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    • 1. 发明授权
    • Silicone resin compositions and molded articles thereof
    • 硅树脂组合物及其模制品
    • US07385017B2
    • 2008-06-10
    • US10544391
    • 2004-03-22
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • C08F30/08
    • C08G77/442C08F230/08C08F290/068C08G77/04G02B1/04C08L43/04
    • This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
    • 本发明涉及一种具有高耐热性,高透明性和高尺寸稳定性的有机硅树脂组合物,因此可以适用于透镜,光盘,光纤,平板显示器用基板等光学应用, 用于汽车的窗材料等。 一种有机硅树脂组合物,其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂:其中R表示(ⅰ) 具有(甲基)丙烯酰基的有机官能团,n为8,10或12,并且其结构单元具有笼型结构,在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2,其中R 1,R 2, 其中R 3表示亚烷基,亚烷基或-OCO-基,R 4表示氢原子或烷基,并且能够自由基共聚 与上述有机硅树脂的重量比为1:99至99:1。
    • 2. 发明申请
    • Silicone resin composition and molded product thereof
    • 硅树脂组合物及其成型体
    • US20060069216A1
    • 2006-03-30
    • US11230612
    • 2005-09-21
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • C08L83/08C08L83/10
    • C08G77/442C08L83/06
    • The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2] (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
    • 本发明涉及可用于双折射小的辊膜的有机硅树脂组合物,该硅酮树脂组合物适用于例如光学应用,以及汽车用窗材料,该有机硅树脂组合物具有高热 电阻,硅树脂组合物在低水平下染色,硅树脂组合物具有低热膨胀系数,能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。 有机硅树脂组合物包含:A)主要由结构单元具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂,所述聚有机倍半硅氧烷由[RSiO 3/2/2]表示(其中R为 具有(甲基)丙烯酰基的有机官能团和n为8,10或12); B)与硅氧烷树脂自由基共聚的低聚物,含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2,并且具有氨基甲酸酯键的低聚物; 和C)与硅树脂自由基共聚的另一不饱和化合物。 在有机硅树脂组合物中,硅酮树脂,低聚物和其它不饱和化合物以5至80:1至50:0至80的重量比配混。
    • 3. 发明申请
    • Silicone resin compositions and moldings thereof
    • 硅树脂组合物及其模制品
    • US20060052567A1
    • 2006-03-09
    • US10544391
    • 2004-03-22
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • C08G77/04C08L83/04
    • C08G77/442C08F230/08C08F290/068C08G77/04G02B1/04C08L43/04
    • This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
    • 本发明涉及一种具有高耐热性,高透明性和高尺寸稳定性的有机硅树脂组合物,因此可以适用于透镜,光盘,光纤,平板显示器用基板等光学应用, 用于汽车的窗材料等。 一种有机硅树脂组合物,其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂:其中R表示(ⅰ) 具有(甲基)丙烯酰基的有机官能团,n为8,10或12,并且其结构单元具有笼型结构,在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2,其中R 1,R 2, 其中R 3表示亚烷基,亚烷基或-OCO-基,R 4表示氢原子或烷基,并且能够自由基共聚 与上述有机硅树脂的重量比为1:99至99:1。
    • 4. 发明授权
    • Silicone resin composition and molded product thereof
    • 硅树脂组合物及其成型体
    • US07345125B2
    • 2008-03-18
    • US11230612
    • 2005-09-21
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • C08F30/08
    • C08G77/442C08L83/06
    • The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2]n (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
    • 本发明涉及可用于双折射小的辊膜的有机硅树脂组合物,该硅酮树脂组合物适用于例如光学应用,以及汽车用窗材料,该有机硅树脂组合物具有高热 电阻,硅树脂组合物在低水平下染色,硅树脂组合物具有低热膨胀系数,能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。 有机硅树脂组合物包含:A)主要由结构单元中具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂,聚有机倍半硅氧烷由[RSiO 3/2 N] /(其中R是具有(甲基)丙烯酰基的有机官能团,n为8,10或12); B)与硅氧烷树脂自由基共聚的低聚物,含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2,并且具有氨基甲酸酯键的低聚物; 和C)与硅树脂自由基共聚的另一不饱和化合物。 在有机硅树脂组合物中,硅酮树脂,低聚物和其它不饱和化合物以5至80:1至50:0至80的重量比配混。
    • 6. 发明申请
    • Silica-Containing Silicone Resin Composition and Its Molded Product
    • 含硅硅树脂组合物及其成型产品
    • US20070260008A1
    • 2007-11-08
    • US11662596
    • 2005-09-21
    • Takashi SaitoMasayoshi IsozakiHideki AndoAkiko Yamasaki
    • Takashi SaitoMasayoshi IsozakiHideki AndoAkiko Yamasaki
    • C08L43/04
    • C08L83/04C08G77/045C08K3/34C08K3/36C08L43/04
    • The present invention relates to a silica-containing silicone resin composition which provides high heat resistance, high transparency, and high dimension stability, and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, and a substrate for a flat panel display, or for a window material for an automobile and the like. The silica-containing silicone resin composition is obtained by incorporating 1 to 70 wt % of silica fine particles in a silicone resin composition, which is formulated with a cage type silicone resin mainly constituted of a polyorganosilsesquioxane represented by [RSiO3/2]n (where R is an organic functional group containing a (meth)acryloyl group and n is 8, 10, or 12), and containing a cage type structure in its constitutional unit; and an unsaturated compound containing at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, (where R3 represents an alkylene group, an alkylidene group, or a —OCO— group, and R4 represents hydrogen or an alkyl group in a molecule), and capable of undergoing radical copolymerization with the silicone resin at a weight ratio of 1:99 to 99:1.
