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    • 3. 发明公开
    • OLEFIN RESIN AND METHOD FOR PRODUCING SAME
    • OLEFINHARZ UND VERFAHREN ZUR HERSTELLUNG DAVON
    • EP3124506A1
    • 2017-02-01
    • EP15770050.1
    • 2015-03-26
    • Mitsui Chemicals, Inc.
    • YANAGIMOTO, YasushiMATSUGI, TomoakiIWASHITA, AkihikoNAKAMURA, TatsuyaSAITO, Junji
    • C08F10/00C08F4/62C08F4/646C08F4/6592C08F210/16
    • C08F210/16C08F4/64048C08F4/65927C08F290/042C08L23/0815C08F4/65904C08F210/06C08F2500/04C08F2500/05C08F2500/17C08F210/08C08F210/14C08F210/02
    • The present invention provides an olefin resin with an improved heat resistance, reduced stickiness, excellent optical and low temperature properties, as well as the balance between these physical properties. The olefin resin according to the present invention satisfies the following requirements: (I) a melting peak (Tm) is observed within the range of from 60°C to 130°C, and the heat of fusion ΔH at the melting peak is within the range of from 5 to 150 J/g; (II) the percentage E (wt%) of a portion soluble in o-dichlorobenzene at 20 °C or lower, and the heat of fusion ΔH satisfy certain relationships; (III) the glass transition temperature (Tg) is from -80 to -30°C; (IV) the spin-spin relaxation time (T2) of a component having the highest mobility, as obtained in a four-component approximation with a Lorentzian function performed for a free induction decay curve, is within the range of from 150 to 500 ms, and the abundance ratio of the component is within the range of from 15 to 50%; and (V) the intrinsic viscosity [η] as measured in decalin at 135°C is within the range of from 0.1 to 12 dl/g.
    • 本发明提供了具有改善的耐热性,降低的粘性,优异的光学和低温性能以及这些物理性能之间的平衡的烯烃树脂。 根据本发明的烯烃树脂满足以下要求:(I)在60℃至130℃的范围内观察到熔融峰(Tm),熔融峰处的熔化热“H”在 范围为5〜150J / g; (II)在20℃以下可溶于邻二氯苯的部分的比例E(wt%),熔融热“H”满足一定关系; (III)玻璃化转变温度(Tg)为-80〜-30℃; (IV)具有最高迁移率的成分的自旋 - 自旋弛豫时间(T2)在用自由诱导衰变曲线进行的洛伦兹函数的四分量近似中获得的范围为150-500ms ,成分的丰度比在15〜50%的范围内。 和(V)在135℃萘烷中测定的特性粘度[·]为0.1〜12dl / g的范围。
    • 6. 发明公开
    • Catalysts
    • Katalysatoren
    • EP1997834A1
    • 2008-12-03
    • EP07252186.7
    • 2007-05-29
    • Borealis Technology Oy
    • Bildstein, BennoKopacka, HolgerEnk, BarbaraWurst, KlausMaaranen, JanneVanne, TiinaMansner, ErikKauhanen, Jurki
    • C08F4/62C08F10/00C07F7/28C07F7/00C07F5/00C07F11/00C07F19/00
    • C07C251/24C07C45/46C07C45/64C07C49/835C07C251/00C07C2601/10C07F11/005C08F4/65912C08F4/65916C08F10/00C08F110/02C08F2410/03C08F2420/04C07C49/798C08F4/52C08F4/6592C08F4/545C08F4/64013C08F4/64044C08F4/69112C08F4/64058C08F4/64048
    • An olefin polymerisation catalyst comprising:
      (I) a complex comprising a ligand of formula (I)

      coordinated (as shown) to a metal ion M; and
      (II) a cocatalyst; or the reaction product thereof;

      wherein each X which may be the same or different is NR 3 or O;
      each Y which may be the same or different is C, S, P, S=O;
      each R 1 which may be the same or different is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, -CN, N(R 4 ) 2 , silyl, siloxy, -CF 3 , -SH, -C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)R 4 , -NR 4 C(=NR 4 )R 4 , -NR 4 C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)OR 4 , -NR 4 C(=O)NR 4 R 4 , -NR 4 S(O) 2 R 4 , -S(O) 2 NR 4 R 4 , -C(=S)NR 4 R 4 , -OC(=O)R 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl;
      each R 2 which may be the same or different is an optionally substituted C 1-20 hydrocarbyl group, halo, silyl, siloxy, nitro, -CN, N(R 4 ) 2 , -CF 3 , -SH, C(=O)R 4 , OC(=O)R 4 , C(=O)OR 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl or two R 2 groups attached to adjacent ring atoms together form an optionally substituted 5- to 8-membered fused ring;
      each R 3 which may be the same or different is hydrogen, or an optionally substituted C 1-20 hydrocarbyl group;
      each R 4 which may be the same or different is a hydrogen, an optionally substituted C 1-20 hydrocarbyl group, or two R 4 groups taken together form an optionally substituted 5- to 8-membered fused ring;
      a is 0 to 3;
      b is 1 unless the atom Y to which R 1 is attached is P wherein b is 2.
    • 一种烯烃聚合催化剂,其包含:(I)包含与金属离子M配位的(如图所示)的式(I)配位体的络合物; 和(II)助催化剂; 或其反应产物; 其中可以相同或不同的每个X是NR 3或O; C,S,P,S = O可以是相同或不同的Y。 每个R 1可以相同或不同,是氢,任选取代的C 1-20烃基,-CN,N(R 4)2,甲硅烷基,甲硅烷氧基,-CF 3,-SH,-C(= NR 4) )NR 4 R 4,-NR 4 C(= O)R 4,-NR 4 C(= NR 4)R 4,-NR 4 C(= NR 4)NR 4 R 4,-NR 4 C(= O )OR 4,-NR 4 C(= O)NR 4 R 4,-NR 4 S(O)2 R 4,-S(O)2 NR 4 R 4,-C(= S)NR 4 R 4, -OC(= O)R 4,-OC(= O)NR 4 R 4,-OR 4,任选取代的杂环基或任选取代的杂芳基; 每个R 2可以相同或不同,是任选取代的C 1-20烃基,卤素,甲硅烷基,甲硅烷氧基,硝基,-CN,N(R 4)2,-CF 3,-SH,C(= O )R 4,OC(= O)R 4,C(= O)OR 4,-OC(= O)NR 4 R 4,-OR 4,任选取代的杂环基或任选取代的杂芳基或两个R 2基团 相邻的环原子一起形成任选取代的5至8元稠环; 每个R 3可以相同或不同,是氢或任选取代的C 1-20烃基; 每个可以相同或不同的R 4是氢,任选取代的C 1-20烃基,或两个R 4基团一起形成任选取代的5至8元稠环; a是0到3; b除非与R 1连接的原子Y是P,其中b是2,b是1。