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1. 发明授权

US06559246B2 Primer composition for silicone pressure-sensitive adhesives 失效
公开(公告)号：US06559246B2
公开(公告)日：2003-05-06
申请号：US09805942
申请日：2001-03-15
申请人： Yasuyoshi Kuroda , Shunji Aoki , Masahiko Ogawa
发明人： Yasuyoshi Kuroda , Shunji Aoki , Masahiko Ogawa
IPC分类号： C08G7714
CPC分类号： C08K5/541 , C08K5/1539 , C09D183/04 , C09J7/50 , C09J2423/006 , C09J2479/086 , C09J2481/006 , C09J2483/00 , C09J2483/003 , Y10T428/31663 , C08L83/04 , C08L83/00 , C08L2666/34 , C08L2666/28
摘要： A primer composition comprising (A) a diorganopolysiloxane having an average degree of polymerization of 500-2,000 and alkenyl groups at both ends of its molecular chain in an amount of 0.001-0.005 mol per 100 g of the diorganopolysiloxane, (B) an organohydrogenpolysiloxane having at least two SiH groups in a molecule, (C) a platinum base curing catalyst, and (D) a retarder is effective for improving the adhesion between various plastic films and silicone pressure-sensitive adhesives and thus forming satisfactory pressure-sensitive adhesive tapes.

2. 发明授权

US06331604B1 Grafted rubber-like silicone gel with enhanced oil compatibility and its synthetic process 失效
标题翻译：接枝橡胶状硅胶，具有增强的油相容性及其合成过程
公开(公告)号：US06331604B1
公开(公告)日：2001-12-18
申请号：US09269631
申请日：1999-03-31
申请人： James Wang , Thomas J. Hrubec
发明人： James Wang , Thomas J. Hrubec
IPC分类号： C08G7714
CPC分类号： C08L83/04 , A61K8/042 , A61K8/892 , A61K8/92 , A61K47/34 , A61Q19/00 , C08G77/12 , C08G77/14 , C08G77/18 , C08G77/20 , C08G77/38 , C08L83/06 , C08L83/00
摘要： Fatty alcohol or aliphatic glycol-grafted rubber-like silicone gels with enhanced oil compatibility are synthesized by 1) reacting a fatty alcohol or a aliphatic glycol with methylhydrodimethylsiloxane copolymer in the presence of a platinum catalyst in a reaction medium of a silicone fluid or a cosmetic oil or a mixture thereof, and 2) further reacting the mixture with a vinyl-functional siloxane polymer. The resulting compounds may be used as gelling agents for hydrocarbon oils, vegetable oils and silicone oils. The efficient synthetic process approaches a 100% yield.
摘要翻译：通过以下方式合成具有增强的油相溶性的脂肪醇或脂族二醇接枝橡胶状硅凝胶：1）在铂催化剂存在下，在硅油或化妆品的反应介质中使脂肪醇或脂族二醇与甲基氢二甲基硅氧烷共聚物反应油或其混合物，和2）进一步使该混合物与乙烯基官能的硅氧烷聚合物反应。所得化合物可用作烃油，植物油和硅油的胶凝剂。有效的合成过程接近100％的收率。

3. 发明授权

US06337383B1 Polysiloxane polymers with multiple oligooxyethylene side chains 有权
标题翻译：具有多个低聚氧乙烯侧链的聚硅氧烷聚合物
公开(公告)号：US06337383B1
公开(公告)日：2002-01-08
申请号：US09517821
申请日：2000-03-02
申请人： Robert C. West , Richard Hooper , David A. Moline
发明人： Robert C. West , Richard Hooper , David A. Moline
IPC分类号： C08G7714
CPC分类号： C08G77/46 , C08G65/336 , C08G77/18
摘要： Disclosed herein are solid polysiloxane polymers having multiple oligooxyethylene side chains per silicon. The multiple oligooxyethylene side chains are each directly connected to the silicons, or they can be linked by a branching structure and then jointly linked to the silicons. Methods for producing these compounds, and intermediates which are disubstituted silicon compounds, are also disclosed. These materials are highly conductive, and thus appear particularly useful in lithium automotive batteries.
摘要翻译：本文公开了具有每硅多个低聚氧乙烯侧链的固体聚硅氧烷聚合物。多个寡氧乙烯侧链各自直接连接到硅，或者它们可以通过支化结构连接，然后与硅连接。还公开了制备这些化合物的方法和二取代的硅化合物的中间体。这些材料是高导电性的，因此在锂汽车电池中特别有用。

