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1. 发明公开

EP1586591A1 PROCESS FOR PRODUCING ETHYLENE/a-OLEFIN/UNCONJUGATED POLYENE COPOLYMER AND ETHYLENE/a-OLEFIN/UNCONJUGATED POLYENE COPOLYME R 审中-公开
标题翻译：工艺生产乙烯，乙烯的烯烃和非共轭多烯和共聚物，烯烃和非共轭多烯共聚物
公开(公告)号：EP1586591A1
公开(公告)日：2005-10-19
申请号：EP04704723.8
申请日：2004-01-23
申请人： Mitsui Chemicals, Inc.
发明人： MATSUURA, Sadahiko , MURAKAMI, Hidetatsu , HASADA, Yasuhiro , SAITO, Junji , FUJITA, Terunori , MATSUI, Shigekazu
IPC分类号： C08F210/18 , C08F4/64
CPC分类号： C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17 , C08F4/64048
摘要： The invention has an object of providing a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer with good polymerization activity and high conversion of non-conjugated polyene.
The invention achieves the object by providing a process for producing an ethylene/α-olefin/non-conjugated polyene copolymer that comprises copolymerizing ethylene, an α-olefin and a non-conjugated polyene in a hydrocarbon solvent with use of a transition metal compound catalyst, and removing the unreacted monomers and the hydrocarbon solvent from the copolymer solution without removing the catalyst residue, wherein the copolymerization is carried out at a polymerization temperature of 100°C or above and a polymerization pressure of 2.7 MPa or above in a manner such that the non-conjugated polyene concentration in the polymerization solution is less than the maximum non-conjugated polyene concentration Cmax (mol/L) indicated below:

Cmax = 0.050 (mol/L) when the copolymer has an iodine value (IV) of 9.0 g/100 g to less than 17.0 g/100 g; or
Cmax = 0.104 (mol/L) when the copolymer has an iodine value (IV) of 17.0 g/100 g or above.
摘要翻译：本发明已经致力于提供一种用于在具有良好聚合活性和非共轭多烯的高转化率/α-烯烃/非共轭多烯共聚物的制造的过程的乙烯对象。本发明通过用于在乙烯/α-烯烃/非共轭多烯共聚物的制造提供一种方法实现该对象确实包括共聚合乙烯，α-烯烃的非共轭多烯和在烃溶剂中利用的过渡金属化合物催化剂，并除去未反应的单体和由该共聚物溶液，而不除去催化剂残基，worin共聚的烃溶剂中，在100℃以上的聚合温度下和以上在2.7 MPa的聚合压力下进行的方式检查的确在聚合溶液中的非共轭多烯的浓度低于下图所示的最大非共轭多烯浓度的C max（摩尔/ L）：Cmax为0.050（摩尔/ L）当共聚物具有碘值（IV ）9.0克/ 100克至小于17.0克/ 100克; 或的C max = 0.104（摩尔/ L）当共聚物具有碘值17.0克/ 100克或以上（IV）。

2. 发明授权

EP1243598B1 PROCESS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：工艺聚合烯烃
公开(公告)号：EP1243598B1
公开(公告)日：2015-08-12
申请号：EP01943881.1
申请日：2001-06-29
申请人： Mitsui Chemicals, Inc.
发明人： SUZUKI, Yasuhiko , MATSUGI, Tomoaki , TAKAGI, Yukihiro , YOSHIDA, Yasunori , SAITO, Junji , MATSUI, Shigekazu , INOUE, Yoshihisa , FUJITA, Terunori
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/64048 , C08F2500/17 , C08F210/08 , C08F210/14

3. 发明公开

EP3712187A1 POLYURETHANE RESIN COMPOSITION, POLYURETHANE RESIN, MOULDED ARTICLE, FIBRE-REINFORCED PLASTIC, AND METHOD FOR PRODUCING FIBRE-REINFORCED PLASTIC 无效转让
公开(公告)号：EP3712187A1
公开(公告)日：2020-09-23
申请号：EP18875409.7
申请日：2018-11-07
申请人： Mitsui Chemicals, Inc.
发明人： TANAKA, Toshihiro , KANAYAMA, Hiroshi , WATANABE, Minoru , INOUE, Hiroki , SAITO, Junji
IPC分类号： C08G18/08 , C08G18/22 , C08G18/72 , C08G18/76 , C08J5/04
摘要： The polyurethane resin composition contains a polyisocyanate component containing p-MDI, a polyol component, an organic metal catalyst, and a reaction retardant represented by general formula (1) below, wherein the mole ratio of the reaction retardant relative to 1 mol of the organic metal catalyst is 0.50 or more and 2.50 or less. (in general formula (1), A represents an aliphatic ring or an aromatic ring. R 1 represents a hydrocarbon group composing ring A. R 2 represents an aliphatic hydrocarbon group bonded to ring A. R 3 represents a hydrogen atom or alkyl group bonded to nitrogen atom included in ring A. R 4 represents a hydrogen atom or carboxyl group bonded to ring A. m is 1 or 2, n is 0 or 1, and total of n and m is 2 or less.)

