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1. 发明授权

EP1188743B1 PROCESS FOR PREPARING ORGANIC SULFUR ACIDS OR SALTS THEREOF 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG有机化学家SCHWEFELSÄURENODER IHREN SALZEN
公开(公告)号：EP1188743B1
公开(公告)日：2009-06-17
申请号：EP01906350.2
申请日：2001-02-27
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya
IPC分类号： C07C303/14 , C07C309/04 , C07C309/25
CPC分类号： C07C303/14 , C07C2601/14 , C07C2601/18 , C07C2603/74 , C07C309/25 , C07C309/04
摘要： A process for preparing organic sulfur acids or salts thereof, which comprises reacting an organic substrate with a sulfur oxide in the presence of a metal compound catalyst in the absence of N-hydroxy- and N-oxo-cyclic imide compounds to thereby obtain the corresponding organic sulfur acid or a salt thereof. The organic substrate includes (a) methylene-bearing homo- and hetero-cyclic compounds, (b) compounds bearing methyne carbon atoms, (c) unsaturated compounds bearing methyl or methylene groups at the position adjacent to the unsaturated bond, (d) nonaromatic heterocyclic compounds having carbon-hydrogen bonds at the position adjacent to the heteroatom, (e) linear alkanes, and so on, while the sulfur oxide may be sulfur dioxide or the like. This process permits efficient production of organic sulfur acids or salts thereof under mild conditions.
摘要翻译：本发明的有机硫酸或其盐的制备方法允许有机基质在金属化合物催化剂的存在下和在不存在N-羟基和N-氧代环状酰亚胺化合物的情况下与硫氧化物反应，从而得到相应的有机硫酸或其盐。这样的有机底物包括例如（a）具有亚甲基的双环或杂环化合物，（b）具有次甲基碳原子的化合物，（c）在与不饱和键相邻的位置具有甲基或亚甲基的化合物，（d）在与杂原子相邻位置具有碳 - 氢键的非芳族杂环化合物，和（e）直链烷烃。硫氧化物包括例如二氧化硫。该生产方法可以在温和条件下有效地生产有机硫酸或其盐。

2. 发明授权

EP0990631B1 PROCESS FOR COOXIDIZING ORGANIC COMPOUNDS 有权
标题翻译：有机化合物方法共氧化
公开(公告)号：EP0990631B1
公开(公告)日：2007-01-24
申请号：EP99909321.4
申请日：1999-03-23
申请人： DAICEL CHEMICAL INDUSTRIES, LTD.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya
IPC分类号： C07B41/00 , C07B33/00 , C07D301/06 , C07D303/04 , C07D303/14 , C07D303/16 , B01J31/02 , C07D315/00
CPC分类号： C07B41/12 , B01J31/006 , B01J31/0231 , B01J31/0247 , B01J31/0271 , B01J31/20 , B01J31/2208 , B01J2231/70 , B01J2231/72 , B01J2531/64 , B01J2531/845 , C07D315/00
摘要： A process for cooxidizing organic compounds which comprises, in the presence of an imide compound such as N-hydroxyphthalimide, oxidizing with molecular oxygen a compound (A) which is selected from among (A1) compounds having nonaromatic ethylenic linkage and (A2) ketones or alcohols corresponding to the ketones and a compound (B) which can be oxidized by the above imide compound with oxygen and is different from the above compound (A). As the compound (B), use can be made of (a) primary or secondary alcohols (benzhydrol, cyclohexanol, etc.), and (b) compounds having a carbon-hydrogen bond adjacent to an unsaturated bond (tetralin, ethylbenzene, etc.). Use of this process makes it possible to obtain the corresponding epoxy compounds from (A1) compounds having nonaromatic ethylenic linkage, and the corresponding esters or lactones from (A2) ketones or alcohols corresponding to the ketones, each at a high yield.

