent in economical efficiency because of a small amount of the electrodeposition coating material used, having slight influence on the environment, enabling short-time electrodeposition.
      SOLUTION: The electrodeposition is carried out at a temperature lower by ≤2°C than the lowest film-forming temperature of the coating film and higher by ≤6°C than the lowest film-forming temperature by using the lead-free cation electrodeposition coating material composition comprising a sulfonium- modified epoxy resin as a binder resin, an amino-modified novolak epoxy resin and a blocked isocyanate curing agent, having ≤1 wt.% volatile organic content and 1,000-2,500 μS/cm coating liquid electric conductivity and 20-35°C lowest film-forming temperature of the coating film electrodeposited to the material to be coated.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:即使在使用锌钢板作为被覆材料的情况下,也可以使用在涂膜中不形成针孔和凹坑的无铅阳离子电沉积涂料的电沉积法,经济效率优异,因为 的少量电沉积涂料,对环境有轻微的影响,能够进行短时间的电沉积。

      解决方案:电沉积在比涂膜的最低成膜温度低2℃的温度下进行,并且比最低成膜温度高不超过6℃ 阳离子电沉积涂料组合物,其包含锍改性环氧树脂作为粘合剂树脂,氨基改性酚醛清漆环氧树脂和封端异氰酸酯固化剂,具有≤1wt%挥发性有机物含量和1,000-2,500μS/ cm涂布液体电 电导率和20-35℃最低成膜温度的涂膜电沉积到待涂覆的材料上。 版权所有(C)2004,JPO