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1. 发明授权

US08754181B2 Silicone resin, process for producing the same, and curable resin composition comprising the same 失效
公开(公告)号：US08754181B2
公开(公告)日：2014-06-17
申请号：US12864684
申请日：2009-02-04
申请人： Yuki Ono , Masayoshi Isozaki , Takashi Saito
发明人： Yuki Ono , Masayoshi Isozaki , Takashi Saito
IPC分类号： C08G77/20 , C08F283/12
CPC分类号： C08G77/38 , C08F299/08 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/44 , C08G77/70 , C08L83/04 , G02B1/04 , G11B7/2533 , C08L83/00
摘要： Provided are a silicone resin that yields a cured product excellent in flexibility, toughness, and heat resistance and high in transparency, a process for producing the said silicone resin, and a curable resin composition comprising the said silicone resin. The silicone resin is obtained by reacting an organopolysiloxane containing SiH groups represented by general formula (3) with an organopolysiloxane containing hydroxyl groups at both ends represented by general formula (5) and an alcohol containing radically reactive groups represented by general formula (6) in the presence of a hydroxylamine compound represented by general formula (4) as a catalyst and this silicone resin is used in formulating a curable resin composition. In the general formulas, R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, R1 is an alkyl group, Y is a hydrocarbon group of 1-12 carbon atoms optionally containing an oxygen atom, Z is a (meth)acryloyl group, a vinyl group, or an allyl group, and n, s, m, and r are numbers respectively expressed as 0

2. 发明申请

US20100311919A1 SILICONE RESIN, PROCESS FOR PRODUCING THE SAME, AND CURABLE RESIN COMPOSITION COMPRISING THE SAME 失效
标题翻译：硅树脂，其制造方法和包含其的可固化树脂组合物
公开(公告)号：US20100311919A1
公开(公告)日：2010-12-09
申请号：US12864684
申请日：2009-02-04
申请人： Yuki Ono , Masayoshi Isozaki , Takashi Saito
发明人： Yuki Ono , Masayoshi Isozaki , Takashi Saito
IPC分类号： C08L83/06 , C08G77/08 , C08G77/14
CPC分类号： C08G77/38 , C08F299/08 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/44 , C08G77/70 , C08L83/04 , G02B1/04 , G11B7/2533 , C08L83/00
摘要： Provided are a silicone resin that yields a cured product excellent in flexibility, toughness, and heat resistance and high in transparency, a process for producing the said silicone resin, and a curable resin composition comprising the said silicone resin. The silicone resin is obtained by reacting an organopolysiloxane containing SiH groups represented by general formula (3) with an organopolysiloxane containing hydroxyl groups at both ends represented by general formula (5) and an alcohol containing radically reactive groups represented by general formula (6) in the presence of a hydroxylamine compound represented by general formula (4) as a catalyst and this silicone resin is used in formulating a curable resin composition. In the general formulas, R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, R1 is an alkyl group, Y is a hydrocarbon group of 1-12 carbon atoms optionally containing an oxygen atom, Z is a (meth)acryloyl group, a vinyl group, or an allyl group, and n, s, m, and r are numbers respectively expressed as 0
摘要翻译：提供了产生柔软性，韧性和耐热性优异，透明度高的固化产物的硅氧烷树脂，所述有机硅树脂的制备方法和包含所述有机硅树脂的固化性树脂组合物。有机硅树脂通过使通式（3）表示的SiH基的有机聚硅氧烷与通式（5）表示的两端含羟基的有机聚硅氧烷和通式（6）表示的自由基反应性基团的醇反应，存在通式（4）表示的羟胺化合物作为催化剂，该有机硅树脂用于配制可固化树脂组合物。在通式中，R是任选含有氧原子或芳基的1-12个碳原子的烷基，R1是烷基，Y是任选地含有氧原子的1-12个碳原子的烃基，Z 是（甲基）丙烯酰基，乙烯基或烯丙基，n，s，m和r分别表示为0

3. 发明授权

US07345125B2 Silicone resin composition and molded product thereof 有权
标题翻译：硅树脂组合物及其成型体
公开(公告)号：US07345125B2
公开(公告)日：2008-03-18
申请号：US11230612
申请日：2005-09-21
申请人： Masayoshi Isozaki , Takashi Saito , Hideki Andoh
发明人： Masayoshi Isozaki , Takashi Saito , Hideki Andoh
IPC分类号： C08F30/08
CPC分类号： C08G77/442 , C08L83/06
摘要： The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2]n (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
摘要翻译：本发明涉及可用于双折射小的辊膜的有机硅树脂组合物，该硅酮树脂组合物适用于例如光学应用，以及汽车用窗材料，该有机硅树脂组合物具有高热电阻，硅树脂组合物在低水平下染色，硅树脂组合物具有低热膨胀系数，能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。有机硅树脂组合物包含：A）主要由结构单元中具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂，聚有机倍半硅氧烷由[RSiO 3/2 N] /（其中R是具有（甲基）丙烯酰基的有机官能团，n为8,10或12）; B）与硅氧烷树脂自由基共聚的低聚物，含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2，并且具有氨基甲酸酯键的低聚物; 和C）与硅树脂自由基共聚的另一不饱和化合物。在有机硅树脂组合物中，硅酮树脂，低聚物和其它不饱和化合物以5至80：1至50：0至80的重量比配混。

