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1. 发明申请

US20130261207A1 PROCESS FOR PRODUCTION OF POLYMER POLYOLS 有权
标题翻译：生产聚合物多元醇的方法
公开(公告)号：US20130261207A1
公开(公告)日：2013-10-03
申请号：US13900814
申请日：2013-05-23
申请人： Jose F. Pazos , John E. Hayes
发明人： Jose F. Pazos , John E. Hayes
IPC分类号： C08G65/00
CPC分类号： C08G65/002 , C08G18/4866 , C08G18/632 , C08G65/26 , C08G65/2663 , C08G2101/00
摘要： The present invention provides a process for preparing a polymer polyol (PMPO) by alkoxylating a starter compound(s) having active hydrogen atoms in the presence of a double metal cyanide (DMC) catalyst, radical initiator(s) and optionally PMPO stabilizers and simultaneously polymerizing unsaturated monomer(s) with radical initiator(s). The polymer polyols (PMPOs) made by the inventive process may find use in the preparation of polyurethane foams and elastomers,
摘要翻译：本发明提供一种通过在双金属氰化物（DMC）催化剂，自由基引发剂和任选的PMPO稳定剂的存在下烷氧基化具有活性氢原子的起始化合物来制备聚合物多元醇（PMPO）的方法，同时用自由基引发剂聚合不饱和单体。通过本发明方法制备的聚合物多元醇（PMPO）可用于制备聚氨酯泡沫和弹性体，

2. 发明申请

US20100324340A1 SHORT CHAIN POLYETHER POLYOLS PREPARED FROM ULTRA-LOW WATER-CONTENT STARTERS VIA DMC CATALYSIS 审中-公开
标题翻译：通过DMC催化分析从超低水含量起动器制备的短链聚醚多元醇
公开(公告)号：US20100324340A1
公开(公告)日：2010-12-23
申请号：US12489522
申请日：2009-06-23
申请人： Jose F. Pazos , Edward P. Browne , Anthony Loveday
发明人： Jose F. Pazos , Edward P. Browne , Anthony Loveday
IPC分类号： C07C43/10 , C07C41/03
CPC分类号： C08G65/2663 , C08G65/2696
摘要： The present invention provides a process for the polyoxyalkylation of a starter involving establishing oxyalkylation conditions in an oxyalkylation reactor in the presence of a double metal cyanide (DMC) catalyst, continuously introducing into the reactor at least one alkylene oxide and an acidified, ultra-low water content starter, in which the starter contains greater than about 100 ppm and less than or equal to about 500 ppm water, based on the weight of the starter, and recovering an oxyalkylated low molecular weight starter polyether product. The inventive process allows the production of short chain polyether polyols which have hydroxyl numbers of from greater than 250 up to about 500, from hygroscopic initiators, such as glycerin, without DMC catalyst deactivation.
摘要翻译：本发明提供了一种引发剂的聚氧化烷基化方法，其涉及在双重金属氰化物（DMC）催化剂的存在下在烷氧基化反应器中建立烷氧基化条件，连续向反应器中引入至少一种烯化氧和酸化的超低水含量起动器，其中起动器基于起动器的重量包含大于约100ppm且小于或等于约500ppm的水，并且回收烷氧基化的低分子量引发剂聚醚产物。本发明的方法允许生产具有大于250至约500的羟值的短链聚醚多元醇，来自吸湿性引发剂如甘油，没有DMC催化剂失活。