4. 发明授权

US06313255B1 Telechelic siloxane polymers with multiple epoxy end-groups 失效
标题翻译：具有多个环氧端基的极性薄荷硅氧烷聚合物
公开(公告)号：US06313255B1
公开(公告)日：2001-11-06
申请号：US09437548
申请日：1999-11-10
申请人： Slawomir Rubinsztajn
发明人： Slawomir Rubinsztajn
IPC分类号： C08G7714
CPC分类号： C08G77/38 , C08L83/06
摘要： Telechelic polymers are presented, comprising polysiloxane polymers having multiple epoxy end-groups of the formula G—R3—SiR1R2O(SiR1R2O)mSiR1R2—R3—G wherein each R1 and R2 are independently monovalent alkyl, alkoxy, aryl, aryloxy, and halohydrocarbon radicals having from 1 to 20 carbon atoms, halohydrocarbon radicals having the formula CnF2n+1CH2CH2— wherein n is an integer from 1 to 18; m is an integer in the range from 10 to about 1000; R3 is a divalent hydrocarbon radical having from 2 to 18 carbon atoms; and G is a silicon-based functionalized end group, wherein the functionalities are selected from the group consisting of epoxides, vinyl ethers, propenyl ether, or a combination thereof.
摘要翻译：提供了远端聚合物，其包含具有多个环氧基的多个环氧端基的聚硅氧烷聚合物，每个R 1和R 2独立地为具有1至20个碳原子的一价烷基，烷氧基，芳基，芳氧基和卤代烃基，具有式C n F 2n + 1CH2CH2-其中n是1至18的整数; m为10〜1000的整数; R3是具有2至18个碳原子的二价烃基; 并且G是硅基官能化端基，其中所述官能团选自环氧化物，乙烯基醚，丙烯基醚或其组合。

5. 发明授权

US06750308B2 Silicone resin compositions and molded products of silicone resins 有权
标题翻译：硅树脂组合物和有机硅树脂的模制产品
公开(公告)号：US06750308B2
公开(公告)日：2004-06-15
申请号：US10284206
申请日：2002-10-31
申请人： Hideki Andoh , Masayoshi Isozaki , Takero Teramoto
发明人： Hideki Andoh , Masayoshi Isozaki , Takero Teramoto
IPC分类号： C08G7714
CPC分类号： C08F283/12
摘要： This invention relates to a silicone resin composition comprising a silicone resin and an unsaturated compound. This resin composition is formulated from a silicone resin which has in its structural unit cage type polyorganosilsesquioxane whose siloxy groups are linked to a triorganosilyl group represented by —Si(CH3)2—X (wherein X is —R1—OCO—CR2═CH2, —R1—CR2═CH2 or —CH═CH2, R1 is an alkyl group, an alkylidene group or phenylene group and R2 is a hydrogen atom or an alkyl group) and an unsaturated compound which contains an unsaturated group represented by —R3—CR4═CH2 or —CR4═CH2 (wherein R3 is an alkylene group, an alkylidene group or —OCO— group and R4 is a hydrogen atom or an alkyl group) at the weight ratio of the silicone resin to the unsaturated compound in the range of 1:99 to 99:1. The copolymer to be obtained from this silicone resin composition shows such excellent heat resistance and light transmission as to be capable of substituting for glass, low water absorption, high dimensional stability and good moldability.
摘要翻译：本发明涉及含硅树脂和不饱和化合物的有机硅树脂组合物。该树脂组合物由硅氧烷树脂配制，该硅氧烷树脂的结构单元为笼型多聚倍半硅氧烷，其硅氧烷基与由-Si（CH3）2-X表示的三有机甲硅烷基（其中X为-R 1 -OCO-CR 2 = CH 2，-R 1 -CR 2 = CH 2或-CH = CH 2，R 1是烷基，亚烷基或亚苯基，R 2是氢原子或烷基）和含有由-R 3 -CR 4 = CH 2或-CR 4 = CH 2表示的不饱和基团的不饱和化合物（其中R 3为亚烷基，亚烷基或 - OCO-基和R 4是氢原子或烷基），其硅氧烷树脂与不饱和化合物的重量比在1:99至99:1的范围内。从该有机硅树脂组合物获得的共聚物显示出能够代替玻璃，低吸水性，高尺寸稳定性和良好的成型性的优异的耐热性和透光性。

