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1. 发明授权

US06303833B1 Multi-metal cyanide complexes as catalysts and their use in preparing polyetherpolyols 有权
标题翻译：多金属氰化物络合物作为催化剂及其在制备聚醚多元醇中的应用
公开(公告)号：US06303833B1
公开(公告)日：2001-10-16
申请号：US09509515
申请日：2000-03-29
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
IPC分类号： C07C4311
CPC分类号： B01J27/26 , C08G65/2663
摘要： A crystalline multimetal cyanide complex of the formula (I) M1a[M2(CN)bL1c]d*e(M1fXg)*hL2′iH2O (I) where M1 is at least one element from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II). Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II, W(IV), W(VI), Cu(II), and Cr(III), M2 is at least one element from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), L1 is at least one ligand from the group consisting of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, X is a formate anion, an acetate anion or propionate anion, L2 is at least one water-miscible ligand from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides, a, b, c, d, e, f, g, h, i are integers, with a, b, c and d being chosen so that the electrical neutrality condition is satisfied, and f and g being chosen so that the electrical neutrality condition is satisfied, the X-ray diffiactogram of which shows reflections at particular d values, can be employed as catalyst.
摘要翻译：式（I）的结晶多金属氰化物络合物，其中M 1是由Zn（II），Fe（II），Co（III），Ni（II），Mn（II），Co（II）组成的组中的至少一种元素），Sn（II）。 Pb（II），Fe（III），Mo（IV），Mo（VI），Al（III），V（IV），V（V）（II），Fe（Ⅲ），Co（Ⅲ），Cr（Ⅲ），Mn（Ⅱ），Mn（Ⅲ）等元素中的至少一种元素，，Ir（III），Rh（III），Ru（II），V（IV），V（V），Co（II）和Cr（II），L1是至少一种由氰化物，羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，X是甲酸根阴离子，乙酸根阴离子或丙酸根阴离子，L2是至少一种与醇，醛，酮，醚，聚醚，酯，尿素衍生物，酰胺，腈和硫化物，a，b，c，d，e，f，g，h，i是整数，其中选择a，b，c和d，使得满足电中性条件，被选择为使得电中性条件满足，其X射线衍射图示出特定d值的反射可用作催化剂。

2. 发明授权

US06441247B1 Method for preparing polyether polyols 失效
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US06441247B1
公开(公告)日：2002-08-27
申请号：US09890119
申请日：2001-07-26
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
IPC分类号： C07L4311
CPC分类号： C08G65/2609 , C08G18/4866 , C08G65/2663
摘要： The present invention relates to a process for the preparation of polyether polyols by catalytic reaction of H-functional initiators with lower alkylene oxides, wherein the catalysts used are multimetal cyanide compounds and the H-functional initiators used are butane-1,4-diol, &agr;-hydroxy-&ohgr;-hydroxypoly(oxybutane-1,4-diyl), pentane-1,5-diol, decane-1,10-diol or mixtures of at least two of these compounds.
摘要翻译：本发明涉及通过H官能引发剂与低级环氧烷的催化反应制备聚醚多元醇的方法，其中使用的催化剂是多金属氰化物，所用的H官能引发剂是丁烷-1,4-二醇， α-羟基-ω-羟基聚（氧丁烷-1,4-二基），戊烷-1,5-二醇，癸烷-1,10-二醇或这些化合物中的至少两种的混合物。