3. 发明授权

US06083420A Method for decreasing the propensity for phase-out of the high molecular weight component of double metal cyanide-catalyzed high secondary hydroxyl polyoxypropylene polyols 有权
标题翻译：降低双金属氰化物催化的高级羟基聚氧丙烯多元醇的高分子量组分的淘汰倾向的方法
公开(公告)号：US06083420A
公开(公告)日：2000-07-04
申请号：US356625
申请日：1999-07-19
申请人： Jeffrey J. Lear , Oliver D. Sloan , Jose F. Pazos
发明人： Jeffrey J. Lear , Oliver D. Sloan , Jose F. Pazos
IPC分类号： C08G18/48 , C08G65/26 , C07C43/18
CPC分类号： C08G65/2663 , C08G18/4845 , C08G18/485 , C08G18/4866 , C08G2101/0008
摘要： During polyoxyalkylation in the presence of certain double metal cyanide catalysts, a very high molecular weight hydrophobic fraction, i.e. a "tail", is produced during preparation of high secondary hydroxyl polyols which is believed to contribute to foam collapse in polyurethane foam formulations. The processing latitude of such foams may be improved by altering the hydrophile/lipophile balance of the high molecular weight tail by oxyalkylating with a mixture of ethylene oxide and higher alkylene oxide during the greatest portion of total oxyalkylation such that essentially pure higher alkylene oxide is present in a terminal portion of oxyalkylation not exceeding 15 weight percent of total polyol weight.
摘要翻译：在某些双金属氰化物催化剂存在下的聚氧化烷基化过程中，在制备高次羟基多羟基化合物期间产生非常高分子量的疏水部分，即“尾”，这被认为有助于聚氨酯泡沫制剂中的泡沫破裂。通过在总烷氧基化的最大部分期间通过用环氧乙烷和较高环氧烷的混合物进行烷氧基化改变高分子量尾料的亲水/亲油平衡来改善这种泡沫的加工范围，使得基本上纯的高级环氧烷存在在烷氧基化的末端部分不超过总多元醇重量的15重量％。

4. 发明授权

US5777177A Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter 失效
标题翻译：通过连续加入起始物制备双金属氰化物催化的多元醇
公开(公告)号：US5777177A
公开(公告)日：1998-07-07
申请号：US597781
申请日：1996-02-07
申请人： Jose F. Pazos
发明人： Jose F. Pazos
IPC分类号： C08G65/10 , C08G18/08 , C08G18/48 , C08G65/26 , C07C41/03
CPC分类号： C08G65/2663 , C08G18/14 , C08G18/4866 , C08G65/2696 , C08G2101/0008 , C08G2101/0083
摘要： Double metal cyanide-catalyzed polyols are made by an improved process in which a starter is continuously added during polymerization of the epoxide. The process includes a continuously added starter (S.sub.c), and optionally, an initially charged starter (S.sub.i). The continuously added starter comprises at least about 2 equivalent percent of the total starter used. The process enables the use of water and low molecular weight polyol starters in DMC-catalyzed polyol synthesis. In addition, the process gives polyether polyols having reduced levels of high molecular weight polyol tail, which can adversely affect polyurethane foam processing.
摘要翻译：双金属氰化物催化的多元醇通过改进的方法制备，其中在环氧化物的聚合期间连续加入起始物。该方法包括连续添加的起动器（Sc），以及可选的初始充电起动器（Si）。连续添加的起动器包括使用的总起动器的至少约2当量％。该方法能够在DMC催化的多元醇合成中使用水和低分子量多元醇起始物。此外，该方法提供具有降低水平的高分子量多元醇尾巴的聚醚多元醇，其可能不利地影响聚氨酯泡沫处理。

5. 发明授权

US5773525A Process of oxyalkylation employing solid, heterogeneous oxyalkylation catalysts 失效
标题翻译：使用固体，异相烷氧基化催化剂进行烷氧基化的方法
公开(公告)号：US5773525A
公开(公告)日：1998-06-30
申请号：US880040
申请日：1997-06-20
申请人： Jose F. Pazos
发明人： Jose F. Pazos
IPC分类号： B01J21/10 , C08G65/26 , C08G65/28
CPC分类号： B01J21/10 , C08G65/2609 , C08G65/2651 , C08G65/2663
摘要： Oligomeric polyoxyalkylene polyethers are prepared by oxyalkylating a low molecular weight hydroxyl-functional starter molecule with one or more alkylene oxides in the presence of a solid, heterogeneous magnesium oxide catalyst. The catalyst is readily and rapidly removed by simple filtration to yield a polyether with minimal metal ion content suitable for use directly or as a starter molecule for further double metal cyanide complex catalyzed oxyalkylation.
摘要翻译：低聚聚氧化烯聚醚通过在固体异相氧化镁催化剂存在下，用低级分子量的羟基官能起始物分子与一种或多种烯化氧进行烷氧基化来制备。催化剂通过简单的过滤容易且快速地除去，得到最小金属离子含量的聚醚，其适用于直接使用或作为进一步双金属氰化物络合物催化氧化烷基化的起始分子。