4. 发明授权

EP1875961B1 CAPSULAR FINE PARTICLE COMPRISING OLEFINIC POLYMER 有权
公开(公告)号：EP1875961B1
公开(公告)日：2018-08-29
申请号：EP06731444.3
申请日：2006-04-07
申请人： Mitsui Chemicals, Inc.
发明人： NAKAYAMA, Yasushi , MATSUKAWA, Naoto , SAITO, Junji , MURATA, Susumu , MITANI, Makoto , FUJITA, Terunori
IPC分类号： B01J13/04
CPC分类号： B01J13/14 , B01J13/02 , Y10T428/2982 , Y10T428/2985 , Y10T428/2987 , Y10T428/2989
摘要： To provide capsular fine particles comprising an olefinic polymer which have a uniform particle size distribution and a uniform particle size, and which are spherical and free from the coagulation between particles. Capsular fine particles comprising the olefinic polymer, of which the ratio (L/M) of the outer diameter (L) to the inner diameter (M) is 1.1 to 6.0, and the average diameter is 0.6 to 40 µm.

5. 发明公开

EP1241194A1 POLYMER AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译： POLYMER UND VERFAHREN ZU DESSEN HERSTELLUNG
公开(公告)号：EP1241194A1
公开(公告)日：2002-09-18
申请号：EP01954350.3
申请日：2001-07-26
申请人： Mitsui Chemicals, Inc.
发明人： KASHIWA, Norio , KOJOH, Shinichi , MATSUO, Shingo , SAITO, Junji , FUJITA, Terunori , MITANI, Makoto , TAKAHASHI, Mamoru , SATO, Yasuo
IPC分类号： C08F290/00 , C08F10/00 , C08F4/60
CPC分类号： C08F290/06 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F255/00 , C08F255/02 , C08F290/00 , C08F290/042 , C08F2420/02 , C08F4/64048 , C08F2500/12 , C08F2500/03 , C08F2500/09 , C08F2500/20 , C08F2500/11 , C08F210/14 , C08F4/65904
摘要： The present invention relates to a polymer having a melt tension (MT (g)) substantially the same as or lower than that of a conventional polymer which is substantially the same as the polymer in the recurring unit of the main skeleton, the molecular weight, the molecular weight distribution and the crystallinity, and having a flow activation energy (Ea (KJ/mol)) larger than a value obtained by adding 5 KJ/mol to the Ea value of the conventional polymer. A preferred example 'of the polymer is a branched polyolefin comprising 50 to 100 % by mol of recurring units derived from ethylene and 0 to 50 % by mol of recurring units derived from an α-olefin of 3 to 20 carbon atoms and having the following properties: the flow activation energy (Ea (KJ/mol)) and the α-olefin content (C (% by weight)) satisfy a specific relation, and the melt tension (MT (g)) and the melt flow rate (MFR (g/10 min)) satisfy a specific relation. This branched polyolefin is excellent in moldability and mechanical strength.
摘要翻译：本发明涉及一种熔体张力（MT（g））基本上等于或低于常规聚合物的聚合物的聚合物，其与主骨架的重复单元中的聚合物基本相同，分子量，分子量分布和结晶度，并且具有大于通过向常规聚合物的Ea值加入5KJ / mol获得的值的流动活化能（Ea（KJ / mol））。聚合物的优选实例是包含50至100摩尔％的衍生自乙烯的重复单元和0至50摩尔％的衍生自3-20个碳原子的α-烯烃的重复单元并具有以下的支链聚烯烃性质：流动活化能（Ea（KJ / mol））和α-烯烃含量（C（重量％））满足特定关系，熔体张力（MT（g））和熔体流动速率（MFR （g / 10分钟））满足特定关系。该支化聚烯烃的成型性和机械强度优异。

