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    • 1. 发明授权
    • Silicone resin compositions and molded products of silicone resins
    • 硅树脂组合物和有机硅树脂的模制产品
    • US06750308B2
    • 2004-06-15
    • US10284206
    • 2002-10-31
    • Hideki AndohMasayoshi IsozakiTakero Teramoto
    • Hideki AndohMasayoshi IsozakiTakero Teramoto
    • C08G7714
    • C08F283/12
    • This invention relates to a silicone resin composition comprising a silicone resin and an unsaturated compound. This resin composition is formulated from a silicone resin which has in its structural unit cage type polyorganosilsesquioxane whose siloxy groups are linked to a triorganosilyl group represented by —Si(CH3)2—X (wherein X is —R1—OCO—CR2═CH2, —R1—CR2═CH2 or —CH═CH2, R1 is an alkyl group, an alkylidene group or phenylene group and R2 is a hydrogen atom or an alkyl group) and an unsaturated compound which contains an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 (wherein R3 is an alkylene group, an alkylidene group or —OCO— group and R4 is a hydrogen atom or an alkyl group) at the weight ratio of the silicone resin to the unsaturated compound in the range of 1:99 to 99:1. The copolymer to be obtained from this silicone resin composition shows such excellent heat resistance and light transmission as to be capable of substituting for glass, low water absorption, high dimensional stability and good moldability.
    • 本发明涉及含硅树脂和不饱和化合物的有机硅树脂组合物。 该树脂组合物由硅氧烷树脂配制,该硅氧烷树脂的结构单元为笼型多聚倍半硅氧烷,其硅氧烷基与由-Si(CH3)2-X表示的三有机甲硅烷基(其中X为-R 1 -OCO-CR 2 = CH 2,-R 1 -CR 2 = CH 2或-CH = CH 2,R 1是烷基,亚烷基或亚苯基,R 2是氢原子或 烷基)和含有由-R 3 -CR 4 = CH 2或-CR 4 = CH 2表示的不饱和基团的不饱和化合物(其中R 3为亚烷基,亚烷基或 - OCO-基和R 4是氢原子或烷基),其硅氧烷树脂与不饱和化合物的重量比在1:99至99:1的范围内。 从该有机硅树脂组合物获得的共聚物显示出能够代替玻璃,低吸水性,高尺寸稳定性和良好的成型性的优异的耐热性和透光性。
    • 2. 发明授权
    • Silicone resin composition and molded product thereof
    • 硅树脂组合物及其成型体
    • US07345125B2
    • 2008-03-18
    • US11230612
    • 2005-09-21
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • C08F30/08
    • C08G77/442C08L83/06
    • The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2]n (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
    • 本发明涉及可用于双折射小的辊膜的有机硅树脂组合物,该硅酮树脂组合物适用于例如光学应用,以及汽车用窗材料,该有机硅树脂组合物具有高热 电阻,硅树脂组合物在低水平下染色,硅树脂组合物具有低热膨胀系数,能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。 有机硅树脂组合物包含:A)主要由结构单元中具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂,聚有机倍半硅氧烷由[RSiO 3/2 N] /(其中R是具有(甲基)丙烯酰基的有机官能团,n为8,10或12); B)与硅氧烷树脂自由基共聚的低聚物,含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2,并且具有氨基甲酸酯键的低聚物; 和C)与硅树脂自由基共聚的另一不饱和化合物。 在有机硅树脂组合物中,硅酮树脂,低聚物和其它不饱和化合物以5至80:1至50:0至80的重量比配混。
    • 3. 发明授权
    • Silicone resin compositions and molded articles thereof
    • 硅树脂组合物及其模制品
    • US07385017B2
    • 2008-06-10
    • US10544391
    • 2004-03-22
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • C08F30/08
    • C08G77/442C08F230/08C08F290/068C08G77/04G02B1/04C08L43/04
    • This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
    • 本发明涉及一种具有高耐热性,高透明性和高尺寸稳定性的有机硅树脂组合物,因此可以适用于透镜,光盘,光纤,平板显示器用基板等光学应用, 用于汽车的窗材料等。 一种有机硅树脂组合物,其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂:其中R表示(ⅰ) 具有(甲基)丙烯酰基的有机官能团,n为8,10或12,并且其结构单元具有笼型结构,在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2,其中R 1,R 2, 其中R 3表示亚烷基,亚烷基或-OCO-基,R 4表示氢原子或烷基,并且能够自由基共聚 与上述有机硅树脂的重量比为1:99至99:1。
    • 4. 发明申请
    • Silicone resin composition and molded product thereof
    • 硅树脂组合物及其成型体
    • US20060069216A1