6. 发明授权

US5364973A Productive process for making conventional and low-unsaturation polyether polyols 失效
标题翻译：制备常规和低不饱和度聚醚多元醇的生产方法
公开(公告)号：US5364973A
公开(公告)日：1994-11-15
申请号：US58109
申请日：1993-05-06
申请人： Jose F. Pazos
发明人： Jose F. Pazos
IPC分类号： C08G65/04 , C08G18/48 , C08G65/02 , C08G65/28 , C08G65/30 , C07C41/03 , C07C213/00
CPC分类号： C08G65/30 , C08G18/4866
摘要： A productive process for making conventional and low-unsaturation polyether polyols is disclosed. The process involves continuous removal of allyl alcohol and lower allyl alcohol propoxylates from the polyol during manufacture. The process can be performed at high temperatures and/or low catalyst concentrations. Polyether polyols with exceptionally low monol contents can be prepared.
摘要翻译：公开了制备常规和低不饱和度聚醚多元醇的生产方法。该方法包括在制备期间从多元醇中连续除去烯丙醇和降低烯丙醇丙氧基化物。该方法可以在高温和/或低催化剂浓度下进行。可以制备具有非常低的单醇含量的聚醚多元醇。

7. 发明授权

US5219974A Thermally reversible polymer sheets and method of forming the same 失效
标题翻译：热可逆聚合物片及其形成方法
公开(公告)号：US5219974A
公开(公告)日：1993-06-15
申请号：US341457
申请日：1989-04-21
申请人： Fidelis C. Onwumere , Jose F. Pazos
发明人： Fidelis C. Onwumere , Jose F. Pazos
IPC分类号： C08G18/10 , D01D5/098 , D01F6/70 , D04H1/56
CPC分类号： D01F6/70 , C08G18/10 , D01D5/0985 , D04H1/56
摘要： The invention provides fibers and sheets formed from a polymer having a thermally reversible bond which is adapted to evanesce at an elevated temperature and revert to a thermally reversible bond upon cooling to ambient temperature so that said polymer is adapted, upon being heated to said elevated temperature, to dissociate into melt processable polymer fragments and, upon being cooled from said elevated temperature to ambient temperature, to re-associate. The polymer fibers may be meltblown fibers which may be formed into a coherent nonwoven web or sheet. The meltblown fibers may include microfibers. The meltblown web may also include at least one type of secondary fiber, particulates or a mixture of fibers and particulates.
摘要翻译：本发明提供由具有热可逆键的聚合物形成的纤维和片材，其适于在升高的温度下消失，并且在冷却至环境温度时还原成热可逆接合，使得所述聚合物在被加热到所述高温解离成可熔融加工的聚合物碎片，并且在从所述升高的温度冷却至环境温度时，重新结合。聚合物纤维可以是可以形成相干非织造纤维网或片材的熔喷纤维。熔喷纤维可以包括微纤维。熔喷纤维网还可以包括至少一种类型的次级纤维，颗粒或纤维和颗粒的混合物。

