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    • 7. 发明公开
    • SUBSTITUIERTE QUATERRYLENTETRACARBONSÄUREDIIMIDE
    • SUBSTITUIERTEQUATERRYLENTETRACARBONSÄUREDIIMIDE
    • EP0804507A1
    • 1997-11-05
    • EP96900944.0
    • 1996-01-12
    • BASF AKTIENGESELLSCHAFTMax-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Berlin
    • MÜLLEN, KlausQUANTE, HeribertBÖHM, Arno
    • C07D221C07D471C09B5C09B57
    • C07D221/18C09B5/62
    • The invention concerns quaterrylene tetracarboxylic acid diimides of formula (I), in which the variables have the following meanings: R represents hydrogen; C1-C30-alkyl whose carbon chain can be interrupted by one or more of the groupings -O-, -S-, -NR1-, -CO- and/or -SO¿2?- and which can be singly or multiply substituted by cyano, C1-C6-alkoxy or a 5-7 member heterocyclic group, bound by a nitrogen atom, which can contain additional heteroatoms and can be aromatic; R?1¿ then represents hydrogen or C¿1?-C6 alkyl; C5-C8 cycloalkyl whose carbon skeleton can be interrupted by one or more of the groupings -O-, -S- and/or -NR?1¿-, aryl or hetaryl which can be singly or multiply substituted by C¿1?-C18 alkyl, C1-C6 alkoxy, cyano, -CONHR?2¿, -NHCOR2 and/or aryl or a hetarylazo which itself can be substituted by C¿1?-C10 alkyl, C1-C6 alkoxy or cyano; R?2¿ represents hydrogen; C¿1?-C18 alkyl or hetaryl which can be substituted by C1-C6 alkyl, C1-C6 alkoxy, halogen or cyano; X represents hydrogen; C1-C18 alkyl; aryloxy, arylthio, hetaryloxy or hetarylthio which can be substituted by C1-C4 alkyl or C1-C4 alkoxy; n is a number between 2 and 12. The invention also concerns the production of the said compounds and their use as pigments or fluorescent dyes, and substituted 9-haloperylene-3,4-dicarboxylic acid imides III as their intermediate products.
    • 本发明涉及式(I)的四萘嵌苯四羧酸二酰亚胺,其中各变量具有以下含义:R表示氢; 其碳链可以被-O - , - S - , - NR 1 - , - CO-和/或-SO 2 - 基团中的一个或多个基团间断的C 1 -C 30烷基,并且可以被单取代或多取代 由氰基,C1-C6-烷氧基或5-7元杂环基团结合,所述杂环基团可以含有另外的杂原子并且可以是芳族的; R 1'代表氢或C 1 -C 6烷基; 其碳骨架可以被一个或多个-O-,-S-和/或-NR'1-, - 芳基或杂芳基中的一个或多个基团间隔的C5-C8环烷基,其可以被C1- C18烷基,C1-C6烷氧基,氰基,-CONHR2',-NHCOR2和/或芳基或杂芳基,其本身可以被C1-C10烷基,C1-C6烷氧基或氰基取代; R 2'代表氢; 可以被C1-C6烷基,C1-C6烷氧基,卤素或氰基取代的C1-C18烷基或杂芳基; X代表氢; C1-C18烷基; 可以被C1-C4烷基或C1-C4烷氧基取代的芳氧基,芳硫基,杂芳氧基或杂芳硫基; n是2和12之间的数。本发明还涉及所述化合物的制备及其作为颜料或荧光染料以及作为其中间产物的取代的9-卤代苝-3,4-二羧酸酰亚胺III的用途。