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    • 8. 发明公开
    • PROCESS
    • 处理
    • EP3207014A1
    • 2017-08-23
    • EP15791479.7
    • 2015-10-15
    • Spolek Pro Chemickou A Hutni Vyrobu, Akciova Spolecnost
    • FILAS, KarelKUBICEK, PavelONDRUS, ZdenekSLADEK, Petr
    • C07C17/272C07C17/275C07C17/383C07C19/01
    • C07C17/02C07C17/275C07C17/38C07C17/383C07C19/01Y02P20/582
    • Disclosed is a process for producing a chlorinated C3-6 alkane comprising providing a reaction mixture comprising an alkene and carbon tetrachloride in a principal alkylation zone to produce chlorinated C3-6 alkane in the reaction mixture, and extracting a portion of the reaction mixture from the principal alkylation zone, wherein: a) the concentration of the chlorinated C3-6 alkane in the reaction mixture in the principal alkylation zone is maintained at a level such that the molar ratio of chlorinated C3-6 alkane:carbon tetrachloride in the reaction mixture extracted from the alkylation zone does not exceed 95:5 when the principal alkylation zone is in continuous operation; and/or b) the reaction mixture extracted from the principal alkylation zone additionally comprises alkene and the reaction mixture is subjected to a dealkenation step in which at least about 50% or more by weight of the alkene present in the reaction mixture is extracted therefrom and at least about 50% of the extracted alkene is fed back into the reaction mixture provided in the principal alkylation zone; and/or c) the reaction mixture present in the principal alkylation zone and extracted from the principal alkylation zone additionally comprises a catalyst, and the reaction mixture extracted from the principal alkylation zone is subjected to an aqueous treatment step in which the reaction mixture is contacted with an aqueous medium in an aqueous treatment zone, a biphasic mixture is formed and an organic phase comprising catalyst is extracted from the biphasic mixture.
    • 公开了一种生产氯化C 3-6烷烃的方法,包括在主烷基化区提供包含烯烃和四氯化碳的反应混合物以在反应混合物中生成氯化C 3-6烷烃,并从反应混合物中提取一部分反应混合物 主烷基化区,其中:a)主烷基化区中反应混合物中氯化C3-6烷烃的浓度保持在一定的水平,使得提取的反应混合物中氯化C3-6烷:四氯化碳的摩尔比 当主烷基化区处于连续操作中时,来自烷基化区的重量不超过95:5; 和/或b)从主烷基化区中提取的反应混合物还包含烯烃,并且使反应混合物经历脱烷基化步骤,其中从反应混合物中存在的至少约50重量%或更多的链烯烃被提取出来并且 至少约50%的提取的烯烃被回送到主烷基化区中提供的反应混合物中; 和/或c)存在于主烷基化区中并从主烷基化区中提取的反应混合物还包含催化剂,并且从主烷基化区中提取的反应混合物进行水性处理步骤,其中使反应混合物接触 在含水处理区中用含水介质形成双相混合物,并从双相混合物中提取包含催化剂的有机相。