4. 发明申请

US20070260008A1 Silica-Containing Silicone Resin Composition and Its Molded Product 审中-公开
标题翻译：含硅硅树脂组合物及其成型产品
公开(公告)号：US20070260008A1
公开(公告)日：2007-11-08
申请号：US11662596
申请日：2005-09-21
申请人： Takashi Saito , Masayoshi Isozaki , Hideki Ando , Akiko Yamasaki
发明人： Takashi Saito , Masayoshi Isozaki , Hideki Ando , Akiko Yamasaki
IPC分类号： C08L43/04
CPC分类号： C08L83/04 , C08G77/045 , C08K3/34 , C08K3/36 , C08L43/04
摘要： The present invention relates to a silica-containing silicone resin composition which provides high heat resistance, high transparency, and high dimension stability, and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, and a substrate for a flat panel display, or for a window material for an automobile and the like. The silica-containing silicone resin composition is obtained by incorporating 1 to 70 wt % of silica fine particles in a silicone resin composition, which is formulated with a cage type silicone resin mainly constituted of a polyorganosilsesquioxane represented by [RSiO3/2]n (where R is an organic functional group containing a (meth)acryloyl group and n is 8, 10, or 12), and containing a cage type structure in its constitutional unit; and an unsaturated compound containing at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, (where R3 represents an alkylene group, an alkylidene group, or a —OCO— group, and R4 represents hydrogen or an alkyl group in a molecule), and capable of undergoing radical copolymerization with the silicone resin at a weight ratio of 1:99 to 99:1.
摘要翻译：本发明涉及一种提供高耐热性，高透明性和高尺寸稳定性的含二氧化硅的有机硅树脂组合物，因此可以适用于诸如透镜，光盘，光纤和用于平板显示器的基板，或用于汽车等的窗材料。含硅氧烷树脂组合物是通过在硅树脂组合物中加入1〜70重量％的二氧化硅微粒而得到的，该有机硅树脂组合物由主要由[RSiO 3/2/2]代表的聚有机倍半硅氧烷（其中R是含有（甲基）丙烯酰基的有机官能团，n是8,10或12），并且其结构单元包含笼型结构; 和含有至少一个不饱和基团的不饱和化合物，所述不饱和化合物由-R 3 -CR 4 -CH 2或-CR 4表示，其中R 3表示亚烷基，亚烷基或-OCO-基，R 4 O， >分子中表示氢或烷基），并且能够以1:99至99:1的重量比与硅树脂进行自由基共聚。

5. 发明授权

US07385017B2 Silicone resin compositions and molded articles thereof 有权
标题翻译：硅树脂组合物及其模制品
公开(公告)号：US07385017B2
公开(公告)日：2008-06-10
申请号：US10544391
申请日：2004-03-22
申请人： Takashi Saito , Masayoshi Isozaki , Hideki Andoh
发明人： Takashi Saito , Masayoshi Isozaki , Hideki Andoh
IPC分类号： C08F30/08
CPC分类号： C08G77/442 , C08F230/08 , C08F290/068 , C08G77/04 , G02B1/04 , C08L43/04
摘要： This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
摘要翻译：本发明涉及一种具有高耐热性，高透明性和高尺寸稳定性的有机硅树脂组合物，因此可以适用于透镜，光盘，光纤，平板显示器用基板等光学应用，用于汽车的窗材料等。一种有机硅树脂组合物，其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂：其中R表示（ⅰ）具有（甲基）丙烯酰基的有机官能团，n为8,10或12，并且其结构单元具有笼型结构，在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2，其中R 1，R 2，其中R 3表示亚烷基，亚烷基或-OCO-基，R 4表示氢原子或烷基，并且能够自由基共聚与上述有机硅树脂的重量比为1:99至99:1。

