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    • 9. 发明公开
    • PYROELECTRIC CERAMIC COMPOSITION, PYROELECTRIC ELEMENT, AND INFRARED DETECTOR
    • 红十字国际委员会KERAMIKZUSAMMENSETZUNG,PYROELEKTRISCHES ELEMENT UND INFRAROTDETEKTOR
    • EP2017239A1
    • 2009-01-21
    • EP07714005.1
    • 2007-02-09
    • Murata Manufacturing Co. Ltd.
    • ISHII, HidekiHORIKAWA, KatsuhiroHAYASHI, Koji
    • C04B35/472G01J1/02H01B3/12H01L37/02
    • G01J5/34C04B35/472C04B2235/3208C04B2235/3251C04B2235/3262C04B2235/3279C04B2235/768C04B2235/79C04B2235/81C04B2235/85H01L37/025
    • A pyroelectric ceramic composition contains a compound represented by (Pb 1-x Ca x ) (1+a) {(Ni 1/3 Nb 2/3 ) y Ti (1-y) }O 3 (wherein x, y, and a satisfy 0.20 ≤ x ≤ 0.27, 0.01 ≤ y ≤ 0.06, and 0.001 ≤ a ≤ 0.02, respectively) as a main component and 0.3 to 2.5 mol of Mn per 100 mol of the main component. The amount of segregates containing Ni, Ti, and Mn is 1.0 vol% or less (including 0 vol%) of a fired sinter. In this manner, a pyroelectric ceramic composition that has an adequately low insulation resistance and a high Curie temperature while achieving satisfactory pyroelectric properties is realized. Since the composition has a high Curie temperature, a thin, small pyroelectric element that withstands a reflow process can be obtained. Since the composition has a low insulation resistance, an infrared detector incorporating a pyroelectric element composed of the composition does not require a load resistance to be provided in parallel to the pyroelectric element and size reduction is possible.
    • 热电陶瓷组合物含有(Pb 1-x Ca x)(1 + a){(Ni 1/3 Nb 2/3)y Ti(1-y)} O 3(其中x,y和 主要成分分别为0.20‰¤‰‰0.27,0.01‰‰‰0.06和0.001‰¤‰¤0.02,主要成分为0.3〜2.5mol Mn。 含有Ni,Ti和Mn的析出物的量为烧结烧结体的1.0体积%以下(包括0体积%)。 以这种方式,实现了具有足够低的绝缘电阻和高居里温度同时获得令人满意的热电性能的热电陶瓷组合物。 由于组成具有高的居里温度,因此可以获得耐受回流处理的薄的小型热电元件。 由于组合物具有低的绝缘电阻,所以并入由该组合物构成的热释电元件的红外检测器不需要与热电元件平行设置的负载电阻,并且可以减小尺寸。