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    • 3. 发明公开
    • Metal-insulator-metal capacitor and method for manufacturing thereof
    • Metall-Isolier-Metall-Kondensator和Herstellungsverfahrendafür
    • EP2434531A2
    • 2012-03-28
    • EP11182813.3
    • 2011-09-26
    • IMEC
    • Popovici, Mihaela IoanaSwerts, JohanPawlak, MalgorzataTomida, KazuyukiKim, Min-SooKittl, JorgeVan Elshocht, Sven
    • H01L21/02C23C16/455H01L49/02
    • H01L21/02356C23C16/409C23C16/45529H01L21/02197H01L21/0228H01L21/02304H01L28/56
    • The present invention is related to a method for producing a stack of layers on a semiconductor substrate, the method comprising the steps of:
      ● providing a substrate,
      ● producing on said substrate a first conductive layer,
      ● by atomic layer deposition, producing a sub-stack of layers on said conductive layer, at least one of said layers of the sub-stack being a TiO 2 layer, the other layers of the sub-stack being layers of a dielectric material having a composition suitable to form a cubic perovskite phase upon crystallization of said sub-stack of layers,

      The substrate including said sub-stack of layers is subjected to a heat treatment to thereby obtain a crystallized dielectric layer. A second conductive layer is produced before or after the heat treatment so as to obtain a metal-insulator-metal capacitor with improved characteristics as a consequence of the Ti02 layer being present in the sub-stack. Notably, in a MIM capacitor according to the invention, the k-value of the dielectric layer is between 50 and 100 and the EOT of the MIM capacitor is between 0.35nm and 0.55nm.
    • 本发明涉及一种用于在半导体衬底上制备层叠层的方法,所述方法包括以下步骤: - 提供衬底, - 在所述衬底上产生第一导电层, - 通过原子层沉积, 在所述导电层上产生一层子层,所述子堆叠的至少一层是TiO 2层,所述子堆叠的其它层是具有适于形成 在所述子层叠层结晶时立方体的钙钛矿相进行热处理,从而得到包含所述层叠层的基板,从而得到结晶化的介电层。 在热处理之前或之后产生第二导电层,从而获得由于TiO 2层存在于子堆中而具有改进特性的金属 - 绝缘体 - 金属电容器。 值得注意的是,在根据本发明的MIM电容器中,电介质层的k值在50和100之间,MIM电容器的EOT在0.35nm和0.55nm之间。
    • 10. 发明公开
    • Sol-gel processing of piezoelectric and ferroelectric films
    • Sol-Gel Verfahrenfürpiezoelektrische und ferroelektrische Schichten。
    • EP0489519A2
    • 1992-06-10
    • EP91310761.1
    • 1991-11-21
    • RAYTHEON COMPANY
    • Bernstein, Steven D.Wahl, Joseph Matthew
    • H01L21/314H01L21/316C23C18/12H01L21/3205
    • H01L41/1876H01L21/02197H01L21/02356H01L21/31691H01L28/55H01L41/318
    • A method of providing a perovskite film having a general chemical formula of ABO₃ over a substrate includes the steps of providing (42,44,46,48,50,52) a sol-gel solution of composition of A and B using alkoxides in organic salts and depositing (54) the sol-gel solution as a thin film over the substrate . The film is converted into the perovskite film by rapidly heating (56) the thin film. Preferred perovskite materials include lead zirconate titanate. In one embodiment the films are deposited from sol-gel solutions containing lead, zirconium, and titanium and are converted (58) to a lead zirconate titante crystalline material in an atmosphere of oxygen to provide a ferroelectric dielectric having a high remanent polarization. In an alternate embodiment (Fig. 3), the sol-gel solution of lead, zirconium, and titanium is converted (62) to lead zirconate titanate crystalline material in a non-oxidizing atmosphere of an inert gas, nitrogen, or forming gas to provide materials having high dielectric constants and high and substantially linear dielectric constants with respect to applied voltages.
    • 在衬底上提供具有一般化学式ABO 3的钙钛矿膜的方法包括以下步骤:使用有机物中的醇盐提供(42,44,46,48,50,52)A和B组合物的溶胶 - 凝胶溶液 盐,并将溶胶 - 凝胶溶液(54)作为薄膜沉积在基材上。 通过快速加热(56)薄膜,将膜转变成钙钛矿膜。 优选的钙钛矿材料包括锆钛酸铅。 在一个实施方案中,薄膜由含有铅,锆和钛的溶胶 - 凝胶溶液沉积,并在氧气氛中将其转化为锆锆酸铅钛结晶材料,以提供具有高残留极化的铁电电介质。 在替代实施方案(图3)中,将铅,锆和钛的溶胶 - 凝胶溶液在惰性气体,氮气或形成气体的非氧化性气氛中转化(62)为锆钛酸铅晶体材料, 提供相对于施加的电压具有高介电常数和高且基本线性介电常数的材料。