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1. 发明授权

US06670406B2 Process for producing polyether polyols 有权
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US06670406B2
公开(公告)日：2003-12-30
申请号：US10077855
申请日：2002-02-19
申请人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
发明人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
IPC分类号： C07C4311
CPC分类号： B01J19/2465 , C08G65/2663 , C08G65/2696
摘要： The present invention relates to a process for the production of a polyether polyol by polyaddition of an alkylene oxide onto a starter compound containing active hydrogen atoms conducted in the presence of a double metal cyanide catalyst comprising conducting a reaction mixture at least once through a zone which has an energy density of at least 5×106 J/m3, wherein the dwell time of the reaction mixture in this zone is at least 10−6 seconds per pass.
摘要翻译：本发明涉及一种生产聚醚多元醇的方法，该方法是通过在双金属氰化物催化剂的存在下将烯化氧加成到含有活性氢原子的起始化合物上，包括将反应混合物至少一次通过一个具有至少5×10 6 J / m 3的能量密度，其中该区域中反应混合物的停留时间为每次通过至少10 -6秒。

2. 发明授权

US06620976B2 Polyethylene glycol and process for producing the same 有权
标题翻译：聚乙二醇及其制造方法
公开(公告)号：US06620976B2
公开(公告)日：2003-09-16
申请号：US10106219
申请日：2002-03-27
申请人： Kenji Sakanoue , Kouzoh Sanchika , Tohru Yasukohchi
发明人： Kenji Sakanoue , Kouzoh Sanchika , Tohru Yasukohchi
IPC分类号： C07C4311
CPC分类号： C08G65/2609 , C08L2203/02
摘要： Polyethylene glycol for use in fields with application to a living body wherein the sum of the contents of ethylene glycol and diethylene glycol in the polyethylene glycol is less than or equal to that expressed in the following formula [I]: Sum ⁢ ⁢ of ⁢ ⁢ ethylene ⁢ ⁢ glycol ⁢ ⁢ and ⁢ ⁢ diethylene ⁢ ⁢ glycol ⁢ ⁢ contents ⁢ ⁢ ( ppm ) = 150 × 2900 × 0.85 ( x - 150 ) / 44 x [ I ] wherein x represents the average molecular weight of the polyethylene glycol, and the polyethylene glycol has an average molecular weight ranging from 190 to 1,050.
摘要翻译：聚乙二醇用于应用于生物体的领域，其中聚乙二醇中乙二醇和二甘醇的含量之和小于或等于下式[I]表示：其中x表示平均分子量聚乙二醇的重量，聚乙二醇的平均分子量为190〜1050。

3. 发明授权

US06495727B1 Process for preparing ether-capped poly(oxyalkylated) alcohol surfactants 失效
标题翻译：制备醚封端的聚（烷氧基化）醇表面活性剂的方法
公开(公告)号：US06495727B1
公开(公告)日：2002-12-17
申请号：US09831117
申请日：2001-05-04
申请人： Glenn Thomas Jordan, IV , Larry Eugene Miller , Donald Eugene Levengood , Mark Robert Sivik , Bernard William Kluesener , Terry Franklin Formyduval , Deborah Jean Back
发明人： Glenn Thomas Jordan, IV , Larry Eugene Miller , Donald Eugene Levengood , Mark Robert Sivik , Bernard William Kluesener , Terry Franklin Formyduval , Deborah Jean Back
IPC分类号： C07C4311
CPC分类号： B01F17/0028 , C08G65/22 , C08G65/2609 , C08G2650/06 , C08G2650/34 , C11D1/721
摘要： A process for preparing an ether-capped poly(oxyalkylated) alcohol surfactant having the formula R1O[CH2CH(R3)O]xCH2CH(OH)CH2OR2 wherein R1 and R2 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having from 1 to about 30 carbon atoms; R3 is H, or a linear aliphatic hydrocarbon radical having from 1 to about 4 carbon atoms; x is an integer having an average value from 1 to about 30, wherein when x is about 2 or greater R3 may be the same or different; further wherein when x is about 15 or greater and R3 is H and methyl, at least four of R3 are methyl, further wherein when x is about 15 or greater and R3 includes H and from 1 to 3 methyl groups, then at least one R3 is ethyl, propyl or butyl, further wherein R2 can optionally be alkoxylated, wherein said alkoxy is selected from ethoxy, propoxy, butoxy and mixtures thereof; said process comprising the steps of: (b) providing a glycidyl ether having the formula: wherein R2 is defined as above; (c) providing an ethoxylated alcohol having the formula: wherein R1, R3 and x are defined as above; (f) reacting said glycidyl ether with said ethoxylated alcohol to form said surfactant in the presence of a basic catalyst; (g) said surfactant is sparged with an inert gas, preferably N2, Ar and mixtures thereof, optionally under vacuum, preferably a vacuum in the range of 5 to 500 mmHg; and said surfactant is bleached with an about 0.05% to about 5.0%, preferably about 0.1% to about 1.0%, by weight solution of a bleach at a temperature from about 25° C. to about 95° C.
摘要翻译：制备具有式R 1和R 2的醚的聚（烷氧基化）醇表面活性剂的方法是具有1至约30个碳原子的直链或支链，饱和或不饱和的脂族或芳族烃基; R3是H或具有1至约4个碳原子的直链脂族烃基; x是平均值为1至约30的整数，其中当x为约2或更大时，R 3可以相同或不同; 其中当x为约15或更大且R 3为H和甲基时，R 3中的至少4个为甲基，此外，当X为约15或更大且R 3包括H和1至3个甲基时，则至少一个R 3 乙基，丙基或丁基，其中R 2可任选地被烷氧基化，其中所述烷氧基选自乙氧基，丙氧基，丁氧基及其混合物; 所述方法包括以下步骤：（b）提供具有下式的缩水甘油醚：其中R2如上定义;（c）提供具有下式的乙氧基化醇：其中R1，R3和x如上定义;（f）使所述缩水甘油醚与所述乙氧基化醇反应以在碱性催化剂存在下形成所述表面活性剂;（g）任选地在真空下，优选在该范围内的真空下，用惰性气体，优选N 2，Ar及其混合物喷射所述表面活性剂为5〜500mmHg; 漂白剂在约25℃至约95℃的温度下漂白约0.05％至约5.0％，优选约0.1％至约1.0％的漂白剂。