3. 发明授权

US06362126B1 Supported double metal cyanide catalysts, method for producing them, and their use for producing polyether alcohols 失效
标题翻译：负载型双金属氰化物催化剂，其制备方法及其制备聚醚醇的用途
公开(公告)号：US06362126B1
公开(公告)日：2002-03-26
申请号：US09623553
申请日：2000-09-09
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Ulrich Kammel
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Ulrich Kammel
IPC分类号： B01J3100
CPC分类号： C08G65/2693 , B01J27/26 , C08G65/2663
摘要： Double-metal cyanide catalysts of the formula M1a[M2(CN)b(A)c]d. fM1gXn. h (H2O). eL, where M1 is a metal ion selected from the group consisting of Zn2+, Fe2+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Mo4+, Mo6+, Al3+, V4+, V5+, Sr2+, W4+, W6+, Cr2+, Cr3+ and Cd2+, M2 is a metal ion selected from the group consisting of Fe2+, Fe3+, Co2+, Co3+, Mn2+, Mn3+, V4+, V5+, Cr2+, Cr3+, Rh3+, Ru2+ and Ir3+ and M1 and M2 are identical or different, A is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and nitrate, X is an anion selected from the group consisting of halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate and nitrate, L is a water-miscible ligand selected from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, ureas, amides, nitriles and sulfides, a, b, c, d, g and n are selected so as to make the compound electrically neutral, and e denotes the coordination number of the ligand, e and f denote fractions or integers greater than or equal to zero, h denotes a fraction or integer greater than or equal to zero, wherein the double-metal cyanides have been applied to or incorporated into solid, inert, unfoamed supports or have been shaped to give moldings.
摘要翻译：式M1的双金属氰化物催化剂是选自Zn2 +，Fe2 +，Co3 +，Ni2 +，Mn2 +，Co2 +，Sn2 +，Pb2 +，Mo4 +，Mo6 +，Al3 +，V4 +，V5 +，Sr2 +，W4 +，W6 + Cr2 +，Cr3 +和Cd2 +，M2是选自Fe2 +，Fe3 +，Co2 +，Co3 +，Mn2 +，Mn3 +，V4 +，V5 +，Cr2 +，Cr3 +，Rh3 +，Ru2 +和Ir3 +的金属离子，M1和M2相同或相同不同的是，A是选自卤化物，氢氧化物，硫酸盐，碳酸盐，氰化物，硫氰酸盐，异氰酸盐，氰酸盐，羧酸盐，草酸盐和硝酸盐的阴离子，X是选自卤化物，氢氧化物，硫酸盐，碳酸盐，氰化物，硫氰酸盐，异氰酸盐，氰酸盐，羧酸盐，草酸盐和硝酸盐，L是选自醇，醛，酮，醚，聚醚，酯，脲，酰胺，腈和硫化物的水混溶配体，选择b，c，d，g和n以使化合物电中性，并且e表示配位数 r的配体，e和f表示大于或等于零的分数或整数，h表示大于或等于零的分数或整数，其中双金属氰化物已经施加到固体，惰性，未发泡的支撑或已经成形为赋予模制品。

4. 发明授权

US06548714B1 Method for producing polyetherols by ring-opening polymerisation of alkylene oxides 失效
标题翻译：通过环氧烷开环聚合生产聚醚的方法
公开(公告)号：US06548714B1
公开(公告)日：2003-04-15
申请号：US09744512
申请日：2001-01-24
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Kathrin Harre
IPC分类号： C07C4100
CPC分类号： B01J23/007 , B01J27/232 , B01J27/236 , B01J27/26 , C08G65/2642 , C08G65/2657 , C08G65/2663 , C08G65/269
摘要： A process for preparing polyetherols by ring-opening polymerization of alkylene oxides onto H-functional initiator molecules comprises at least one process step a) in which a compound of the formula (I) M′aM″b(OH)cOd* Ae*Lf (I), is applied to a solid inert support or incorporated in the latter or molded to form a shaped body is used as catalyst, and at least one process step b) in which a multimetal cyanide compound of the formula (II) M1a[M2(CN)b(A)c]d·fM1gXn·h(H20) eL (II) is applied to a solid, inert support or incorporated in the latter or molded to form a shaped body or in powder or paste form is used as catalyst.
摘要翻译：通过环氧烷烃在H-官能引发剂分子上的开环聚合制备聚醚的方法包括至少一种方法步骤a），其中将式（I）化合物施用于固体惰性载体或并入其中用于形成成形体的成型体用作催化剂，以及至少一种方法步骤b），其中将式（II）的多金属氰化物化合物施加到固体惰性载体上或并入其中，或者模制成形成身体或以粉末或糊状形式用作催化剂。

5. 发明授权

US06800583B2 Suspension of multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化物的悬浮液，其制备及其用途
公开(公告)号：US06800583B2
公开(公告)日：2004-10-05
申请号：US09324271
申请日：1999-06-02
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge , Edward Michael Dexheimer
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge , Edward Michael Dexheimer
IPC分类号： B01J2726
CPC分类号： B01J27/26 , C08G65/2663
摘要： Catalyst suspensions for the ring-opening polymerization of alkylene oxides comprise a) at least one multimetal cyanide compound having a crystalline structure and a content of platelet-shaped particles of at least 30% by weight, based on the multimetal cyanide compound, and b) at least one organic complexing agent c) water and/or d) at least one polyether and/or e) at least one surface-active substance, with the proviso that at least component a) and at least two of the components b) to e) have to be present.
摘要翻译：用于烯化氧的开环聚合的催化剂悬浮液包括：a）至少一种具有至少30重量％以上的多金属氰化合物的结晶结构和片状颗粒的含量的多金属氰化物化合物，和b）至少一种有机络合剂c）水和/或）至少一种聚醚和/矿）至少一种表面活性物质，条件是至少组分a）和至少两种组分b）至e）必须是当下。

6. 发明授权

US06806393B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06806393B2
公开(公告)日：2004-10-19
申请号：US10447521
申请日：2003-05-29
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

