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    • 5. 发明公开
    • Catalysts
    • Katalysatoren
    • EP1997834A1
    • 2008-12-03
    • EP07252186.7
    • 2007-05-29
    • Borealis Technology Oy
    • Bildstein, BennoKopacka, HolgerEnk, BarbaraWurst, KlausMaaranen, JanneVanne, TiinaMansner, ErikKauhanen, Jurki
    • C08F4/62C08F10/00C07F7/28C07F7/00C07F5/00C07F11/00C07F19/00
    • C07C251/24C07C45/46C07C45/64C07C49/835C07C251/00C07C2601/10C07F11/005C08F4/65912C08F4/65916C08F10/00C08F110/02C08F2410/03C08F2420/04C07C49/798C08F4/52C08F4/6592C08F4/545C08F4/64013C08F4/64044C08F4/69112C08F4/64058C08F4/64048
    • An olefin polymerisation catalyst comprising:
      (I) a complex comprising a ligand of formula (I)

      coordinated (as shown) to a metal ion M; and
      (II) a cocatalyst; or the reaction product thereof;

      wherein each X which may be the same or different is NR 3 or O;
      each Y which may be the same or different is C, S, P, S=O;
      each R 1 which may be the same or different is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, -CN, N(R 4 ) 2 , silyl, siloxy, -CF 3 , -SH, -C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)R 4 , -NR 4 C(=NR 4 )R 4 , -NR 4 C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)OR 4 , -NR 4 C(=O)NR 4 R 4 , -NR 4 S(O) 2 R 4 , -S(O) 2 NR 4 R 4 , -C(=S)NR 4 R 4 , -OC(=O)R 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl;
      each R 2 which may be the same or different is an optionally substituted C 1-20 hydrocarbyl group, halo, silyl, siloxy, nitro, -CN, N(R 4 ) 2 , -CF 3 , -SH, C(=O)R 4 , OC(=O)R 4 , C(=O)OR 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl or two R 2 groups attached to adjacent ring atoms together form an optionally substituted 5- to 8-membered fused ring;
      each R 3 which may be the same or different is hydrogen, or an optionally substituted C 1-20 hydrocarbyl group;
      each R 4 which may be the same or different is a hydrogen, an optionally substituted C 1-20 hydrocarbyl group, or two R 4 groups taken together form an optionally substituted 5- to 8-membered fused ring;
      a is 0 to 3;
      b is 1 unless the atom Y to which R 1 is attached is P wherein b is 2.
    • 一种烯烃聚合催化剂,其包含:(I)包含与金属离子M配位的(如图所示)的式(I)配位体的络合物; 和(II)助催化剂; 或其反应产物; 其中可以相同或不同的每个X是NR 3或O; C,S,P,S = O可以是相同或不同的Y。 每个R 1可以相同或不同,是氢,任选取代的C 1-20烃基,-CN,N(R 4)2,甲硅烷基,甲硅烷氧基,-CF 3,-SH,-C(= NR 4) )NR 4 R 4,-NR 4 C(= O)R 4,-NR 4 C(= NR 4)R 4,-NR 4 C(= NR 4)NR 4 R 4,-NR 4 C(= O )OR 4,-NR 4 C(= O)NR 4 R 4,-NR 4 S(O)2 R 4,-S(O)2 NR 4 R 4,-C(= S)NR 4 R 4, -OC(= O)R 4,-OC(= O)NR 4 R 4,-OR 4,任选取代的杂环基或任选取代的杂芳基; 每个R 2可以相同或不同,是任选取代的C 1-20烃基,卤素,甲硅烷基,甲硅烷氧基,硝基,-CN,N(R 4)2,-CF 3,-SH,C(= O )R 4,OC(= O)R 4,C(= O)OR 4,-OC(= O)NR 4 R 4,-OR 4,任选取代的杂环基或任选取代的杂芳基或两个R 2基团 相邻的环原子一起形成任选取代的5至8元稠环; 每个R 3可以相同或不同,是氢或任选取代的C 1-20烃基; 每个可以相同或不同的R 4是氢,任选取代的C 1-20烃基,或两个R 4基团一起形成任选取代的5至8元稠环; a是0到3; b除非与R 1连接的原子Y是P,其中b是2,b是1。