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    • 5. 发明公开
    • METHOD FOR PRODUCING MONOLITHIC POROUS BODY COMPRISING TITANIA
    • 生产包含二氧化钛的单层多孔体的方法
    • EP3263528A1
    • 2018-01-03
    • EP16755543.2
    • 2016-02-24
    • SNG Inc.
    • MIYAMOTO, Riichi
    • C01G23/053
    • C01G23/053C04B35/46C04B35/624C04B38/0045C04B2235/441
    • Provided is a producing method that makes it possible to stably manufacture a homogeneous titania monolithic porous body by a sol-gel method using various titanium alkoxides as a titanium precursor. The method comprises the steps of: preparing a titanium precursor solution by mixing a titanium alkoxide other than titanium methoxide, which is a titanium precursor, and a first anion source in an organic solvent; preparing a sol by adding water or an aqueous solution containing a second anion source to the titanium precursor solution; forming a co-continuous structure of a titania hydrogel phase and a solvent phase by subjecting the sol to sol-gel transition and phase separation in parallel; and removing the solvent phase from the co-continuous structure, in which a temperature lower than the boiling point of the compound having the lowest boiling point present in the titanium precursor solution is maintained in the first three steps, and in which a blending amount of the first anion source or that of the first and the second anion sources is set such that a molar ratio of the first anion source or a molar ratio of the first and the second anion sources in total to the titanium precursor is equal to or higher than 1.05.
    • 本发明提供一种制造方法,该制造方法能够使用各种钛醇盐作为钛前体,通过溶胶 - 凝胶法稳定地制造均匀的二氧化钛单块多孔体。 该方法包括以下步骤:通过在有机溶剂中混合除钛甲醇盐以外的钛醇盐和第一阴离子源来制备钛前体溶液; 通过将水或含有第二阴离子源的水溶液加入到所述钛前体溶液中来制备溶胶; 通过使所述溶胶平行进行溶胶 - 凝胶转变和相分离而形成二氧化钛水凝胶相和溶剂相的共连续结构; 并且从共连续结构中除去溶剂相,其中在前三个步骤中保持低于钛前体溶液中存在的沸点最低的化合物的沸点的温度,并且其中混合量为 第一阴离子源或第一阴离子源和第二阴离子源的阴离子源被设定为使得第一阴离子源的摩尔比或第一阴离子源与第二阴离子源的总量与钛前体的摩尔比等于或高于 1.05。