6. 发明申请

US20060069216A1 Silicone resin composition and molded product thereof 有权
标题翻译：硅树脂组合物及其成型体
公开(公告)号：US20060069216A1
公开(公告)日：2006-03-30
申请号：US11230612
申请日：2005-09-21
申请人： Masayoshi Isozaki , Takashi Saito , Hideki Andoh
发明人： Masayoshi Isozaki , Takashi Saito , Hideki Andoh
IPC分类号： C08L83/08 , C08L83/10
CPC分类号： C08G77/442 , C08L83/06
摘要： The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2] (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
摘要翻译：本发明涉及可用于双折射小的辊膜的有机硅树脂组合物，该硅酮树脂组合物适用于例如光学应用，以及汽车用窗材料，该有机硅树脂组合物具有高热电阻，硅树脂组合物在低水平下染色，硅树脂组合物具有低热膨胀系数，能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。有机硅树脂组合物包含：A）主要由结构单元具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂，所述聚有机倍半硅氧烷由[RSiO 3/2/2]表示（其中R为具有（甲基）丙烯酰基的有机官能团和n为8,10或12）; B）与硅氧烷树脂自由基共聚的低聚物，含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2，并且具有氨基甲酸酯键的低聚物; 和C）与硅树脂自由基共聚的另一不饱和化合物。在有机硅树脂组合物中，硅酮树脂，低聚物和其它不饱和化合物以5至80：1至50：0至80的重量比配混。

7. 发明申请

US20060052567A1 Silicone resin compositions and moldings thereof 有权
标题翻译：硅树脂组合物及其模制品
公开(公告)号：US20060052567A1
公开(公告)日：2006-03-09
申请号：US10544391
申请日：2004-03-22
申请人： Takashi Saito , Masayoshi Isozaki , Hideki Andoh
发明人： Takashi Saito , Masayoshi Isozaki , Hideki Andoh
IPC分类号： C08G77/04 , C08L83/04
CPC分类号： C08G77/442 , C08F230/08 , C08F290/068 , C08G77/04 , G02B1/04 , C08L43/04
摘要： This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
摘要翻译：本发明涉及一种具有高耐热性，高透明性和高尺寸稳定性的有机硅树脂组合物，因此可以适用于透镜，光盘，光纤，平板显示器用基板等光学应用，用于汽车的窗材料等。一种有机硅树脂组合物，其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂：其中R表示（ⅰ）具有（甲基）丙烯酰基的有机官能团，n为8,10或12，并且其结构单元具有笼型结构，在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2，其中R 1，R 2，其中R 3表示亚烷基，亚烷基或-OCO-基，R 4表示氢原子或烷基，并且能够自由基共聚与上述有机硅树脂的重量比为1:99至99:1。

8. 发明授权

US06750308B2 Silicone resin compositions and molded products of silicone resins 有权
标题翻译：硅树脂组合物和有机硅树脂的模制产品
公开(公告)号：US06750308B2
公开(公告)日：2004-06-15
申请号：US10284206
申请日：2002-10-31
申请人： Hideki Andoh , Masayoshi Isozaki , Takero Teramoto
发明人： Hideki Andoh , Masayoshi Isozaki , Takero Teramoto
IPC分类号： C08G7714
CPC分类号： C08F283/12
摘要： This invention relates to a silicone resin composition comprising a silicone resin and an unsaturated compound. This resin composition is formulated from a silicone resin which has in its structural unit cage type polyorganosilsesquioxane whose siloxy groups are linked to a triorganosilyl group represented by —Si(CH3)2—X (wherein X is —R1—OCO—CR2═CH2, —R1—CR2═CH2 or —CH═CH2, R1 is an alkyl group, an alkylidene group or phenylene group and R2 is a hydrogen atom or an alkyl group) and an unsaturated compound which contains an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 (wherein R3 is an alkylene group, an alkylidene group or —OCO— group and R4 is a hydrogen atom or an alkyl group) at the weight ratio of the silicone resin to the unsaturated compound in the range of 1:99 to 99:1. The copolymer to be obtained from this silicone resin composition shows such excellent heat resistance and light transmission as to be capable of substituting for glass, low water absorption, high dimensional stability and good moldability.
摘要翻译：本发明涉及含硅树脂和不饱和化合物的有机硅树脂组合物。该树脂组合物由硅氧烷树脂配制，该硅氧烷树脂的结构单元为笼型多聚倍半硅氧烷，其硅氧烷基与由-Si（CH3）2-X表示的三有机甲硅烷基（其中X为-R 1 -OCO-CR 2 = CH 2，-R 1 -CR 2 = CH 2或-CH = CH 2，R 1是烷基，亚烷基或亚苯基，R 2是氢原子或烷基）和含有由-R 3 -CR 4 = CH 2或-CR 4 = CH 2表示的不饱和基团的不饱和化合物（其中R 3为亚烷基，亚烷基或 - OCO-基和R 4是氢原子或烷基），其硅氧烷树脂与不饱和化合物的重量比在1:99至99:1的范围内。从该有机硅树脂组合物获得的共聚物显示出能够代替玻璃，低吸水性，高尺寸稳定性和良好的成型性的优异的耐热性和透光性。

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