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1. 发明公开

EP3312200A1 SOLID POLYALUMINOXANE COMPOSITION, OLEFIN POLYMERIZATION CATALYST, OLEFIN POLYMER PRODUCTION METHOD AND SOLID POLYALUMINOXANE COMPOSITION PRODUCTION METHOD 有权
标题翻译：固体聚氨酯组合物，烯烃聚合催化剂，烯烃聚合物生产方法和固体聚铝氧烷组合物生产方法
公开(公告)号：EP3312200A1
公开(公告)日：2018-04-25
申请号：EP17207804.0
申请日：2014-02-07
申请人： Mitsui Chemicals, Inc.
发明人： TSURUGI, Kou , HANADA, Siori , SHIBAHARA, Atsushi , KAWAMURA, Kazumori , NISHINO, Fumiaki , HARADA, Yasuyuki , YAMADA, Wataru , MATSUMOTO, Akiko , HARA, Isao , NAKAMURA, Tatsuya , MUROTO, Toshihiro
IPC分类号： C08F4/6592 , C08F210/16 , C07F5/06 , C08G79/10
CPC分类号： C08F10/02 , C08F4/02 , C08F4/027 , C08F4/65912 , C08F4/6592 , C08F4/65922 , C08F110/02 , C08G79/10 , C08F210/16 , C08F4/65927
摘要： An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).
摘要翻译：本发明的目的是提供适合用作助催化剂和催化剂载体与烯烃低聚或聚合催化剂组合的固体聚铝氧烷组合物，而不使用固体无机载体如二氧化硅。本发明的固体聚铝氧烷组合物包含聚烷基铝氧烷和三烷基铝，并且在25℃下在正己烷中的溶解度通过特定方法（i）测量小于0.50摩尔％，在25℃下在甲苯中的溶解度通过特定方法（ii）测定的小于1.0摩尔％，以及相对于衍生自聚烷基铝氧烷部分的烷基的总摩尔数的13摩尔％以上的来自三烷基铝部分的烷基的摩尔分数和通过特定方法（iii），相对于四氢呋喃-d8可溶性组分测定的衍生自三烷基铝部分的烷基。

2. 发明公开

EP4095168A1 OPTICAL COMPONENT 审中-实审转让
公开(公告)号：EP4095168A1
公开(公告)日：2022-11-30
申请号：EP20915377.4
申请日：2020-12-14
申请人： Mitsui Chemicals, Inc.
发明人： WASA, Hideki , FUJIMURA, Futoshi , SAITO, Haruka , NAKAMURA, Tatsuya , NAKASHIMA, Makoto
IPC分类号： C08F210/00 , C08F232/04 , G02B1/04
摘要： Provided is an optical component including a cyclic olefin-based copolymer (A), in which the cyclic olefin-based copolymer (A) has a constitutional unit (a) derived from at least one olefin represented by the following general formula (I), a constitutional unit (b) derived from at least one cyclic olefin represented by the following general formula (II), and a constitutional unit (c) derived from at least one cyclic olefin represented by the following general formula (III), and the content of the constitutional unit (a) is equal to or less than 50 mol% in a case where the total content of the constitutional unit (a), the constitutional unit (b), and the constitutional unit (c) is taken as 100 mol%.

3. 发明授权

EP3124514B1 OLEFIN-BASED RESIN, METHOD FOR PRODUCING SAME AND PROPYLENE-BASED RESIN COMPOSITION 有权转让
公开(公告)号：EP3124514B1
公开(公告)日：2019-07-10
申请号：EP15768930.8
申请日：2015-03-26
申请人： Mitsui Chemicals, Inc.
发明人： YANAGIMOTO, Yasushi , MATSUGI, Tomoaki , IWASHITA, Akihiko , NAKAMURA, Tatsuya , ITAKURA, Keita , TSUNORI, Ryoichi
IPC分类号： C08F290/04 , C08F4/6592 , C08F255/02 , C08L23/10 , C08L51/06 , C08L55/00

4. 发明授权

EP2955187B1 SOLID POLYALUMINOXANE COMPOSITION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：固体聚铝氧烷组合物，用于烯烃聚合的催化剂和用于制备烯烃聚合物的方法
公开(公告)号：EP2955187B1
公开(公告)日：2018-01-31
申请号：EP14748938.9
申请日：2014-02-07
申请人： Mitsui Chemicals, Inc.
发明人： TSURUGI, Kou , HANADA, Siori , SHIBAHARA, Atsushi , KAWAMURA, Kazumori , NISHINO, Fumiaki , HARADA, Yasuyuki , YAMADA, Wataru , MATSUMOTO, Akiko , HARA, Isao , NAKAMURA, Tatsuya , MUROTO, Toshihiro
IPC分类号： C08F4/6592 , C08F210/16 , C07F5/06 , C08G79/10
CPC分类号： C08F10/02 , C08F4/02 , C08F4/027 , C08F4/65912 , C08F4/6592 , C08F4/65922 , C08F110/02 , C08G79/10 , C08F210/16 , C08F4/65927
摘要： An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).