8. 发明授权

US4725629A Process of making an interpenetrating superabsorbent polyurethane foam 失效
标题翻译：制造互穿超吸收性聚氨酯泡沫的方法
公开(公告)号：US4725629A
公开(公告)日：1988-02-16
申请号：US888301
申请日：1986-07-18
申请人： Chad E. Garvey , Jose F. Pazos
发明人： Chad E. Garvey , Jose F. Pazos
IPC分类号： C08G18/48 , C08L75/00 , C08G18/10 , C08G18/67
CPC分类号： C08G18/4833 , C08G2101/0083 , C08G2270/00 , Y10S521/905
摘要： A superabsorbent polyurethane foam based on an interpenetrating polymer network of a crosslinked polyurethane and a crosslinked addition polymer containing a plurality of chain segments made up of functional group-containing repeating units which may be the same or different. The functional groups of the repeating units are selected from the group consisting of carbamoyl, substituted carbamoyl, and carboxy and the alkali metal and ammonium salts thereof. A method of preparing the foams is described which involves forming the polyurethane foam in the presence of addition polymerizable monomers and crosslinking agent and a thermally activated free radical initiator. Addition polymerization can take place during or after foam formation. Reactants and reaction conditions are selected so as to essentially avoid grafting addition polymer to polyurethane.Preferably, the polyurethane is derived from an isocyanate-terminated poly(oxyalkylene) polyol having an isocyanate functionality greater than two and the addition polymer is the reaction product of a crosslinking agent, such as methylene-bis-acrylamide and 1,6-hexanediol diacrylate, with at least one compound selected from the group consisting of acrylamides, substituted acrylamides, and acrylate and methacrylate salts, i.e., alkali metal and ammonium salts of acrylic and methacrylic acid.Such superabsorbent polyurethane foam is useful in the manufacture of absorbent articles, especially disposable absorbent articles such as diapers, sanitary napkins, bedpads, incontinent pads, and the like.
摘要翻译：基于交联聚氨酯的互穿聚合物网络和含有由相同或不同的含官能团的重复单元组成的多个链段的交联加成聚合物的超吸收性聚氨酯泡沫。重复单元的官能团选自氨基甲酰基，取代的氨基甲酰基和羧基及其碱金属和铵盐。描述了制备泡沫的方法，其涉及在加成聚合单体和交联剂和热活化的自由基引发剂的存在下形成聚氨酯泡沫。加成聚合可以在泡沫形成期间或之后进行。选择反应物和反应条件以便基本上避免将加成聚合物接枝到聚氨酯上。优选地，聚氨酯衍生自具有大于2的异氰酸酯官能度的异氰酸酯封端的聚（氧化烯）多元醇，加成聚合物是交联剂如亚甲基双丙烯酰胺和1,6-己二醇二丙烯酸酯的反应产物与至少一种选自丙烯酰胺，取代的丙烯酰胺和丙烯酸酯和甲基丙烯酸盐的化合物，即丙烯酸和甲基丙烯酸的碱金属和铵盐。这种超吸收性聚氨酯泡沫可用于制造吸收制品，特别是一次性吸收制品如尿布，卫生巾，床垫，失禁垫等。

9. 发明授权

US4198242A Photopolymerizable composition containing an o-nitroaromatic compound as photoinhibitor 失效
标题翻译：含有邻硝基芳族化合物作为光抑制剂的光聚合组合物
公开(公告)号：US4198242A
公开(公告)日：1980-04-15
申请号：US913906
申请日：1978-06-08
申请人： Jose F. Pazos
发明人： Jose F. Pazos
IPC分类号： C08F2/50 , G03F7/027
CPC分类号： G03F7/027 , C08F2/50 , Y10S430/111 , Y10S430/118
摘要： A photopolymerizable coating composition comprising(1) a nongaseous, ethylenically unsaturated, polymerizable compound,(2) a specified nitroaromatic compound, and(3) an organic, radiation-sensitive, free-radical generating systemis useful for making a positive or negative polymeric image on a substrate.
摘要翻译：一种可光聚合的涂料组合物，其包含（1）非气态，烯键式不饱和的可聚合化合物，（2）特定的硝基芳族化合物和（3）有机辐射敏感的自由基产生体系，可用于制备正或负聚合物图像在基板上。

10. 发明授权

US06670406B2 Process for producing polyether polyols 有权
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US06670406B2
公开(公告)日：2003-12-30
申请号：US10077855
申请日：2002-02-19
申请人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
发明人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
IPC分类号： C07C4311
CPC分类号： B01J19/2465 , C08G65/2663 , C08G65/2696
摘要： The present invention relates to a process for the production of a polyether polyol by polyaddition of an alkylene oxide onto a starter compound containing active hydrogen atoms conducted in the presence of a double metal cyanide catalyst comprising conducting a reaction mixture at least once through a zone which has an energy density of at least 5×106 J/m3, wherein the dwell time of the reaction mixture in this zone is at least 10−6 seconds per pass.
摘要翻译：本发明涉及一种生产聚醚多元醇的方法，该方法是通过在双金属氰化物催化剂的存在下将烯化氧加成到含有活性氢原子的起始化合物上，包括将反应混合物至少一次通过一个具有至少5×10 6 J / m 3的能量密度，其中该区域中反应混合物的停留时间为每次通过至少10 -6秒。

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