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1. 发明专利

JP2008208205A Coating composition, coated article and automobile exterior plate 审中-公开
标题翻译：涂料组合物，涂层物品和汽车外墙板
公开(公告)号：JP2008208205A
公开(公告)日：2008-09-11
申请号：JP2007045632
申请日：2007-02-26
申请人： Mitsubishi Rayon Co Ltd , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱レイヨン株式会社
发明人： HAYAMA YASUSHI , FUJIMOTO JUICHI , YAJIMA SHIGE , KATO YOSHITAMA , KODAMA SATOSHI , NARITA YOSHINORI
IPC分类号： C09D4/00 , C08F290/06 , C08G18/10 , C08L33/14 , C09D133/00 , C09D175/04 , C09D175/14
摘要： PROBLEM TO BE SOLVED: To provide a coating composition capable of forming a cured film excellent in abrasion resistance and also excellent in scratch resistance, and useful for a coated article such as an automobile exterior plate, etc.
SOLUTION: This coating composition contains (A) a compound obtained by reacting (a1) a compound having 3 isocyanate groups in one molecule with (a2) a compound having one hydroxy group and ≥1 (meth)acryloyl group by a ratio of (the total number of hydroxy groups)/(the total number of isocyanate groups)
摘要翻译：要解决的问题：提供能够形成耐磨性优异并且耐刮擦性优异的固化膜的涂料组合物，并且可用于汽车外板等涂布制品。解决方案：该涂料组合物含有（A）通过使（a1）在一个分子中具有3个异氰酸酯基的化合物与（a2）具有一个羟基的化合物和≥1（甲基）丙烯酰基的化合物（（总数）的羟基）/（异氰酸酯基的总数）<1，（B）具有-50〜0℃玻璃化转变点和50〜350mgKOH / g羟值的丙烯酸共聚物，（C）自由基聚合引发剂，并且还提供具有这种固化膜的涂覆制品和由这种涂覆制品组成的汽车外部主体面板。版权所有（C）2008，JPO＆INPIT

2. 发明专利

JP2014237812A 活性エネルギー線硬化性組成物、積層体、及び偏光板审中-公开
标题翻译：活性能量可固化组合物，层压板和极化板
公开(公告)号：JP2014237812A
公开(公告)日：2014-12-18
申请号：JP2014091458
申请日：2014-04-25
申请人：三菱レイヨン株式会社 , Mitsubishi Rayon Co Ltd
发明人： TAJIMA YOSHIMI , HAYAMA YASUSHI , SATO AKIRA
IPC分类号： C09J4/00 , C08F2/44 , C08G18/62 , C08G59/32 , C09J4/02 , C09J11/06 , C09J157/10 , G02B5/30
摘要：【課題】接着剤として取扱いし易い適度な粘度を有しており、プラスチックフィルム、特にPVAフィルムとの接着性に優れる活性エネルギー線硬化性組成物、及び優れた耐熱性を有する偏光板等の積層体を提供する。【解決手段】重量平均分子量が2,000〜50,000であるエポキシ基含有ビニル系重合体(A)及びビニル系単量体(B)を含み、前記重合体(A)及び前記単量体(B)の合計に対して、前記重合体(A)の含有量が5〜60質量%、前記単量体(B)の含有量が40〜95質量%である活性エネルギー線硬化性組成物、前記組成物を硬化して得られた接着層を有する積層体、並びに、保護フィルム、前記組成物を硬化して得られた接着層及び偏光子フィルムがこの順に連続して積層した構造を含む偏光板。【選択図】なし
摘要翻译：要解决的问题：提供具有适当粘度的活性能量射线固化性组合物，以便容易地作为粘合剂处理，并且对塑料膜，特别是PVA膜的粘附性优异，并且提供层压体如偏振片具有优异的耐热性。溶液：提供含有重均分子量为2,000〜50,000的含环氧基的乙烯基系聚合物（A）和乙烯基类单体（B）的活性能量射线固化性组合物相对于聚合物（A）和单体（B）的合计，聚合物（A）的含量为5〜60质量％，单体（B）的含量为40〜95质量％的量。还提供：具有通过固化该组合物获得的粘合剂层的层压体; 并且具有这样的结构的偏振片，其中保护膜和通过固化该组合物获得的粘合剂层和偏振膜依次层叠。

