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    • 9. 发明公开
    • ETHYLENE COPOLYMER COMPOSITION AND MOLDINGS
    • 乙烯共聚物ZUSAMMENSETZUNG UND FORMENMASSEN
    • EP0869146A1
    • 1998-10-07
    • EP97944181.3
    • 1997-10-20
    • Mitsui Chemicals, Inc.
    • OKADA, KeijiTAKIMOTO, KazuyukiMATSUMOTO, TetsuhiroMORIZONO, Ken-ichi
    • C08L23/08
    • C08L23/06C08L23/08C08L23/0815C08L23/0838C08L2205/02C08L2666/04
    • The present invention provides a copolymer composition based on ethylene which exhibits an adequate extensible flexibility and an ability for adhering onto various surfaces and which is superior in the transparency, strength, restorability from strain, blocking resistance and processibility and has no content of chlorine, as well as formed products made thereof, such as films, sheets, pipes and tubes, wherein said copolymer composition comprises

      (A) 10 - 90 % by weight of a copolymer of ethylene with an aromatic vinyl compound and/or an α - olefin, which has a degree of crystallinity of at least 10 % but less than 90 % and an intrinsic viscosity [η A ] of 1 - 10 dl/g and
      (B) 10 - 90 % by weight of a homopolymer of ethylene or a copolymer of ethylene with an aromatic vinyl compound and/or an α -olefin, which has a degree of crystallinity higher than 10 % but not higher than 90 % and an intrinsic viscosity [η B ] of 0.1 - 2 dl/g
      wherein at least one of the above ethylenic copolymer (A) and the ethylenic polymer (B) has the copolymerized aromatic vinyl compound and wherein the ratio of [degree of crystallinity of (A)/degreee of crystallinity of (B)] is less than 1 and the ratio of [η A ]/[η B ] is greater than 1.
    • 本发明提供了一种基于乙烯的共聚物组合物,其表现出足够的可伸长的柔韧性和粘附在各种表面上的能力,其透明度,强度,耐应变性,耐粘连性和加工性均优异,并且不含氯量,如 以及其制成的成品,例如膜,片,管和管,其中所述共聚物组合物包含(A)10-90重量%的乙烯与芳族乙烯基化合物和/或α-烯烃的共聚物,其中 结晶度至少为10%但小于90%,特性粘度ÄetaAÜ为1-10dl / g,(B)为乙烯均聚物或乙烯与乙烯的共聚物的重量比为10〜90% 芳族乙烯基化合物和/或α-烯烃,其结晶度高于10%但不高于90%,特性粘度ÄetaBÜ为0.1-2dl / g,其中至少一种上述烯属 共聚物(A)和乙烯性聚合物(B)具有共聚的芳族乙烯基化合物,其中(A)的结晶度/(B)Ü的结晶度的比例小于1,ÄetaAÜ/ ÄetaBÜ大于1。