3. 发明授权

EP0915077B1 POLYMERIZABLE ADAMANTANE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME 失效
标题翻译：用于生产聚合金刚烷衍生物和过程
公开(公告)号：EP0915077B1
公开(公告)日：2004-11-17
申请号：EP98919559.9
申请日：1998-05-12
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya , HIRAI, Naruhisa
IPC分类号： C07C67/08 , C07C69/54 , C07C69/732 , C07C201/12 , C07C205/05 , C07C231/02 , C07C233/25 , B01J27/10 , B01J31/22 , C08F20/10 , C08F16/14
CPC分类号： C07C67/03 , C07C2603/74 , C07C69/54
摘要： High yields of polymerizable adamantane derivatives each having at least one polymerizable unsaturated group are produced by the esterification or amidation of a compound of general formula (1a) and a polymerizable unsaturated compound (e.g. an alcohol, a carboxylic acid or an amine) in the presence of a catalyst comprising a compound of a Group 3 element of the periodic table, such as a samarium compound. In said formula, R?1a to R4a¿ represent each a substituent selected from among inert atoms, inert groups, hydroxyl, carboxyl and amino, provided at least two groups of R?1a to R4a¿ are hydroxyl, carboxyl or amino.

4. 发明公开

EP1338336A1 CATALYSTS COMPRISING N-SUBSTITUTED CYCLIC IMIDES AND PROCESSES FOR PREPARING ORGANIC COMPOUNDS WITH THE CATALYSTS 有权
标题翻译： N-取代环形IMID含催化剂的FOR有机化合物的生产中使用
公开(公告)号：EP1338336A1
公开(公告)日：2003-08-27
申请号：EP01996429.5
申请日：2001-11-08
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya , IWAHAMA, Takahiro , HIRAI, Naruhisa
IPC分类号： B01J31/02 , C07C27/12 , C07C33/20 , C07C49/78 , C07C51/21 , C07C51/265 , C07C55/14 , C07C63/04 , C07C63/06 , C07C63/26 , C07C63/313 , C07D213/80 , C07D215/54
CPC分类号： C07C45/34 , B01J23/34 , B01J23/75 , B01J31/0247 , B01J31/2208 , B01J2231/348 , B01J2231/42 , B01J2531/72 , B01J2531/845 , C07C45/00 , C07C45/33 , C07C45/36 , C07C51/265 , C07C51/313 , C07D207/46 , C07D209/48 , C07D215/54 , Y02P20/55 , C07C49/403 , C07C49/78 , C07C65/32 , C07C63/26 , C07C63/04 , C07C55/14
摘要： A catalyst of the invention includes an imide compound having a N-substituted cyclic imide skeleton represented by following Formula (I):
wherein R is a hydroxyl-protecting group. Preferred R is a hydrolyzable protecting group. R may be a group obtained from an acid by eliminating an OH group therefrom. Such acids include, for example, carboxylic acids, sulfonic acids, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acids and boric acids. The catalyst may include the imide compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.

5. 发明公开

EP1178031A1 PROCESS FOR THE PREPARATION OF ORGANIC COMPOUNDS WITH MANGANESE CATALYSTS OR THE LIKE 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG ORGANISCHER VERBINDUNGEN MIT MANGANKATALYSATORENODERÄHNLICHENVERBINDUNGEN
公开(公告)号：EP1178031A1
公开(公告)日：2002-02-06
申请号：EP01912189.6
申请日：2001-03-08
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , IWAHAMA, Takahiro , SAKAGUCHI, Satoshi , NAKANO, Tatsuya
IPC分类号： C07C45/69
CPC分类号： C07C403/02 , C07C45/33 , C07C45/69 , C07C51/56 , C07C67/347 , C07C253/30 , C07C2601/14 , C07D307/20 , C07D307/33 , C07D307/83 , C07D313/04 , C07C49/413 , C07C49/403 , C07C49/395 , C07C49/82 , C07C49/683 , C07C49/04 , C07C55/21 , C07C69/708 , C07C69/34 , C07C69/716 , C07C255/04
摘要： A process of the present invention produces an organic compound by allowing a compound containing an electron attractive group of following Formula (1):

wherein Y is an electron attractive group; and R b and R c are each a hydrogen atom or an organic group, where Y, R b and R c may respectively be combined with each other to form a ring with an adjacent carbon atom, to react with a compound containing an unsaturated carbon-carbon bond of following Formula (2) or (7):

wherein R d , R e , R f , R g , R i and R j are each a hydrogen atom or an organic group, where R d , R e , R f and R g may respectively be combined to form a ring with one or two adjacent carbon atoms, and R i and R j may be combined to form a ring with adjacent two carbon atoms,
in the presence of oxygen and a catalytic compound of a Group 5, 6, 7, 8 or 9 element of the Periodic Table of Elements to yield a compound of following Formula (3) or (8):