    • 2006-03-30
    • US11230612
    • 2005-09-21
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • Masayoshi IsozakiTakashi SaitoHideki Andoh
    • C08L83/08C08L83/10
    • C08G77/442C08L83/06
    • The present invention relates to a silicone resin composition that can be used for a roll film having small birefringence, the silicone resin composition being suitable for, for example, optical applications, and a window material for an automobile, the silicone resin composition having high heat resistance, the silicon resin composition being stained at a low level, the silicone resin composition having a low thermal expansion coefficient, the silicone resin composition enabling a transparent conductive film to be stably formed, and the silicone resin composition providing good winding property. The silicone resin composition contains: A) a silicone resin mainly composed of a polyorganosilsesquioxane having a cage-type structure in a structural unit, the polyorganosilsesquioxane being represented by [RSiO3/2] (wherein R is an organic functional group having a (meth)acryloyl group and n is 8, 10, or 12); B) an oligomer that is radically copolymerizable with the silicone resin, the oligomer containing an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 in a molecule, and the oligomer having a urethane bond; and C) an other unsaturated compound that is radically copolymerizable with the silicone resin. In the silicone resin composition, the silicone resin, the oligomer, and the other unsaturated compound are compounded at a weight ratio of 5 to 80:1 to 50:0 to 80.
    • 本发明涉及可用于双折射小的辊膜的有机硅树脂组合物,该硅酮树脂组合物适用于例如光学应用,以及汽车用窗材料,该有机硅树脂组合物具有高热 电阻,硅树脂组合物在低水平下染色,硅树脂组合物具有低热膨胀系数,能够稳定形成透明导电膜的有机硅树脂组合物和提供良好卷绕性能的有机硅树脂组合物。 有机硅树脂组合物包含:A)主要由结构单元具有笼型结构的聚有机倍半硅氧烷组成的有机硅树脂,所述聚有机倍半硅氧烷由[RSiO 3/2/2]表示(其中R为 具有(甲基)丙烯酰基的有机官能团和n为8,10或12); B)与硅氧烷树脂自由基共聚的低聚物,含有由-R 3 3 -CR 4 -CH 2表示的不饱和基团的低聚物 >或-CR 4〜4个CH 2,并且具有氨基甲酸酯键的低聚物; 和C)与硅树脂自由基共聚的另一不饱和化合物。 在有机硅树脂组合物中,硅酮树脂,低聚物和其它不饱和化合物以5至80:1至50:0至80的重量比配混。
    • 5. 发明申请
    • Silicone resin compositions and moldings thereof
    • 硅树脂组合物及其模制品
    • US20060052567A1
    • 2006-03-09
    • US10544391
    • 2004-03-22
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • Takashi SaitoMasayoshi IsozakiHideki Andoh
    • C08G77/04C08L83/04
    • C08G77/442C08F230/08C08F290/068C08G77/04G02B1/04C08L43/04
    • This invention relates to a silicone resin composition which exhibits high heat resistance, high transparency and high dimensional stability and thus can be suitably used for optical applications such as a lens, an optical disc, an optical fiber, a substrate for a plat panel display, a window material for an automobile, and the like. A silicone resin composition, which comprises a silicone resin comprising, as a primary component, a polyorganosilsesquioxane being represented by the formula: [RSiO3/2]n, wherein R represents an organic functional group having a (meth)acryloyl group, and n is 8, 10 or 12, and having a cage type structure in its structural unit, and an unsaturated compound having, in its molecule, at least one unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2, wherein R3 represents an alkylene group, an alkylidene group or a —OCO— group and R4 represents a hydrogen atom or an alkyl group, and being capable of radically copolymerizing with the above silicone resin, in a weight proportion of 1:99 to 99:1.