6. 发明授权

US06265516B1 Anti-staining additive and room-temperature-curable polyorganosiloxane composition 失效
标题翻译：防污添加剂和室温可固化聚有机硅氧烷组合物
公开(公告)号：US06265516B1
公开(公告)日：2001-07-24
申请号：US09507716
申请日：2000-02-18
申请人： Tadashi Okawa , Wataru Nishiumi , Seiji Hori
发明人： Tadashi Okawa , Wataru Nishiumi , Seiji Hori
IPC分类号： C08G7714
CPC分类号： C08L83/04 , C08G77/12 , C08G77/16 , C08G77/38 , C09D183/04 , C08L83/00 , C08L2666/28
摘要： An anti-staining additive comprising a higher unsaturated aliphatic acid ester-modified organosilicon compound that is produced by carrying out an addition reaction between (a) a higher unsaturated aliphatic acid ester that contains more than one aliphatically unsaturated bond in each molecule and (b) an organosilicon compounds that contains at least 1 silicon-bonded hydrogen atom in each molecule with the aliphatically unsaturated bonds in component (a) present in molar excess over the silicon-bonded hydrogen in component (b). The additive can be used at 0.01 to 50 weight percent in a polyorganosiloxane composition that cures at room temperature by a condensation reaction.
摘要翻译：一种防污添加剂，其包含通过在（a）在每个分子中含有多于一个脂族不饱和键的高级不饱和脂肪酸酯和（b）之间进行加成反应而产生的高级不饱和脂肪酸酯改性的有机硅化合物，在每个分子中含有至少1个与硅键合的氢原子的组分（a）中的脂族不饱和键的有机硅化合物以摩尔超过组分（b）中与硅键合的氢存在。该添加剂可以在通过缩合反应在室温下固化的聚有机硅氧烷组合物中以0.01至50重量％使用。

7. 发明授权

US06743884B2 Dicarboxy functionalized silicone 有权
标题翻译：二羧基官能化硅酮
公开(公告)号：US06743884B2
公开(公告)日：2004-06-01
申请号：US10428446
申请日：2003-05-02
申请人： Philippe Olier
发明人： Philippe Olier
IPC分类号： C08G7714
CPC分类号： C08G77/38 , C08G77/14
摘要： Dicarboxy functionalized polyorganosiloxanes having the formula X(R4R5SiO)p(R6ASiO)qY (I) wherein the X end group represents a triorganosiloxyl end group of formula R1R2R3SiO, or a Z end group, wherein Z represents —OH the Y end group represents a triorganosilyl end group of formula SiR3R2R1, or a W end group, wherein W represents —H R1 to R6 represent a C1-C8 alkyl or phenyl radical, preferably methyl A represents the dicarboxy radical of formula (I′) or salts thereof —(CH2)3—CH(COOH)—CH2COOH (I′) p is an average value ranging from 0 to 1000 q is an average value ranging from 1 to 100 the ratio of the number of Z and W end groups to the total number of X and Y end groups being from 0/100 to 75/100. They can be used for the water repellent treatment of surfaces, particularly inorganic surfaces or surfaces containing alkaline or earth-alkaline metal, and as anti-corrosion additives for the treatment of metal surfaces.
摘要翻译：具有X末端基团的二羧基官能化聚有机硅氧烷表示式R 1 R 2 R 3 SiO的三有机甲硅烷基端基或Z端基，其中Z表示-OH，Y端基表示三官能甲硅烷基端基式SiR 3 R 2 R或W端基，其中W表示-HR 1至R 6表示C 1 -C 8烷基或苯基，优选甲基A表示二价基团，式（I'）或其盐的平均值为0至1000q的平均值是1至100的平均值，Z和W端基数与X和Y端基的总数之比为0 / 100至75/100。它们可以用于表面，特别是无机表面或含有碱金属或碱土金属的表面的防水处理，以及用于处理金属表面的防腐蚀添加剂。

8. 发明授权

US06268458B1 Coupler fluids for projection televisions 失效
标题翻译：用于投影电视的耦合器流体
公开(公告)号：US06268458B1
公开(公告)日：2001-07-31
申请号：US09341022
申请日：1999-09-03
申请人： David S. Soane , Zoya M. Soane
发明人： David S. Soane , Zoya M. Soane
IPC分类号： C08G7714
CPC分类号： H01J29/894 , G02B1/06 , H01J2229/0084 , H04N5/74 , H04N5/7425
摘要： Coupling fluids for use in optically coupling a projection lens system of a projection television to a cathode ray tube (CRT (16)) are provided. The fluids have: (1) at least one polymer having a siloxane backbone, i.e., at least one polymer having a —Si—O—Si—O—Si— backbone, and (2) methyl, phenyl, and hydrophilic groups attached to the silicon atoms of the backbone. The fluid can be composed of a single siloxane polymer having methyl, phenyl, and hydrophilic side groups or a mixture of a siloxane polymer having methyl and phenyl side groups with a siloxane polymer having methyl and hydrophylic side groups. The index of refraction of the fluid is preferably greater than 1.52 so as to minimize reflections at the interface between the fluid and the faceplate (17) of the CRT (16).
摘要翻译：提供用于将投影电视的投影透镜系统光学耦合到阴极射线管（CRT（16））的耦合流体。流体具有：（1）至少一种具有硅氧烷骨架的聚合物，即至少一种具有-Si-O-Si-O-Si-主链的聚合物，和（2）甲基，苯基和亲水基团连接到骨架的硅原子。流体可以由具有甲基，苯基和亲水侧基的单一硅氧烷聚合物或具有甲基和苯基侧基的硅氧烷聚合物与具有甲基和亲水侧基的硅氧烷聚合物的混合物组成。流体的折射率优选大于1.52，以使流体和CRT（16）的面板（17）之间的界面处的反射最小化。

