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    • 62. 发明公开
    • METHOD FOR PRODUCING PURIFIED ACTIVE SILICIC ACID SOLUTION AND SILICA SOL
    • 生产纯化活性硅酸溶液和硅溶胶的方法
    • EP3168191A1
    • 2017-05-17
    • EP16204020.8
    • 2012-09-14
    • Nissan Chemical Industries, Ltd.
    • Ema, KiyomiTakakuma, NoriyukiNishimura, TohruKawashita, NaokiYamaguchi, Kouji
    • C01B33/141C01B33/143C01B33/148C09K3/14C09K13/04
    • C09K3/1463C01B33/1412C01B33/1435C01B33/1485C09K13/04
    • There is provided a method for producing an active silicic acid solution in which the existing amount of foreign matters as plate-like fine particles is reduced and a method for producing a silica sol in which such foreign matters are reduced. A method for producing an active silicic acid solution fulfilling the following condition: (1) the existing amount of plate-like fine particles having a length of one side of 0.2 to 4.0 µm and a thickness of 1 to 100 nm is measured to be 0% to 30% in accordance with measuring method A, the method characterized by including the steps of: preparing an active silicic acid solution by subjecting an alkali silicate aqueous solution having a silica concentration of 0.5% by mass to 10.0% by mass to cation-exchange to remove alkaline components; and filtering the active silicic acid solution through a filter whose removal rate of particles having a primary particle size of 1.0 µm is 50% or more, and whose filtering rate is 13 L/min to 400 L/min per 1 m 2 of the filtration area of the used filter.
    • 本发明提供一种活性硅酸溶液的制造方法,该活性硅酸溶液中减少了作为板状微粒的异物的存在量,并且提供了减少这种异物的二氧化硅溶胶的制造方法。 满足以下条件的活性硅酸溶液的制造方法:(1)将一边的长度为0.2〜4.0μm,厚度为1〜100nm的板状微粒的存在量设为0 所述方法的特征在于包括以下步骤:通过将具有二氧化硅浓度为0.5质量%至10.0质量%的碱金属硅酸盐水溶液进行阳离子聚合来制备活性硅酸溶液, 交换去除碱性成分; 并且通过过滤器对活性硅酸溶液进行过滤,所述过滤器的一次粒径为1.0μm的颗粒的去除率为50%以上,过滤速度为13L / min〜400L / min / 的过滤器。