5. 发明授权

EP3231842B1 PROPYLENE-BASED RESIN COMPOSITION 有权转让
公开(公告)号：EP3231842B1
公开(公告)日：2020-03-11
申请号：EP15866431.8
申请日：2015-12-09
申请人： Mitsui Chemicals, Inc.
发明人： ITAKURA, Keita , ODAWARA, Akiko , KINOUCHI, Satoru , TAKASHIMA, Tateo , TSUNORI, Ryoichi , MATSUGI, Tomoaki , YANAGIMOTO, Yasushi , NAKAMURA, Tatsuya
IPC分类号： C08L23/10 , C08F4/655 , C08F4/6592 , C08F210/16 , C08L23/08

6. 发明公开

EP3124506A1 OLEFIN RESIN AND METHOD FOR PRODUCING SAME 有权转让
标题翻译： OLEFINHARZ UND VERFAHREN ZUR HERSTELLUNG DAVON
公开(公告)号：EP3124506A1
公开(公告)日：2017-02-01
申请号：EP15770050.1
申请日：2015-03-26
申请人： Mitsui Chemicals, Inc.
发明人： YANAGIMOTO, Yasushi , MATSUGI, Tomoaki , IWASHITA, Akihiko , NAKAMURA, Tatsuya , SAITO, Junji
IPC分类号： C08F10/00 , C08F4/62 , C08F4/646 , C08F4/6592 , C08F210/16
CPC分类号： C08F210/16 , C08F4/64048 , C08F4/65927 , C08F290/042 , C08L23/0815 , C08F4/65904 , C08F210/06 , C08F2500/04 , C08F2500/05 , C08F2500/17 , C08F210/08 , C08F210/14 , C08F210/02
摘要： The present invention provides an olefin resin with an improved heat resistance, reduced stickiness, excellent optical and low temperature properties, as well as the balance between these physical properties. The olefin resin according to the present invention satisfies the following requirements: (I) a melting peak (Tm) is observed within the range of from 60°C to 130°C, and the heat of fusion ΔH at the melting peak is within the range of from 5 to 150 J/g; (II) the percentage E (wt%) of a portion soluble in o-dichlorobenzene at 20 °C or lower, and the heat of fusion ΔH satisfy certain relationships; (III) the glass transition temperature (Tg) is from -80 to -30°C; (IV) the spin-spin relaxation time (T2) of a component having the highest mobility, as obtained in a four-component approximation with a Lorentzian function performed for a free induction decay curve, is within the range of from 150 to 500 ms, and the abundance ratio of the component is within the range of from 15 to 50%; and (V) the intrinsic viscosity [η] as measured in decalin at 135°C is within the range of from 0.1 to 12 dl/g.
摘要翻译：本发明提供了具有改善的耐热性，降低的粘性，优异的光学和低温性能以及这些物理性能之间的平衡的烯烃树脂。根据本发明的烯烃树脂满足以下要求：（I）在60℃至130℃的范围内观察到熔融峰（Tm），熔融峰处的熔化热“H”在范围为5〜150J / g; （II）在20℃以下可溶于邻二氯苯的部分的比例E（wt％），熔融热“H”满足一定关系; （III）玻璃化转变温度（Tg）为-80〜-30℃; （IV）具有最高迁移率的成分的自旋 - 自旋弛豫时间（T2）在用自由诱导衰变曲线进行的洛伦兹函数的四分量近似中获得的范围为150-500ms ，成分的丰度比在15〜50％的范围内。和（V）在135℃萘烷中测定的特性粘度[·]为0.1〜12dl / g的范围。

7. 发明公开

EP2955187A1 SOLID POLYALUMINOXANE COMPOSITION, CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, AND METHOD FOR PRODUCING SOLID POLYALUMINOXANE COMPOSITION 有权
标题翻译： FIXED POLYALUMINOXANZUSAMMENSETZUNG，烯烃聚合催化剂，用于生产烯烃和方法用于制备固体POLYALUMINOXANZUSAMMENSETZUNG
公开(公告)号：EP2955187A1
公开(公告)日：2015-12-16
申请号：EP14748938.9
申请日：2014-02-07
申请人： Mitsui Chemicals, Inc.
发明人： TSURUGI, Kou , HANADA, Siori , SHIBAHARA, Atsushi , KAWAMURA, Kazumori , NISHINO, Fumiaki , HARADA, Yasuyuki , YAMADA, Wataru , MATSUMOTO, Akiko , HARA, Isao , NAKAMURA, Tatsuya , MUROTO, Toshihiro
IPC分类号： C07F5/06 , C08F4/642 , C08F10/00 , C08G79/10
CPC分类号： C08F10/02 , C08F4/02 , C08F4/027 , C08F4/65912 , C08F4/6592 , C08F4/65922 , C08F110/02 , C08G79/10 , C08F210/16 , C08F4/65927
摘要： An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).
摘要翻译：本发明的一个目的是提供适合用作助催化剂和在烯烃低聚或聚合的催化剂组合的催化剂载体与固体组合物polyaluminoxane，在不使用固体无机载体的：例如二氧化硅。本发明的固体polyaluminoxane组合物包括polyalkylaluminoxanes和三烷基铝，并且具有在25℃小于12:50摩尔％在正己烷中的溶解度为通过特定的方法（i），在甲苯中的溶解度在25℃下测得的小于1.0摩尔％的作为测量由特定方法（ii），和13％（摩尔）或从相对于从polyalkylaluminoxanes部分和所导出的烷基的总摩尔数的三烷基铝结构部分衍生的烷基的更摩尔分数从三烷基铝结构部分衍生为由特定方法测定的，对于四氢呋喃-D 8种可溶性组分的烷基（ⅲ）。