wherein Z is a hydrogen atom or a hydroxyl group; and Y, R b , R c , R d , R e , R f , R g , R i and R j have the same meanings as defined above. This process can efficiently produce a compound having an alkyl group or alkenyl group bonded at the alpha position of an electron attractive group, or a derivative thereof, by catalytic radical addition reaction.
摘要翻译：本发明的方法通过使含有下式（1）的电子吸引基团的化合物：其中Y是吸电子基团的产生有机化合物; R和R c分别为氢原子或有机基团，其中Y，R和R c可以分别相互结合形成具有相邻碳原子的环，至与下列式（2）或（7）的含有不饱和碳 - 碳键的化合物反应：其中R d，R e，R f，R g，和R j各自为氢原子或有机基团，其中R d，R e，R f和R g可以分别结合形成具有一个或两个相邻碳原子的环，R 1和R 7可以在氧的存在下和元素周期表第5,6,7,8或9族元素的催化化合物的存在下组合形成具有相邻两个碳原子的环的元素，得到下式（3）或（8）的化合物：其中Z是氢原子或羟基; 并且Y，R b，R c，R d，R e，R f，R g，R i和R j具有与上述相同的含义。该方法可以通过催化自由基加成反应有效地制备具有在吸电子基团的α位上键合的烷基或烯基的化合物或其衍生物。

6. 发明公开

EP0990632A1 ADAMANTANEMETHANOL DERIVATIVES AND PROCESS FOR THE PREPARATION THEREOF 审中-公开
标题翻译：维他命MADHANOL-DERIVATE UND VERFAHREN ZU IHRER HERSTELLUNG
公开(公告)号：EP0990632A1
公开(公告)日：2000-04-05
申请号：EP99917071.5
申请日：1999-04-21
申请人： Daicel Chemical Industries, Ltd.
发明人： NAKANO, Tatsuya , SHIMOJITOSYO, Hiroshi
IPC分类号： C07C31/137 , C07C31/27 , C07C35/37 , C07C29/143 , C07C29/147 , C07C43/196 , C07C41/26
CPC分类号： C07C31/278 , C07C31/137 , C07C43/315 , C07C2603/74 , Y02P20/55
摘要： An adamantanemethanol derivative of the invention is represented by the following formula (1), wherein R a is a hydrogen atom or a hydrocarbon group; R b is a hydrocarbon group having a carbon atom, to which carbon atom at least one hydrogen atom is bonded, at a bonding site with the adjacent carbon atom; R c , R d and R e are each a hydrogen atom, a hydroxyl group which may be protected by a protective group or the like; provided that a hydroxyl group protected by a protective group or the like is bonded to at least one carbon atom constituting the adamantane skeleton when R a is a hydrogen atom or a methyl group and R b is a methyl group; and at least one substituent, in addition to the HO-C(R a )(R b )- group indicated in the formula (1), is bonded to the adamantane ring when one of R a and R b is a methyl group and the other is an ethyl group.
摘要翻译：本发明的金刚烷甲醇衍生物由下式（1）表示，其中R a是氢原子或烃基; R b是在与相邻碳原子的键合位置处具有与碳原子键合至少一个氢原子的碳原子的烃基; R c，R d和R e各自为氢原子，可被保护基等保护的羟基; 条件是当R a为氢原子或甲基且R b为甲基时，由保护基等保护的羟基与构成金刚烷骨架的至少一个碳原子键合; 并且除了式（1）中所示的HO-C（R a）（R））基团之外，至少一个取代基与R a和R R之一键合到金刚烷环上 b是甲基，另一个是乙基。