4. 发明授权

US06469217B2 Process for preparing fluoropolymer 有权
标题翻译：制备含氟聚合物的方法
公开(公告)号：US06469217B2
公开(公告)日：2002-10-22
申请号：US09845888
申请日：2001-04-30
申请人： Satoru Saito , Haruyoshi Tatsu , Vera Grinevskaya
发明人： Satoru Saito , Haruyoshi Tatsu , Vera Grinevskaya
IPC分类号： C07C4311
CPC分类号： B01J31/0232 , B01J31/0209 , B01J2231/48 , C08G65/226 , C08G65/2639
摘要： The polymerization initiator-containing solution obtained by mixing a specific perfluorodicarboxylic acid fluoride (A) with CsF in an aprotic polar solvent with stirring to conduct reaction and thereby form a polymerization initiator (B) and then allowing the reaction solution to stand for not less than 72 hours at a temperature of 0 to 30° C. A polymerization initiator-containing solution comprises a specific polymerization initiator (B′) and an aprotic polar solvent. The process for preparing a perfluoropolyether comprises polymerizing hexafluoropropylene oxide in the presence of the polymerization initiator-containing solution.
摘要翻译：通过在搅拌下将特定的全氟二羧酸氟化物（A）与CsF混合在搅拌下得到的含聚合引发剂的溶液进行反应，从而形成聚合引发剂（B），然后使反应溶液静置不少于在0〜30℃的温度下72小时。含聚合引发剂的溶液包含特定的聚合引发剂（B'）和非质子极性溶剂。制备全氟聚醚的方法包括在含聚合引发剂的溶液的存在下聚合六氟环氧丙烷。

5. 发明授权

US06376645B1 Complexing agent-modified hexacyanometallate hexanitrometallate catalysts 失效
标题翻译：络合剂改性六氰基金属螯合物六苯甲酸盐催化剂
公开(公告)号：US06376645B1
公开(公告)日：2002-04-23
申请号：US09574925
申请日：2000-05-19
申请人： David E. Laycock , Kendra L. Flagler , Robert J. Gulotty, Jr.
发明人： David E. Laycock , Kendra L. Flagler , Robert J. Gulotty, Jr.
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , B01J27/26
摘要： Metal [hexacyanometallate hexanitrometallate] complexes are useful alkylene oxide polymerization catalysts. The metal is any that forms a precipitate with hexacyanometallate and hexanitrometallate groups. These catalysts are made from less expensive raw materials than the common zinc hexacyanocobaltate catalysts, and provide short induction periods and in many cases more controlled exotherms.
摘要翻译：金属[hexacyanometallate hexanitrometallate]复合物是有用的环氧烷聚合催化剂。金属是任何与六氰基金属盐酸盐和己氮铝酸盐基团形成沉淀物的金属。这些催化剂由比普通的六氰合钴酸锌催化剂更便宜的原料制成，并且提供短的诱导期，并且在许多情况下是更受控制的放热。