8. 发明公开

EP1816146A1 SOLID TITANIUM CATALYST COMPONENT, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER 有权
标题翻译：固体钛催化剂组分，用于生产OELFINPOLYMER烯烃聚合催化剂和方法
公开(公告)号：EP1816146A1
公开(公告)日：2007-08-08
申请号：EP05806700.0
申请日：2005-11-16
申请人： Mitsui Chemicals, Inc.
发明人： MATSUMOTO, Tetsuhiro , TSUTSUI, Toshiyuki , RO, Kisu , KUROIWA, Kourei , NAGATA, Takushi , SHIBAHARA, Atsushi , NAKAMURA, Tatsuya , TANAKA, Tooru , SHINOZAKI, Tetsunori
IPC分类号： C08F4/654 , C08F210/14 , C08J5/18
CPC分类号： C08F10/00 , C08F210/14 , C08F2500/26 , C08J5/18 , C08J2323/20 , C08F4/651 , C08F2500/15
摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C 3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
摘要翻译：本发明提供了一种生产在±烯烃聚合物，其包含聚合或共聚的（a）的C 3或更高±在烯烃聚合催化剂，它包括含钛的固体钛催化剂成分（I）的存在下烯烃（S），镁，卤素和具有两个或多个醚键和具有高催化活性有机金属催化剂组分（II）的特定结构的化合物。在这个过程中，特别是即使是在（共）的（a）更高的聚合烯烃，脱矿质是不必要的。通过使用本发明的催化剂聚合获得的基于4-甲基-1-戊烯类聚合物具有优异的立构规整度，透明性，耐热性，和脱模性，并且该聚合物是特别适合于释放的电影。

10. 发明公开

EP3375849A1 VISCOSITY MODIFIER FOR LUBRICATING OILS, ADDITIVE COMPOSITION FOR LUBRICATING OILS, AND LUBRICATING OIL COMPOSITIONS 审中-公开
公开(公告)号：EP3375849A1
公开(公告)日：2018-09-19
申请号：EP16864143.9
申请日：2016-11-07
申请人： Mitsui Chemicals, Inc.
发明人： HAYAKAWA, Akio , YANAGIMOTO, Yasushi , YAMAMOTO, Atsushi , NAKAMURA, Tatsuya , MATSUGI, Tomoaki , OKADA, Keiji
IPC分类号： C10M143/00 , C08F255/04 , C10M143/04 , C10N20/00 , C10N20/02 , C10N20/04 , C10N30/00 , C10N30/02 , C10N40/04 , C10N40/25 , C10N40/26 , C10N50/10
CPC分类号： C10M143/02 , C08F4/65922 , C08F10/02 , C08F10/06 , C08F255/04 , C08F2500/02 , C08F2500/17 , C10M143/00 , C10M143/04 , C10N2030/02 , C10N2230/02
摘要： [Problems]
An object of the present invention is to provide a viscosity modifier for lubricating oils and an additive composition for lubricating oils, for obtaining a lubricating oil composition excellent in storage stability under low temperature conditions as well as in viscosity characteristics at a low temperature.
[Solution to Problems]
The viscosity modifier for lubricating oils according to the present invention contains a resin (α), wherein the resin (α) satisfies specific requirements, and contains a grafted olefin polymer [R1] which is composed of a main chain and a side chain(s) and which satisfies the following requirements (i) and (ii). (i) The main chain is composed of a copolymer of ethylene and at least one α-olefin selected from α-olefins having from 3 to 12 carbon atoms, and contains the structural units derived from ethylene within the range of from 74 to 86 mol%. (ii) The side chain(s) is/are composed of a copolymer of ethylene and at least one α-olefin selected from α-olefins having from 3 to 12 carbon atoms, and contain(s) the structural units derived from ethylene within the range of from 30 to 65 mol%.

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