    • 本发明涉及一种具有高耐热性,高透明性和高尺寸稳定性的有机硅树脂组合物,因此可以适用于透镜,光盘,光纤,平板显示器用基板等光学应用, 用于汽车的窗材料等。 一种有机硅树脂组合物,其包含由下式表示的聚有机倍半硅氧烷作为主要组分的硅氧烷树脂:其中R表示(ⅰ) 具有(甲基)丙烯酰基的有机官能团,n为8,10或12,并且其结构单元具有笼型结构,在分子中具有至少一个由 - R 3 -CR 4 -CH 2或-CR 4 -CH 2,其中R 1,R 2, 其中R 3表示亚烷基,亚烷基或-OCO-基,R 4表示氢原子或烷基,并且能够自由基共聚 与上述有机硅树脂的重量比为1:99至99:1。
    • 6. 发明申请
    • Polyamide resin composition for fuse elements, and fuse element
    • 保险丝元件的聚酰胺树脂组合物和保险丝元件
    • US20060020071A1
    • 2006-01-26
    • US11228197
    • 2005-09-19
    • Masaaki YamazakiKoji FujimotoIwao MurakamiHideki Andoh
    • Masaaki YamazakiKoji FujimotoIwao MurakamiHideki Andoh
    • C08K3/34
    • H01H85/17C08K5/005C08L77/02C08L77/06H01H85/0417C08L77/00
    • The present invention is to provide a polyamide resin composition for fuse elements, assuring sufficient arc resistance upon boosting of vehicles voltage (e.g., 42 V system), being excellent in rigidity, heat resistance and transparency. The present invention relates to a polyamide resin composition for fuse elements, comprising: a mixed polyamide 100 parts by mass consisting of (A) polycaproamide (nylon 6) 95 to 5% by mass and (B) poly(hexamethylene adipamide) (nylon 66) 5 to 95% by mass; and (C) asilicatelayerof lamellarsilicate 0.1 to 20 parts by mass dispersed on molecular order level in the above described (A) and/or (B). The polyamide resin composition may further contain (D) an antioxidant, (E) a metal soap based lubricant, and/or (F) an inorganic fibrous reinforcing material are contained. The present invention also relates to a fuse element formed from the polyamide resin composition for fuse elements.
    • 本发明提供一种用于保险丝元件的聚酰胺树脂组合物,在车辆电压(例如42V系统)升压时确保足够的耐电弧性,刚性,耐热性和透明度优异。 本发明涉及一种熔融元件用聚酰胺树脂组合物,其特征在于,包含:(A)95〜5质量%的(A)聚己内酰胺(尼龙6)和(B)聚己二酰己二胺(尼龙66) )5〜95质量% 和(C)分散在上述(A)和/或(B)中的分子顺序水平上的0.1〜20质量份的层状硅酸铝。 聚酰胺树脂组合物还可以含有(D)抗氧化剂,(E)金属皂类润滑剂和/或(F)无机纤维增强材料。 本发明还涉及由用于熔丝元件的聚酰胺树脂组合物形成的熔丝元件。
    • 10. 发明授权
    • Blade fuse
    • 刀片保险丝
    • US06967560B2
    • 2005-11-22
    • US10432503
    • 2001-11-22
    • Hideki AndohIwao Murakami
    • Hideki AndohIwao Murakami
    • H01H85/02H01H85/041H01H85/045H01H85/147H01H85/153H01H85/165H01H85/17H01H85/175
    • H01H85/17H01H85/0417
    • A compact fuse (1) for an automobile is provided. The fuse is formed by a fuse element (2) and an insulative housing (3) having a cutaway portion (8). The fuse element includes two base plates (4) and a melting portion (5) connecting the base plates. The melting portion is accommodated in the housing and parts of the base plates are exposed from the housing. The length of the base plate is the sum of the length (A) of the melting portion in the longitudinal direction of the base plate, the length (B) of a notch (4c) in the longitudinal direction of the base plate, and the length (C) of a cover supporting portion in the longitudinal direction of the base plate.
    • 提供一种用于汽车的紧凑型保险丝(1)。 保险丝由具有切除部分(8)的保险丝元件(2)和绝缘壳体(3)形成。 保险丝元件包括两个基板(4)和连接基板的熔化部分(5)。 熔化部分容纳在壳体中,并且基板的部分从壳体露出。 基板的长度是基板的长度方向的熔融部的长度(A)与基板的长度方向的切口(4c)的长度(B)和 盖支撑部分在基板的纵向方向上的长度(C)。