7. 发明公开

EP0824962A1 OXIDATION CATALYST SYSTEM AND PROCESS FOR OXIDATION WITH THE SAME 失效
标题翻译：氧化铝制氧化铝系统
公开(公告)号：EP0824962A1
公开(公告)日：1998-02-25
申请号：EP97902584.8
申请日：1997-02-06
申请人： DAICEL CHEMICAL INDUSTRIES, LTD.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya
IPC分类号： B01J31/12
CPC分类号： C07C51/313 , B01J31/006 , B01J31/0247 , B01J31/2234 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/22 , B01J2531/26 , B01J2531/31 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07B2200/09 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07C49/453 , C07C49/675 , C07C51/265 , C07C2601/10 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/20 , C07C2602/28 , C07C2602/42 , C07C2603/18 , C07C2603/68 , C07C2603/74 , C07C2603/78 , C07C2603/86 , C07C49/385 , C07C49/413 , C07C49/403 , C07C49/597 , C07C49/603 , C07C49/607 , C07C47/542 , C07C47/565 , C07C49/76 , C07C49/78 , C07C65/21 , C07C63/16 , C07C63/26 , C07C63/06 , C07C65/03 , C07C55/14 , C07C55/18 , C07C55/20 , C07C35/06 , C07C35/20 , C07C35/37 , C07C35/28 , C07C35/36 , C07C35/44 , C07C35/32 , C07C35/38 , C07C35/08 , C07C33/035 , C07C35/18 , C07C35/30
摘要： A substrate (e.g., a cycloalkane, a polycyclic hydrocarbon, an aromatic compound having a methyl group or methylene group adjacent to an aromatic ring) is oxidized with oxygen in the presence of an oxidation catalyst comprising an imide compound of the following formula (1) (e.g., N-hydroxyphthalimide), and a co-catalyst (except phosphovanadomolybdic acid) containing an element selected from the group consisting of Group 2A elements of the Periodic Table of Elements, transition metals (Group 3A to 7A elements, Group 8 elements, Group 1B elements and Group 2B elements of the Periodic Table of Elements) and Group 3B elements of the Periodic Table of Elements, for the formation of an oxide (e.g., a ketone, an alcohol, a carboxylic acid):
wherein R 1 and R 2 represent a substituent such as a hydrogen atom or a halogen atom, or R 1 and R 2 may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.
摘要翻译：在含有下式（1）的酰亚胺化合物的氧化催化剂的存在下，用氧氧化底物（例如环烷烃，多环烃，具有与芳环相邻的甲基或亚甲基的芳族化合物）（例如N-羟基邻苯二甲酰亚胺），以及含有选自元素周期表的2A族元素，过渡金属（3A〜7A族，第8族元素）的元素的助催化剂（除了含钼钒钼酸除外）元素周期表的1B族元素和2B族元素）和元素周期表3B族元素，用于形成氧化物（例如酮，醇，羧酸）：其中R R 1和R 2代表取代基如氢原子或卤原子，或者R 1和R 2可以一起形成双键或芳族或非芳族的5至12元环， X为O或OH，n为1〜3。

8. 发明授权

EP1055654B1 PROCESS FOR THE PREPARATION OF ORGANIC COMPOUNDS WITH IMIDE CATALYSTS 有权
标题翻译：用于生产有机化合物IMID催化剂
公开(公告)号：EP1055654B1
公开(公告)日：2008-02-20
申请号：EP99959710.7
申请日：1999-12-09
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , IWAHAMA, Takahiro , NAKANO, Tatsuya
IPC分类号： C07B37/02 , C07B37/04 , C07B41/00 , C07C2/82 , C07C13/615 , C07C29/32 , C07C31/137 , C07C67/333 , C07C69/675 , C07C69/716 , C07C69/732 , B01J31/02 , C07D315/00 , C07D307/32 , C07D307/94 , C07D317/30
CPC分类号： C07D307/33 , B01J31/0247 , C07B2200/09 , C07C2/76 , C07C29/36 , C07C45/33 , C07C45/34 , C07C45/39 , C07C49/323 , C07C49/345 , C07C67/347 , C07C2603/28 , C07C2603/68 , C07C2603/74 , C07D315/00 , C07D317/30 , C08F20/30 , C07C13/615 , C07C69/716 , C07C69/608 , C07C69/675 , C07C69/732 , C07C31/137 , C07C35/36 , C07C35/37
摘要： A process of reacting (A) a compound capable of forming a stable radical which is selected from among (A1) oxygen compounds having carbon-hydrogen bonds at the position adjacent to the oxygen atom, (A2) carbonyl compounds and (A3) compounds having hydrocarbon groups bearing methyne carbon with (B) a radical-scavenging compound selected from among (B1) unsaturated compounds, (B2) compounds having hydrocarbon groups bearing methyne carbon, and so on in the presence of molecular oxygen by the use of an imide catalyst represented by general formula (1) or the like to thereby obtain an adduct of the compound (B) with the compound (A), a product of substitution of the compound (B) with the compound (A), or oxides of both. In said formula, R?1 and R2¿ are each hydrogen or the like, or alternatively R?1 and R2¿ may be united to form a double bond or an aromatic or nonaromatic ring; and X is oxygen or hydroxyl. This process makes it possible to efficiently produce various organic compounds under mild conditions through addition or substitution by the use of molecular oxygen.