3. 发明专利

JP2009173769A Curable resin composition, optical member, and layered material 有权
标题翻译：可固化树脂组合物，光学成员和层状材料
公开(公告)号：JP2009173769A
公开(公告)日：2009-08-06
申请号：JP2008013807
申请日：2008-01-24
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： HAYAMA YASUSHI , TERADA KOJI
IPC分类号： C08F2/44 , C08F2/50 , C09J4/00
摘要： PROBLEM TO BE SOLVED: To provide a curable resin composition rapidly cured by an active energy ray and having excellent adhesiveness to a glass base material or a plastic base material, especially a plastic base material having a functional layer and a print layer.
SOLUTION: The curable resin composition contains a vinyl polymer (A) obtained by polymerizing at least a carboxyl group containing vinyl monomer (a1) and an epoxy group containing vinyl monomer (a2) and an alkane diol di(meth)acrylate (B).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决的问题：提供一种通过活性能量射线快速固化并对玻璃基材或塑料基材，特别是具有功能层和印刷层的塑料基材具有优异粘合性的固化性树脂组合物。解决方案：固化性树脂组合物含有通过使至少含有羧基的乙烯基单体（a1）和含有乙烯基单体（a2）的环氧基和二烷基二（甲基）丙烯酸烷基酯（A）聚合而获得的乙烯基聚合物（A） B）。版权所有（C）2009，JPO＆INPIT

4. 发明专利

JP2008088382A Curable composition, its cured product and optical information medium 审中-公开
标题翻译：可固化组合物，固化产品和光学信息介质
公开(公告)号：JP2008088382A
公开(公告)日：2008-04-17
申请号：JP2006273943
申请日：2006-10-05
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： FUJIMOTO JUICHI , SENDA KAZUMI , NURISHI SEIJI , HAYAMA YASUSHI
IPC分类号： C08F290/06 , G11B7/24 , G11B7/254 , G11B7/257
摘要： PROBLEM TO BE SOLVED: To provide a curable composition suitable for a light transmission layer that produces little warpage changes to temperature changes and humidity changes and excels in light resistance. SOLUTION: The curable composition contains a urethane (meth)acrylate (A), a (meth)acrylate (B) represented by general formula (1) and a (meth)acrylate (C) represented by general formula (2): CH 2 =CR 4 COO(C β H 2β )OCOCR 4 =CH 2 . In general formula (1), R 1 indicates a hydrogen atom or a methyl group; R 2 a direct bond, a 1-8C alkylene group or a polyalkyleneoxy group; R 3 a 1-20C organic group; and α an integer of 1-11. In general formula (2), R 4 s each indicates a hydrogen atom or a methyl group and β indicates an integer of 2-16. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供适用于对温度变化和湿度变化几乎没有弯曲变化并且耐光性优异的透光层的可固化组合物。解决方案：可固化组合物含有氨基甲酸酯（甲基）丙烯酸酯（A），由通式（1）表示的（甲基）丙烯酸酯（B）和通式（2）表示的（甲基）丙烯酸酯（C）：CH 2 = CR 4 COO（C β H 2β）OCOCR 4 = CH 2 。在通式（1）中，R“SP”表示氢原子或甲基; 直接键合，1-8C亚烷基或聚亚烷基氧基; 1〜20C有机基团; α为1-11的整数。在通式（2）中，R 4各自表示氢原子或甲基，β表示2〜16的整数。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2007084598A Coating composition for amorphous polyolefin substrate, and amorphous polyolefin film or sheet having cured film of the same 有权
标题翻译：无定形聚烯烃基材的涂料组合物和其固化膜的非晶聚合物薄膜或薄片
