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    • 6. 发明公开
    • SEDIMENTATION STABILIZED RADIATION-CURABLE FILLED COMPOSITIONS
    • SEDIMENTATIONSSTABILISIERTESTRAHLUNGSHÄRTBAREGEFÜLLTEZUSAMMENSETZUNGEN
    • EP0998695A1
    • 2000-05-10
    • EP98939631.2
    • 1998-07-11
    • Ciba Specialty Chemicals Holding Inc.
    • MELISARIS, Anastasios, PanayiotisPANG, Thomas, Hsing
    • G03C9/08G03F7/027
    • G03F7/027B33Y10/00B33Y70/00G03F7/0037G03F7/075
    • The present invention relates to a process for the production of three-dimensional articles by stereolithography using a radiation-curable composition containing a mixture of at least one cationically polymerizable compound and/or at least one free radical polymerizable compound, at least one filler material, at least one photoinitiator for cationic and/or radical polymerizations and at least one antisedimentation agent. An organic viscosity stabilizer material soluble in the base resin may optionally be brought into contact with the composition. A filler material can be introduced in the composition in an effective amount sufficient to at least delay or prevent a significant viscosity increase. The present invention also relates to cured articles resulting from said processes and a process for preparing said compositions.
    • 本发明涉及使用含有至少一种阳离子聚合性化合物和/或至少一种自由基聚合性化合物,至少一种填料的混合物的放射线固化性组合物的立体光刻法来制造三维制品的方法, 至少一种用于阳离子和/或自由基聚合的光引发剂和至少一种抗沉降剂。 可以任选地使可溶于基础树脂的有机粘度稳定剂与组合物接触。 填充材料可以以足以至少延迟或防止显着粘度增加的有效量引入组合物中。 本发明还涉及由所述方法得到的固化制品和制备所述组合物的方法。
    • 8. 发明公开
    • Resist composition
    • Resistzusammensetzung。
    • EP0484021A1
    • 1992-05-06
    • EP91309659.0
    • 1991-10-18
    • NIPPON PAINT CO., LTD.
    • Ohata, MasatoshiYamamoto, Masaharu
    • G03F7/039G03F7/075C08F2/50C08F20/18C08F12/22
    • G03F7/039G03F7/075
    • The present invention provides a positive type resist composition which has excellent photosensitivity in light decomposition. The composition comprises;

      (a) a polymer having at least 70 % of isotactic construction, prepared from polymerizable monomers, at least a portion of which is a (meth)acrylate monomer having a group selected from the class consisting of a t-butyl group, a benzyl group, an alpha-methylbenzyl group, an alpha, alpha-dimethylbenzyl group and a trityl group, and
      (b) a photoactivator which generates an acid in response to a light irradiation.

      The present invention also provides a resist composition into which, instead of the polymer (a), a polymer (c) is formulated which has at least 70 % of isotactic construction and is prepared from polymerizable monomers, at least a portion of which is a hydroxyl styrene selected from the class consisting of p-t-butoxycarbonyloxystyrene, p-t-butoxycarbonyloxy-alpha-methyl-styrene, t-butyl-p-vinyl benzoate and t-butyl-p-isopropenylphenyloxy acetate.
    • 本发明提供一种在光分解中具有优异的光敏性的正型抗蚀剂组合物。 组合物包含 (a)由可聚合单体制备的具有至少70%全同立构构型的聚合物,其至少一部分是(甲基)丙烯酸酯单体,其具有选自叔丁基,苄基 ,α-甲基苄基,α,α-二甲基苄基和三苯甲基,和(b)响应于光照射而产生酸的光活化剂。 本发明还提供一种抗蚀剂组合物,代替聚合物(a),配制聚合物(c),其具有至少70%的全同立构构型,并由可聚合单体制备,其中至少一部分为 选自对叔丁氧羰基氧基苯乙烯,对叔丁氧羰基氧基-α-甲基苯乙烯,叔丁基对乙烯基苯甲酸酯和叔丁基对异丙烯基苯氧基乙酸酯的羟基苯乙烯。