9. 发明授权

EP1070678B1 PROCESS FOR PRODUCING HYDROGEN PEROXIDE 有权
标题翻译：生产过氧化氢的方法
公开(公告)号：EP1070678B1
公开(公告)日：2003-05-07
申请号：EP00902029.8
申请日：2000-02-01
申请人： Daicel Chemical Industries, Ltd.
发明人： ISHII, Yasutaka , NAKANO, Tatsuya
IPC分类号： C01B15/026
CPC分类号： C01B15/026

10. 发明公开

EP0897747A1 NITRATION OR CARBOXYLATION CATALYSTS 失效
标题翻译： NITRIERUNGS- ODER CARBOXYLIERUNGSKATALYSATOREN
公开(公告)号：EP0897747A1
公开(公告)日：1999-02-24
申请号：EP98900216.7
申请日：1998-01-13
申请人： Daicel Chemical Industries, Ltd. , Ishii, Yasutaka
发明人： ISHII, Yasutaka , NAKANO, Tatsuya , SAKAGUCHI, Satoshi
IPC分类号： B01J31/02 , B01J31/26 , C07C201/08 , C07C51/10 , C07C61/28 , C07C211/35 , C07C265/10 , C07C205/55 , C07C62/06 , C07C271/24 , C07B43/02 , C07B41/08
CPC分类号： C07C45/36 , B01J31/006 , B01J31/0247 , B01J31/2208 , B01J2231/70 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07B41/08 , C07B43/02 , C07C51/10 , C07C67/12 , C07C69/757 , C07C205/04 , C07C205/05 , C07C205/06 , C07C205/18 , C07C205/55 , C07C211/35 , C07C211/37 , C07C215/42 , C07C229/50 , C07C233/10 , C07C233/14 , C07C233/23 , C07C233/41 , C07C233/52 , C07C233/58 , C07C233/62 , C07C235/40 , C07C235/82 , C07C237/24 , C07C265/10 , C07C271/24 , C07C2603/74 , C07C49/78 , C07C61/29 , C07C61/135
摘要： In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1):
wherein R 1 and R 2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group and a cycloalkyl group, and R 1 and R 2 may bond together to form a double bond, or an aromatic or non-aromatic ring, and Y is an O or OH, and n denotes 1 to 3;
a substrate is allowed to contact with at least one reactant selected from (i) a nitrogen oxide and (ii) a mixture of carbon monoxide and oxygen to be introduced with at least one functional group selected from a nitro group and a carboxyl group. The nitrogen oxide includes, for example, a compound represented by the formula N x O y (e.g., N 2 O 3 , NO 2 ). The substrate includes, for example, a compound having a methine carbon atom (e.g., adamantane), a compound having a methyl group or a methylene group at an adjacent moiety of an aromatic ring. According to such reaction, the substrate can be efficiently nitrated or carboxylated even in a mild or moderate condition.
摘要翻译：在下式（1）所示的酰亚胺化合物（例如N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2表示氢原子，卤素原子，烷基，芳基和环烷基，R 1和R 2可以键合在一起形成双键，或芳族或非芳香环，Y是O或OH，n表示1至3; 允许底物与选自（i）氮氧化物和（ii）一氧化碳和氧气的混合物中的至少一种反应物接触，以将至少一种选自硝基和羧基的官能团引入。氮氧化物包括例如由式N x O y表示的化合物（例如，N 2 O 3，NO 2）。底物包括例如具有次甲基碳原子的化合物（例如金刚烷），在芳环的相邻部分具有甲基或亚甲基的化合物。根据这种反应，即使在温和或中等条件下，底物也能被有效地硝化或羧化。

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