6. 发明授权

US06323375B1 Crystalline double metal cyanide catalysts for producing polyether polyols 有权
标题翻译：用于生产聚醚多元醇的结晶双金属氰化物催化剂
公开(公告)号：US06323375B1
公开(公告)日：2001-11-27
申请号：US09509979
申请日：2000-04-05
申请人： Jörg Hofmann , Pramod Gupta , Robert-Joseph Kumpf , Pieter Ooms , Walter Schäfer , Michael Schneider
发明人： Jörg Hofmann , Pramod Gupta , Robert-Joseph Kumpf , Pieter Ooms , Walter Schäfer , Michael Schneider
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , B01J27/26
摘要： The present invention relates to highly active, substantially crystalline double metal cyanide (DMC) catalysts, a process for the preparation of these double metal cyanide catalysts, a process for producing polyether polyols by the polyaddition of alcohol ethers onto starter compounds containing active hydrogen atoms from these DMC catalysts, and to the polyether polyols produced by this process. The DMC catalysts of the invention comprise a) double metal cyanide compounds, b) organic complexing ligands, and c) functionalized polymers. These catalysts exhibit increased activity in the process for the production of polyether polyols.
摘要翻译：本发明涉及高活性，基本上结晶的双金属氰化物（DMC）催化剂，制备这些双金属氰化物催化剂的方法，通过将醇醚加成到含有活性氢原子的起始化合物上制备聚醚多元醇的方法这些DMC催化剂，以及通过该方法制备的聚醚多元醇。本发明的DMC催化剂包括a）双金属氰化物化合物，b）有机络合配体，和c）官能化聚合物。这些催化剂在制备聚醚多元醇的方法中表现出增加的活性。

7. 发明授权

US06673972B2 Method for producing polyetherpolyols in the presence of a multi-metal cyanide complex catalyst 失效
标题翻译：在多金属氰化物配合物催化剂存在下制备聚醚多元醇的方法
公开(公告)号：US06673972B2
公开(公告)日：2004-01-06
申请号：US10169683
申请日：2002-07-05
申请人： Thomas Ostrowski , Kathrin Harre , Peter Zehner , Jörn Müller , Dieter Stützer , Georg Heinrich Grosch , Jürgen Winkler , Stephan Bauer
发明人： Thomas Ostrowski , Kathrin Harre , Peter Zehner , Jörn Müller , Dieter Stützer , Georg Heinrich Grosch , Jürgen Winkler , Stephan Bauer
IPC分类号： C07C4311
CPC分类号： C08G65/2696 , B01J27/26 , C08G65/2663
摘要： Polyetherpolyols are prepared by reacting diols or polyols with ethylene oxide, propylene oxide, butylene oxide or a mixture thereof in the presence of a multimetal cyanide complex catalyst by a process which is carried out in a vertical upright cylindrical reactor comprising a jet nozzle which is arranged in the upper reactor region and is directed downward and via which the starting materials and the reaction mixture are fed in, and comprising a take-off, preferably in the lower reactor region, via which the reaction mixture is fed back to the jet nozzle in an external circulation by means of a pump via an equilibration container, comprising a concentric guide tube which extends over the total length of the reactor, except for the reactor ends, and comprising a heat exchanger integrated in the annular space.
摘要翻译：聚醚多元醇通过二元醇或多元醇与环氧乙烷，环氧丙烷，环氧丁烷或其混合物在多金属氰化物配合物催化剂存在下反应来制备，该方法是在包括喷嘴的立式圆柱形反应器中进行的方法，在上反应器区域中并且向下引导起始材料和反应混合物，并且优选在较低的反应器区域中包含起飞物料，反应混合物经反应器区域被反馈到喷嘴中通过平衡容器通过泵的外部循环，包括在反应器的整个长度上延伸的同心引导管，除了反应器端部，并且包括集成在环形空间中的热交换器。