公开(公告)号：JP2007084598A
公开(公告)日：2007-04-05
申请号：JP2005271649
申请日：2005-09-20
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： HAYAMA YASUSHI , FUJIMOTO JUICHI
IPC分类号： C09D4/02 , C08F290/14 , C09D7/12 , C09D175/14
摘要： PROBLEM TO BE SOLVED: To provide a coating composition excellent in close adhesion to an amorphous polyolefin substrate and also capable of obtaining a cured film excellent in surface hardness, scratch resistance and wear resistance, and an amorphous polyolefin film or sheet having such the cured film.
SOLUTION: This coating composition for the amorphous polyolefin substrate consists of 5-50 pts.mass urethane(meth)acrylate A obtained by reacting a polydiene polyol having ≥2 hydroxy groups in one molecule, an organic polyisocyanate and a compound having ≥1 hydroxy and ≥1 polymerizable unsaturated double bond in one molecule, 5-50 pts.mass organic material-covered inorganic fine particles and 20-90 pts.mass compound other than the component A, having ≥2 polymerizable unsaturated double bonds in one molecule (the total of 3 components is 100 pts.mass), a photopolymerization initiator and solvent. The amorphous polyolefin film or sheet having the cured film of the coating composition is also provided.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种与非晶聚烯烃基材的密合性优异的涂料组合物，并且还能够获得表面硬度，耐擦伤性和耐磨性优异的固化膜，以及具有这样的非晶形聚烯烃膜或片固化膜。解决方案：该无定形聚烯烃基材用涂料组合物由一分子中具有≥2个羟基的聚二烯多元醇，有机多异氰酸酯和具有≥2个羟基的化合物得到的5-50重量份氨基甲酸酯（甲基）丙烯酸酯A 1分子中的1个羟基和≥1个可聚合不饱和双键，5-50个有机材料覆盖的无机细颗粒和除了组分A之外的20-90个聚合物，在一个分子中具有≥2个可聚合不饱和双键（共3种成分为100pts.mass），光聚合引发剂和溶剂。还提供了具有涂料组合物的固化膜的无定形聚烯烃膜或片。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2004035715A Composition curable with active energy rays, for optical disc, and optical disc 审中-公开
公开(公告)号：JP2004035715A
公开(公告)日：2004-02-05
申请号：JP2002194739
申请日：2002-07-03
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： FUJIMOTO JUICHI , HAYAMA YASUSHI
IPC分类号： C08F290/06 , G11B7/24 , G11B7/254 , G11B7/257
摘要： PROBLEM TO BE SOLVED: To obtain a low-viscosity composition curable with active energy rays, capable of forming a cured material layer having excellent transparencey, a low cure shrinkage, excellent light transmittance, and an excellent ability to protect a recording film. SOLUTION: The composition contains a urethane (meth)acrylate compound (A) obtained by reacting (a1) an epoxy di(meth)acrylate compound, (a2) at least one diol compound selected from polyether diol compounds, polyester diol compounds, and polycarbonate diol compounds, (a3) a diisocyanate compound, and (a4) a hydroxylated (meth)acrylate, an ethylenically unsaturated compound (B) other than the compound (A), and a photopolymerization initiator (C). COPYRIGHT: (C)2004,JPO

