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    • 82. 发明公开
    • Electrochemical surface analysis using deoxygenated gel electrolyte
    • ElektrochemischeOberflächenanalyseunter Verwendung eines sauerstofffreien Gelelektrolyten
    • EP0711997A2
    • 1996-05-15
    • EP95112705.9
    • 1995-08-11
    • ROCKWELL INTERNATIONAL CORPORATION
    • White, John T.Tench, Morgan, D.
    • G01N27/416
    • B23K31/12B23K2201/36
    • Electrochemical surface analysis using a deoxygenated gel electrolyte provides advantages over a liquid electrolyte in processes such as sequential electrochemical reduction analysis. In sequential electrochemical reduction analysis, a solderable portion of an electronic component or circuit board to be tested is placed in contact with a deoxygenated gel electrolyte such as a borate buffer solution having a gelling agent. The gel electrolyte prevents capillary attraction up or along a lead of the component so that the power source cathode lead does not contact the electrolyte and electrochemical analysis can be localized to the area of interest, such as the portion of the component lead to be soldered. Interfering effects of atmospheric oxygen are minimized for deaerated gel electrolytes because convection mixing is practically absent and diffusion is generally a very slow process in a gel. For a gel electrolyte saturated with inert gas and including an oxygen scavenger, brief exposure to oxygen as test specimens are changed does not affect the electrochemical analysis. In some cases, it is be possible to perform electrochemical analysis in ambient atmosphere rather than in an inert gas as generally required by the prior art.
    • 使用脱氧凝胶电解质的电化学表面分析在诸如顺序电化学还原分析的方法中提供了优于液体电解质的优点。 在顺序电化学还原分析中,将要测试的电子部件或电路板的可焊接部分与脱氧凝胶电解质接触,例如具有胶凝剂的硼酸盐缓冲溶液。 凝胶电解质防止毛细管吸引或沿着部件的引线,使得电源阴极引线不接触电解质,并且电化学分析可以定位到感兴趣的区域,例如待焊接的部件引线的部分。 对于脱气凝胶电解质,大气氧的干扰作用最小化,因为实际上不存在对流混合,而在凝胶中扩散通常是非常缓慢的过程。 对于用惰性气体饱和并含有氧清除剂的凝胶电解质,短时间暴露于氧气作为测试样品,不影响电化学分析。 在一些情况下,可以在环境气氛中进行电化学分析,而不是在现有技术中通常所要求的惰性气体中进行电化学分析。