    • 本发明涉及一种提供高耐热性,高透明性和高尺寸稳定性的含二氧化硅的有机硅树脂组合物,因此可以适用于诸如透镜,光盘,光纤和 用于平板显示器的基板,或用于汽车等的窗材料。 含硅氧烷树脂组合物是通过在硅树脂组合物中加入1〜70重量%的二氧化硅微粒而得到的,该有机硅树脂组合物由主要由[RSiO 3/2/2]代表的聚有机倍半硅氧烷 (其中R是含有(甲基)丙烯酰基的有机官能团,n是8,10或12),并且其结构单元包含笼型结构; 和含有至少一个不饱和基团的不饱和化合物,所述不饱和化合物由-R 3 -CR 4 -CH 2或-CR 4表示, 其中R 3表示亚烷基,亚烷基或-OCO-基,R 4 O, >分子中表示氢或烷基),并且能够以1:99至99:1的重量比与硅树脂进行自由基共聚。
    • 7. 发明申请
    • SILICONE RESIN, PROCESS FOR PRODUCING THE SAME, AND CURABLE RESIN COMPOSITION COMPRISING THE SAME
    • 硅树脂,其制造方法和包含其的可固化树脂组合物
    • US20100311919A1
    • 2010-12-09
    • US12864684
    • 2009-02-04
    • Yuki OnoMasayoshi IsozakiTakashi Saito
    • Yuki OnoMasayoshi IsozakiTakashi Saito
    • C08L83/06C08G77/08C08G77/14
    • C08G77/38C08F299/08C08G77/12C08G77/14C08G77/16C08G77/20C08G77/44C08G77/70C08L83/04G02B1/04G11B7/2533C08L83/00
    • Provided are a silicone resin that yields a cured product excellent in flexibility, toughness, and heat resistance and high in transparency, a process for producing the said silicone resin, and a curable resin composition comprising the said silicone resin. The silicone resin is obtained by reacting an organopolysiloxane containing SiH groups represented by general formula (3) with an organopolysiloxane containing hydroxyl groups at both ends represented by general formula (5) and an alcohol containing radically reactive groups represented by general formula (6) in the presence of a hydroxylamine compound represented by general formula (4) as a catalyst and this silicone resin is used in formulating a curable resin composition. In the general formulas, R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, R1 is an alkyl group, Y is a hydrocarbon group of 1-12 carbon atoms optionally containing an oxygen atom, Z is a (meth)acryloyl group, a vinyl group, or an allyl group, and n, s, m, and r are numbers respectively expressed as 0
    • 提供了产生柔软性,韧性和耐热性优异,透明度高的固化产物的硅氧烷树脂,所述有机硅树脂的制备方法和包含所述有机硅树脂的固化性树脂组合物。 有机硅树脂通过使通式(3)表示的SiH基的有机聚硅氧烷与通式(5)表示的两端含羟基的有机聚硅氧烷和通式(6)表示的自由基反应性基团的醇反应, 存在通式(4)表示的羟胺化合物作为催化剂,该有机硅树脂用于配制可固化树脂组合物。 在通式中,R是任选含有氧原子或芳基的1-12个碳原子的烷基,R1是烷基,Y是任选地含有氧原子的1-12个碳原子的烃基,Z 是(甲基)丙烯酰基,乙烯基或烯丙基,n,s,m和r分别表示为0