8. 发明授权

US06388048B1 Complexing agent-modified trimetal cyanide catalyst 失效
标题翻译：络合剂改性三氰甲基氰催化剂
公开(公告)号：US06388048B1
公开(公告)日：2002-05-14
申请号：US09574924
申请日：2000-05-19
申请人： David E. Laycock , Kendra L. Flagler , Robert J. Gulotty, Jr.
发明人： David E. Laycock , Kendra L. Flagler , Robert J. Gulotty, Jr.
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , C08G65/10
摘要： Metal [hexacyanocobaltate, cobalthexanitrite nitroferricyanide] complexes are useful alkylene oxide polymerization catalysts. The metal is any that forms a precipitate with the hexacyanocobaltate, cobalthexanitrite and nitroferricyanide groups. These catalysts are made from less expensive raw materials than the common zinc hexacyanocobaltate catalysts, and provide short induction periods and many cases more controlled exotherms. In addition, the metal [hexacyanocobaltate, cobalthexanitrite nitroferricyanide] catalysts often provide poly(propylene oxide) polymers having very low unsaturations, even when the catalyst is complexed with a complexing agent such as glyme.
摘要翻译：金属[六氰合钴酸钴，钴六硝基硝基铁氰化物]配合物是有用的环氧烷聚合催化剂。金属是与六氰基钴酸盐，钴六亚硝酸盐和硝基氰化物基团形成沉淀物的任何物质。这些催化剂由比普通的六氰合钴酸锌催化剂更廉价的原料制成，并且提供短的诱导期和许多情况下更有控制的放热。此外，即使当催化剂与络合剂如甘醇二甲醚络合时，金属[六氰合钴酸盐，钴六硝基硝基铁氰化物]催化剂通常提供具有非常低不饱和度的聚（环氧丙烷）聚合物。

9. 发明授权

US06362312B1 Catalyst and method for the production of polytetrahydrofuran 失效
标题翻译：用于生产聚四氢呋喃的催化剂和方法
公开(公告)号：US06362312B1
公开(公告)日：2002-03-26
申请号：US09529180
申请日：2000-04-10
申请人： Karsten Eller , Heinz Rütter , Michael Hesse , Rainer Becker
发明人： Karsten Eller , Heinz Rütter , Michael Hesse , Rainer Becker
IPC分类号： C07C4311
CPC分类号： C08G65/20 , C08G61/125 , C08G65/2657
摘要： In a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters thereof comprises polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer over an acid-activated calcium montmorillonite as catalyst, the calcium montmorillonite has a BET surface area of at least 300 m2/g, an acidity of at least 0.02 mmol/g at pKa
摘要翻译：在制备聚四氢呋喃的方法中，聚四氢呋喃共聚物或二酯或其单酯包括在至少一种前体和/或共聚单体存在下，在酸活化的钙蒙脱石作为催化剂上聚合四氢呋喃，所述钙蒙脱石的BET表面积至少为 300m 2 / g，在pKa <3时酸度至少为0.02mmol / g，孔径在30至200之间的孔体积至少为0.40cm 3 / g。

10. 发明授权

US06303833B1 Multi-metal cyanide complexes as catalysts and their use in preparing polyetherpolyols 有权
标题翻译：多金属氰化物络合物作为催化剂及其在制备聚醚多元醇中的应用
公开(公告)号：US06303833B1
公开(公告)日：2001-10-16
申请号：US09509515
申请日：2000-03-29
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
IPC分类号： C07C4311
CPC分类号： B01J27/26 , C08G65/2663
摘要： A crystalline multimetal cyanide complex of the formula (I) M1a[M2(CN)bL1c]d*e(M1fXg)*hL2′iH2O (I) where M1 is at least one element from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II). Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II, W(IV), W(VI), Cu(II), and Cr(III), M2 is at least one element from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), L1 is at least one ligand from the group consisting of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, X is a formate anion, an acetate anion or propionate anion, L2 is at least one water-miscible ligand from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides, a, b, c, d, e, f, g, h, i are integers, with a, b, c and d being chosen so that the electrical neutrality condition is satisfied, and f and g being chosen so that the electrical neutrality condition is satisfied, the X-ray diffiactogram of which shows reflections at particular d values, can be employed as catalyst.
摘要翻译：式（I）的结晶多金属氰化物络合物，其中M 1是由Zn（II），Fe（II），Co（III），Ni（II），Mn（II），Co（II）组成的组中的至少一种元素），Sn（II）。 Pb（II），Fe（III），Mo（IV），Mo（VI），Al（III），V（IV），V（V）（II），Fe（Ⅲ），Co（Ⅲ），Cr（Ⅲ），Mn（Ⅱ），Mn（Ⅲ）等元素中的至少一种元素，，Ir（III），Rh（III），Ru（II），V（IV），V（V），Co（II）和Cr（II），L1是至少一种由氰化物，羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，X是甲酸根阴离子，乙酸根阴离子或丙酸根阴离子，L2是至少一种与醇，醛，酮，醚，聚醚，酯，尿素衍生物，酰胺，腈和硫化物，a，b，c，d，e，f，g，h，i是整数，其中选择a，b，c和d，使得满足电中性条件，被选择为使得电中性条件满足，其X射线衍射图示出特定d值的反射可用作催化剂。

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