9. 发明授权

US06767983B1 Silicone resin and photosensitive resin composition containing the same 失效
标题翻译：硅树脂和含有它的感光性树脂组合物
公开(公告)号：US06767983B1
公开(公告)日：2004-07-27
申请号：US09937598
申请日：2001-09-28
申请人： Takeshi Fujiyama , Takero Teramoto
发明人： Takeshi Fujiyama , Takero Teramoto
IPC分类号： C08G7714
CPC分类号： C08L83/14 , C08G77/04 , C08G77/045 , C08G77/14 , C08G77/38 , C08L83/06
摘要： This invention relates to photosensitive silicone resins and resin compositions containing the same. Silicone resins of this invention are characterized by that a triorganosilyl group represented by the following general formula (1) wherein R is a divalent organic group and R′ is a divalent group or a direct bond is linked to all or a part of the ends of the backbone of polyorganosilsesquioxanes. Photosensitive resin compositions of this invention are formulated from the aforementioned silicone resins and a photogenerator of acid. The aforementioned silicone resins and photosensitive resin compositions show excellent performance as resist materials for multi-level resist processes and for forming barriers of PDP and, on account of their excellent plasma resistance (resistance to O2-RIE), yield patterns of a high aspect ratio.
摘要翻译：本发明涉及感光性有机硅树脂和含有它的树脂组合物。本发明的硅氧烷树脂的特征在于，由以下通式（1）表示的三有机甲硅烷基（其中R是二价有机基团，R'是二价基团或直接键合）与全部或一部分末端连接聚有机倍半硅氧烷的骨架。本发明的感光树脂组合物由上述有机硅树脂和酸的光发生剂配制。上述有机硅树脂和感光性树脂组合物显示出优异的性能，作为用于多层抗蚀剂工艺的抗蚀剂材料和用于形成PDP的屏障，并且由于其优异的等离子体电阻（耐O2-RIE的耐受性），高纵横比的屈服图案。

10. 发明授权

US06743885B2 Resin composition for intermediate layer of three-layer resist 有权
标题翻译：三层抗蚀剂中间层树脂组合物
公开(公告)号：US06743885B2
公开(公告)日：2004-06-01
申请号：US10198120
申请日：2002-07-19
申请人： Isao Yahagi , Yasunori Uetani , Hiroshi Moriuma
发明人： Isao Yahagi , Yasunori Uetani , Hiroshi Moriuma
IPC分类号： C08G7714
CPC分类号： C09D183/04 , C08K5/0025 , C08K5/3442 , C08K5/3492 , C09D183/06
摘要： The object of the present invention is to provide resin composition for intermediate layer of a three-layer resist comprising (A) a polyorganosilsesquioxane resin having a weight-average molecular weight of from 1000 to 50000 and having two or more functional groups, which polymerize or condense at the presence of a acid, in the molecule, and (B) a compound generating an acid by electromagnetic wave or heat, and resin composition for intermediate layer of a three-layer resist, comprising (C) a polyorganosilsesquioxane resin having in the molecule a hydroxyl group and having a weight-average molecular weight of from 1000 to 50000, as resin composition for intermediate layer of a three-layer resist which, when ketone compounds, aromatic compounds and the like are used as a resist solvent, does not cause dissolution of an intermediate layer in applying an upper layer resist and does not cause formation of a mixing layer at the interface with the upper layer resist, and which shows little change by time, excellent in storage stability, and can form a hardened film without cracking.
摘要翻译：本发明的目的是提供一种三层抗蚀剂的中间层用树脂组合物，其包含（A）重均分子量为1000〜50000的具有2个以上官能团的聚有机倍半硅氧烷树脂，其聚合或在分子中酸存在下缩合，（B）通过电磁波或热产生酸的化合物，以及三层抗蚀剂中间层用树脂组合物，其包含（C）聚有机倍半硅氧烷树脂，其具有分子羟基，重均分子量为1000〜50000，作为三层抗蚀剂的中间层的树脂组合物，当使用酮化合物，芳香族化合物等作为抗蚀剂溶剂时，不会在施加上层抗蚀剂时引起中间层的溶解，并且不会在与上层抗蚀剂的界面处形成混合层，并且显示少量时间变化，储存稳定性优异，可以形成硬化膜而不破裂。

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