6. 发明授权

EP1270603B1 OLEFIN POLYMERIZATION CATALYST, PROCESS FOR POLYMERIZING OLEFINS 有权
标题翻译：的烯烃聚合催化剂，工艺用于烯烃聚合
公开(公告)号：EP1270603B1
公开(公告)日：2014-04-09
申请号：EP02013558.8
申请日：2002-06-19
申请人： Mitsui Chemicals, Inc.
发明人： ISHII, Seiichi , MITANI, Makoto , SAITO, Junji , MATSUURA, Sadahiko , MATSUKAWA, Naoto , TSURU, Kazutaka , FUJITA, Terunori
IPC分类号： C08F4/64 , C08F110/02 , C08F290/04 , C08F8/08 , C08F8/36 , C08F8/46
CPC分类号： C08F290/042 , C08F8/00 , C08F8/36 , C08F8/46 , C08F110/02 , C08F2810/40 , C08F4/64048 , C08F2500/03 , C08F2500/02 , C08F2500/17

7. 发明授权

EP1241194B1 POLYMER AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：聚合物和方法及其
公开(公告)号：EP1241194B1
公开(公告)日：2013-09-04
申请号：EP01954350.3
申请日：2001-07-26
申请人： Mitsui Chemicals, Inc.
发明人： KASHIWA, Norio , KOJOH, Shinichi , MATSUO, Shingo , SAITO, Junji , FUJITA, Terunori , MITANI, Makoto , TAKAHASHI, Mamoru , SATO, Yasuo
IPC分类号： C08F290/04 , C08F210/00 , C08F4/6592 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F290/06 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F255/00 , C08F255/02 , C08F290/00 , C08F290/042 , C08F2420/02 , C08F4/64048 , C08F2500/12 , C08F2500/03 , C08F2500/09 , C08F2500/20 , C08F2500/11 , C08F210/14 , C08F4/65904

8. 发明公开

EP3124506A1 OLEFIN RESIN AND METHOD FOR PRODUCING SAME 有权转让
标题翻译： OLEFINHARZ UND VERFAHREN ZUR HERSTELLUNG DAVON
公开(公告)号：EP3124506A1
公开(公告)日：2017-02-01
申请号：EP15770050.1
申请日：2015-03-26
申请人： Mitsui Chemicals, Inc.
发明人： YANAGIMOTO, Yasushi , MATSUGI, Tomoaki , IWASHITA, Akihiko , NAKAMURA, Tatsuya , SAITO, Junji
IPC分类号： C08F10/00 , C08F4/62 , C08F4/646 , C08F4/6592 , C08F210/16
CPC分类号： C08F210/16 , C08F4/64048 , C08F4/65927 , C08F290/042 , C08L23/0815 , C08F4/65904 , C08F210/06 , C08F2500/04 , C08F2500/05 , C08F2500/17 , C08F210/08 , C08F210/14 , C08F210/02
摘要： The present invention provides an olefin resin with an improved heat resistance, reduced stickiness, excellent optical and low temperature properties, as well as the balance between these physical properties. The olefin resin according to the present invention satisfies the following requirements: (I) a melting peak (Tm) is observed within the range of from 60°C to 130°C, and the heat of fusion ΔH at the melting peak is within the range of from 5 to 150 J/g; (II) the percentage E (wt%) of a portion soluble in o-dichlorobenzene at 20 °C or lower, and the heat of fusion ΔH satisfy certain relationships; (III) the glass transition temperature (Tg) is from -80 to -30°C; (IV) the spin-spin relaxation time (T2) of a component having the highest mobility, as obtained in a four-component approximation with a Lorentzian function performed for a free induction decay curve, is within the range of from 150 to 500 ms, and the abundance ratio of the component is within the range of from 15 to 50%; and (V) the intrinsic viscosity [η] as measured in decalin at 135°C is within the range of from 0.1 to 12 dl/g.
摘要翻译：本发明提供了具有改善的耐热性，降低的粘性，优异的光学和低温性能以及这些物理性能之间的平衡的烯烃树脂。根据本发明的烯烃树脂满足以下要求：（I）在60℃至130℃的范围内观察到熔融峰（Tm），熔融峰处的熔化热“H”在范围为5〜150J / g; （II）在20℃以下可溶于邻二氯苯的部分的比例E（wt％），熔融热“H”满足一定关系; （III）玻璃化转变温度（Tg）为-80〜-30℃; （IV）具有最高迁移率的成分的自旋 - 自旋弛豫时间（T2）在用自由诱导衰变曲线进行的洛伦兹函数的四分量近似中获得的范围为150-500ms ，成分的丰度比在15〜50％的范围内。和（V）在135℃萘烷中测定的特性粘度[·]为0.1〜12dl / g的范围。