7. 发明专利

JP2010275339A Curable composition and article 有权
标题翻译：可固化组合物和物品
公开(公告)号：JP2010275339A
公开(公告)日：2010-12-09
申请号：JP2009126267
申请日：2009-05-26
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： HAYAMA YASUSHI
IPC分类号： C08F299/00 , B32B27/16 , B32B27/40 , C08G18/48 , C08G18/58 , C08J7/04
摘要： PROBLEM TO BE SOLVED: To provide a curable composition giving a cured article excellent in surface hardness and moldability, and a film or a sheet having a cured coating of the curable composition. SOLUTION: The active energy ray curable composition includes a polyurethane compound (A) obtained by reacting the following components (a1) to (a3), an ethylenically unsaturated compound (B) other than the compound (A), and a photopolymerization initiator (C): (a1) an epoxy (meth)acrylate having 2 hydroxyl groups in the molecule, which is synthesized from a diepoxy compound having a cyclic skeleton in the molecule, and a (meth)acrylic acid derivative; (a2) a compound other than the component (a1) having 2 hydroxyl groups in the molecule and a molecular weight of 50-500; (a3) a diisocyanate compound. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供赋予表面硬度和成型性优异的固化物的固化性组合物，以及具有可固化组合物的固化涂层的膜或片。活性能量射线固化性组合物包含通过使以下组分（a1）至（a3），除化合物（A）以外的烯属不饱和化合物（B）和光聚合反应获得的聚氨酯化合物（A）引发剂（C）：（a1）在分子中由具有环状骨架的二环氧化合物合成的分子内具有2个羟基的环氧（甲基）丙烯酸酯和（甲基）丙烯酸衍生物; （a2）分子内具有2个羟基的成分（a1）以外的化合物，分子量为50〜500; （a3）二异氰酸酯化合物。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2009155374A Curable composition, composite, transfer sheet, and manufacturing method therefor 审中-公开
标题翻译：可固化组合物，复合材料，转印片及其制造方法
公开(公告)号：JP2009155374A
公开(公告)日：2009-07-16
申请号：JP2007332047
申请日：2007-12-25
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： MOMOSE FUMINO , SAITO TAKASHI , HAYAMA YASUSHI
IPC分类号： C08F299/06 , B32B27/40 , C08G18/67 , C08G59/17 , C09D4/00 , C09D5/24 , C09D7/12 , C09D175/14
摘要： PROBLEM TO BE SOLVED: To provide a curable composition dispersable in various solvent such as an organic solvent and a water-containing organic solvent, without impairing characteristics of a carbon nano tube itself, capable of preventing the carbon nano tube from being separated or aggregated even for a long period of storage, excellent in electric conductivity, film forming performance and moldability, applicable or coatable onto the base material by a simple method, capable of obtaining a cured film of high transparency, and excellent in scratch resistance, water-proofness, weatherability, adhesiveness onto a base material, mechanical strength, heat conductivity and hardness, a composite or a transfer sheet having a coating film or cured film comprising it, and a manufacturing method therefor. SOLUTION: This curable composition contains the carbon nano tube a, an urethane compound of a reaction product of an epoxy (meth)acrylate b-1 having at least one hydroxyl group in a molecule, and an isocyanate compound b-2, and the solvent c-1. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供可分散在各种溶剂如有机溶剂和含水有机溶剂中的固化组合物，而不损害碳纳米管本身的特性，能够防止碳纳米管分离或者即使长时间的保存也能够聚集，导电性，成膜性和成型性优异，可以通过简单的方法适用或涂布在基材上，能够得到高透明性，耐刮擦性优异的固化膜具有耐候性，对基材的粘合性，机械强度，导热性和硬度的复合材料或具有包含其的涂膜或固化膜的转印片及其制造方法。解决方案：该固化性组合物含有碳纳米管a，分子中具有至少一个羟基的环氧（甲基）丙烯酸酯b-1与异氰酸酯化合物b-2的反应产物的氨基甲酸酯化合物，和溶剂c-1。版权所有（C）2009，JPO＆INPIT

9. 发明专利

JP2005171154A Curable composition, protective coating material for metal and adhesive for optical disc 有权
标题翻译：可固化组合物，用于光盘的金属和粘合剂的保护涂料
公开(公告)号：JP2005171154A
公开(公告)日：2005-06-30
申请号：JP2003415328
申请日：2003-12-12
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： FUJIMOTO JUICHI , NURISHI SEIJI , HAYAMA YASUSHI
IPC分类号： C08F290/06 , C09D4/00 , C09D175/16 , C09J4/00 , C09J175/16
摘要： PROBLEM TO BE SOLVED: To obtain a curable composition that can give a cured product having small warpage, having protective performance on a metal thin film, especially a thin film made of silver or a silver alloy and having excellent durability. SOLUTION: The curable composition comprises (A) a urethane (meth)acrylate produced by reacting (a1) a polycarbonate diol having a number average molecular weight of 250-850, (a2) a diisocyanate compound and (a3) a hydroxyl group-containing (meth)acrylic ester and (B) a (meth)acrylic ester other than the component (A). COPYRIGHT: (C)2005,JPO&NCIPI

10. 发明专利

JP2005146110A Curable composition and article 有权
标题翻译：可固化组合物和物品
公开(公告)号：JP2005146110A
公开(公告)日：2005-06-09
申请号：JP2003385023
申请日：2003-11-14
申请人： Mitsubishi Rayon Co Ltd , 三菱レイヨン株式会社
发明人： FUJIMOTO JUICHI , NURISHI SEIJI , HAYAMA YASUSHI
IPC分类号： C08J7/04 , B32B27/20 , B32B27/30 , C08F2/44 , C08F292/00
摘要： PROBLEM TO BE SOLVED: To provide an article having a cured product with excellent initial and long-term durability (scratch resistance, antistatic properties and stain proof properties) under high-temperature and high-humidity condition; and to obtain a curable composition for obtaining such the cured product.
SOLUTION: The curable composition comprises (A) silica obtained by subjecting a colloidal silica fine particles (a1) and a hydrolyzed product (a2) of an organosilane compound to condensation reaction, (B) an ethylenically unsaturated compound and (C) at least one kind of compound represented by formulas (I) to (III).
COPYRIGHT: (C)2005,JPO&NCIPI

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