7. 发明授权

US06906110B1 Method for the production of polyurethanes 有权
标题翻译：生产聚氨酯的方法
公开(公告)号：US06906110B1
公开(公告)日：2005-06-14
申请号：US10019998
申请日：2000-11-04
申请人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
发明人： Reinhard Lorenz , Stephan Bauer , Dieter Junge , Eva Baum , Kathrin Harre , Jörg Erbes , Thomas Ostrowski , Georg Heinrich Grosch
IPC分类号： C08G18/22 , C08G18/48 , C08G65/26 , C08K3/10 , C08K3/16 , C08K3/24 , C08K3/26 , C08K5/09
CPC分类号： C08G18/4866 , C08G18/225 , C08G65/2663 , C08G2101/0008 , C08G2101/0083
摘要： In a process for producing polyurethanes by reacting at least one polyisocyanate with at least one compound containing at least two hydrogen atoms which are reactive toward isocyanate groups, the compound having at least two active hydrogen atoms which is used is at least one polyether alcohol prepared by addition of alkylene oxides onto H-functional initiator substances by means of multimetal cyanide catalysis and the reaction is carried out in the presence of at least one metal salt.
摘要翻译：在通过使至少一种多异氰酸酯与至少一种含有至少两个对异氰酸酯基团具有反应性的氢原子的化合物反应来生产聚氨酯的方法中，使用至少两个活性氢原子的化合物是至少一种由通过多金属氰化物催化将氧化烯加成到H-官能引发剂物质上，并且反应在至少一种金属盐的存在下进行。

8. 发明授权

US06613714B2 Multimetal cyanide compounds, their preparation and their use 失效
标题翻译：多金属氰化合物，其制备及其用途
公开(公告)号：US06613714B2
公开(公告)日：2003-09-02
申请号：US09324145
申请日：1999-06-02
申请人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
发明人： Georg Heinrich Grosch , Kathrin Harre , Jörg Erbes , Reinhard Lorenz , Stephan Bauer , Thomas Ostrowski , Eva Baum , Dieter Junge
IPC分类号： B01J2726
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023
摘要： In multimetal cyanide complexes, more than 30% by weight of the primary particles have a platelet-like habit, i.e. the length and width of the primary particles is at least three times the thickness of the particles.
摘要翻译：在多金属氰化物络合物中，超过30重量％的初级颗粒具有血小板样习惯，即一次颗粒的长度和宽度至少为颗粒厚度的三倍。

9. 发明授权

US06653441B2 Method for production of polyether alcohols 有权
公开(公告)号：US06653441B2
公开(公告)日：2003-11-25
申请号：US10130846
申请日：2002-05-21
申请人： Kathrin Harre , Gerd Höppner , Georg Heinrich Grosch , Stephan Bauer , Jürgen Winkler , Els Paredis , Reinhard Lorenz , Inge Rotermund
发明人： Kathrin Harre , Gerd Höppner , Georg Heinrich Grosch , Stephan Bauer , Jürgen Winkler , Els Paredis , Reinhard Lorenz , Inge Rotermund
IPC分类号： C07C4311
CPC分类号： C08G65/2663 , C08G18/485 , C08G65/2696
摘要： In a process for preparing polyether alcohols by catalytic addition of at least two alkylene oxides onto H-functional initiator substances, at least one multimetal cyanide compound is used as catalyst and the addition of the alkylene oxides onto the initiator substance includes incorporation of at least one oxyalkylene block during whose formation at least two alkylene oxides are metered in together and the ratio of the alkylene oxides to one another in the mixture is changed during the joint introduction.

10. 发明授权

US06753402B1 Polyester-polyether block copolymers 失效
标题翻译：聚酯 - 聚醚嵌段共聚物
公开(公告)号：US06753402B1
公开(公告)日：2004-06-22
申请号：US10110297
申请日：2002-04-10
申请人： Stephan Bauer , Georg Heinrich Grosch , Gerlinde Tischer , Kathrin Harre , Eva Baum , Thomas Ostrowski , Reinhard Lorenz , Regina Pretzsch , Michael Pcolinski , Stefan Dinsch , Inge Rotermund
发明人： Stephan Bauer , Georg Heinrich Grosch , Gerlinde Tischer , Kathrin Harre , Eva Baum , Thomas Ostrowski , Reinhard Lorenz , Regina Pretzsch , Michael Pcolinski , Stefan Dinsch , Inge Rotermund
IPC分类号： C08G1842
CPC分类号： C08G81/00 , C08G18/4018 , C08G18/42 , C08G18/4261 , C08G65/2609 , C08G65/2663 , C08G2101/0008 , C08G2101/0083 , C08G2130/00 , C08L71/02 , C08L2666/18
摘要： Polyester-polyether block copolymers can be prepared by catalytic addition of alkylene oxides onto H-functional initiator substances, using polyester alcohols as H-functional initiator substances and multimetal cyanide compounds as catalysts.
摘要翻译：聚酯 - 聚醚嵌段共聚物可以通过使用聚酯醇作为H官能引发剂物质和多金属氰化物作为催化剂将环氧烷催化加成到H官能引发剂物质上来制备。

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