9. 发明公开

EP1964865A1 OLEFIN POLYMER, COMPOSITION THEREOF, AND ADHESIVE RESIN COMPOSED OF SUCH COMPOSITION 审中-公开
标题翻译： OLEFINPOLYMER，ZUSAMMENSETZUNG DAVON UND KLEBHARZ AUS EINER DERARTIGEN ZUSAMMENSETZUNG
公开(公告)号：EP1964865A1
公开(公告)日：2008-09-03
申请号：EP06834270.8
申请日：2006-12-08
申请人： Mitsui Chemicals, Inc.
发明人： MATSUGI, Tomoaki , SAITO, Junji , KANEKO, Hideyuki , KASHIWA, Norio , KOJOH, Shin-ichi , ONOGI, Takayuki , ISOKAWA, Motoaki , OTA, Seiji , YASUI, Shigeyuki
IPC分类号： C08F291/00 , C08L23/00 , C08L51/00
CPC分类号： C08L53/00 , C08F8/00 , C08F8/08 , C08F8/12 , C08F8/18 , C08F8/20 , C08F8/42 , C08F255/00 , C08F255/02 , C08F293/00 , C08F293/005 , C08F2810/50 , C08L23/0846 , C08L23/0884 , C08L23/0892 , C08L51/06 , C08L2205/02 , C08L2666/02 , C08L2666/14 , C09J123/02 , C09J123/0846 , C09J151/06 , C09J153/00 , Y10T428/263 , C08L2666/06 , C08F210/02 , C08F110/06 , C08F255/023 , C08F110/14 , C08F210/12
摘要： Provided is a new adhesive polyolefin resin composition, containing 1 to 100 % by weight of a high polymer structure, that has good heat resistance and excellent adhesion performance to polyolefins and various polar materials, wherein a polyolefin segment (A) is bonded with an addition polymer segment (B) of a non-olefinic vinyl monomer and a reactive group is introduced into the addition polymer segment (B) and an adhesive or dispersion obtained therefrom.
摘要翻译：提供了一种新的粘合剂聚烯烃树脂组合物，其含有1至100重量％的高聚物结构，其具有良好的耐热性和对聚烯烃和各种极性材料的优异粘合性能，其中聚烯烃链段（A）与添加剂将非烯烃类乙烯基单体和反应性基团的聚合物链段（B）引入加成聚合物链段（B）和由其获得的粘合剂或分散体。

10. 发明公开

EP1243598A1 PROCESS FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译： VERFAHREN ZUR POLYMERISATION VON OLEFINEN
公开(公告)号：EP1243598A1
公开(公告)日：2002-09-25
申请号：EP01943881.1
申请日：2001-06-29
申请人： Mitsui Chemicals, Inc.
发明人： SUZUKI, Yasuhiko , MATSUGI, Tomoaki , TAKAGI, Yukihiro , YOSHIDA, Yasunori , SAITO, Junji , MATSUI, Shigekazu , INOUE, Yoshihisa , FUJITA, Terunori
IPC分类号： C08F4/615 , C08F10/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/64048 , C08F2500/17 , C08F210/08 , C08F210/14
摘要： A process for polymerizing an olefin is capable of polymerizing an olefin with excellent polymerization activity, and comprises polymerizing or copolymerizing an olefin at a polymerization reaction temperature of 50 to 200 °C in the presence of a catalyst comprising a transition metal compound (A) represented by the following formula (I), a compound (B-1) having a reduction ability which reacts with the transition metal compound (A) to convert an imine structure moiety to a metal amide structure, and a compound (B-2) which reacts with the transition metal compound (A) to form an ion pair;
wherein M is a transition metal atom of Groups 3 to 11 of the periodic table; m is an integer of 1 to 6; Y is O, S, Se, or -C(R 7 )-; R 1 to R 7 may be the same or different, and are each a hydrogen atom, a halogen atom, a hydrocarbon group, an oxgen-containing group, a nitrogen-containing group and the like; n is a number satisfying a valence of M; and X is a hydrogen atom, a halogen atom, a hydrocarbon group and the like.
摘要翻译：聚合烯烃的方法能够聚合具有优异聚合活性的烯烃，并且包括在50-200℃的聚合反应温度下在含有代表的过渡金属化合物（A）的催化剂存在下聚合或共聚烯烃通过下式（I）表示具有与过渡金属化合物（A）反应以将亚胺结构部分转化为金属酰胺结构的还原能力的化合物（B-1）和化合物（B-2），其中与过渡金属化合物（A）反应形成离子对; 其中M是周期表第3至11族的过渡金属原子; m为1〜6的整数。 Y是O，S，Se或-C（R 7） - ; R 1至R 7可以相同或不同，并且各自为氢原子，卤素原子，烃基，含氧基团，含氮基团等; n是满足M价的数; X是氢原子，卤原子，烃基等。

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