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1. 发明授权

US4499153A Sizes 失效
标题翻译：尺寸
公开(公告)号：US4499153A
公开(公告)日：1985-02-12
申请号：US466708
申请日：1983-02-15
申请人： Wulf von Bonin , Peter Mummenhoff , Ulrich Beck , Heinz Baumgen
发明人： Wulf von Bonin , Peter Mummenhoff , Ulrich Beck , Heinz Baumgen
IPC分类号： D21H17/07 , C08L91/00 , B32B27/06 , D21D3/00
CPC分类号： D21H17/07 , Y10T428/31783
摘要： New products having excellent sizing action, in particular on paper are obtained by reacting .alpha.,.beta.-unsaturated carboxylic acids or their reactive derivatives (such as, for example, esters or anhydrides) with amide-amines of higher carboxylic acids at temperatures above 120.degree. C.The new products are used in size formulations, preferably as aqueous alkaline and, in particular, aqueous ammoniacal, dispersions.
摘要翻译：通过使α，β-不饱和羧酸或其反应性衍生物（例如酯或酸酐）与高于120℃的高羧酸的酰胺 - 胺反应，得到具有优异施胶作用的新产品，特别是在纸上。 C.新产品用于尺寸配方中，优选用作碱性水溶液，特别是氨水分散体。

2. 发明授权

US4381367A Sizing agents for paper and a process for the production thereof 失效
标题翻译：纸张上浆剂及其生产方法
公开(公告)号：US4381367A
公开(公告)日：1983-04-26
申请号：US328009
申请日：1981-12-07
申请人： Wulf von Bonin , Peter Mummenhoff , Heinz Baumgen
发明人： Wulf von Bonin , Peter Mummenhoff , Heinz Baumgen
IPC分类号： C08F220/12 , D21H17/43 , C08F8/32
CPC分类号： D21H17/43 , C08F220/12 , Y10T428/31906
摘要： Paper sizing agents in the form of an aqueous preparation of maleic acid anhydride copolymers of which the anhydride groups had been reacted either with organic or inorganic bases or with primary-tertiary diamines and the reaction products subsequently reacted with epichlorohydrin or with inorganic or organic acids to form salts, the copolymers being made up of polymerised units of(a) from 5 to 75%, by weight, of an aromatic vinyl compound;(b) from 10 to 75%, by weight, of acrylic and/or methacrylic acid C.sub.1 -C.sub.18 alkyl esters;(c) from 5 to 35%, by weight, of maleic acid anhydride;(d) from 0 to 25%, by weight, of other vinyl monomers; and(e) from 0.1 to 10%, by weight, based on the sum of monomers (a) to (d) (which amounts to 100%, by weight), of an unsaturated aldehyde or of an enol ether derived therefrom.The copolymers are produced by radical polymerisation preferably in the absence of solvents.
摘要翻译：以马来酸酐共聚物形式的纸浆施胶剂，其酸酐基已经与有机或无机碱反应或与伯 - 叔二胺反应，反应产物随后与表氯醇或无机或有机酸反应，所述共聚物由（a）5-75重量％的芳族乙烯基化合物的聚合单元组成; （b）10至75重量％的丙烯酸和/或甲基丙烯酸C1-C18烷基酯; （c）5至35重量％的马来酸酐; （d）0-25重量％的其它乙烯基单体; 和（e）基于单体（a）至（d）（其为100重量％））的不饱和醛或由其衍生的烯醇醚的总量的0.1至10重量％。

3. 发明授权

US4614546A Sizes based on ketene dimers 失效
标题翻译：基于烯酮二聚体的尺寸
公开(公告)号：US4614546A
公开(公告)日：1986-09-30
申请号：US738640
申请日：1985-05-29
申请人： Wolf-Dieter Schroer , Ulrich Beck , Peter Mummenhoff , Heinz Baumgen
发明人： Wolf-Dieter Schroer , Ulrich Beck , Peter Mummenhoff , Heinz Baumgen
IPC分类号： D21H17/17 , C08L3/00
CPC分类号： D21H17/17
摘要： New aqueous sizes, in particular paper sizes, are made available which contain(a) ketene dimers of the formula ##STR1## in which R.sub.1 and R.sub.2 can be identical or different and represent hydrocarbon radicals having 6 to 30 carbon atoms,(b) amine-modified starch,(c) hydrophobic compound(s) which contain(s) one or more functional groups which are reactive towards OH groups within a pH range of 2 to 6, and(d) if desired further auxiliaries.
摘要翻译：提供新的水性尺寸，特别是纸张尺寸，其包含（a）式（I）的烯酮二聚体，其中R 1和R 2可以相同或不同，并且表示具有6至30个碳原子的烃基（ b）胺改性的淀粉，（c）含有一个或多个官能团的疏水性化合物，所述官能团在pH范围为2-6范围内对OH基团具有反应性，和（d）如果需要的话还有其他助剂。

4. 发明授权

US4784727A Sizing agent and use thereof 失效
标题翻译：上浆剂及其用途
公开(公告)号：US4784727A
公开(公告)日：1988-11-15
申请号：US459314
申请日：1983-01-20
申请人： Wolf-Dieter Schroer , Joachim Probst , Ingeborg Kolb , Ulrich Beck , Peter Mummenhoff , Heinz Baumgen
发明人： Wolf-Dieter Schroer , Joachim Probst , Ingeborg Kolb , Ulrich Beck , Peter Mummenhoff , Heinz Baumgen
IPC分类号： D21H17/08 , D21H17/15 , D21H17/17 , D21H17/35 , D21H17/36 , D21H17/37 , D21H17/45 , D21H3/02
CPC分类号： D21H17/08 , D21H17/15 , D21H17/17 , D21H17/35 , D21H17/36 , D21H17/37 , D21H17/455
摘要： A sizing agent which contains from 1 to 60 parts, by weight, of a fixing and sizing accelerating agent and from 0 to 80 parts, by weight, of conventional auxiliaries per 10 parts by weight of hydrophobic, cellulose-reactive sizing materials, the fixing and sizing accelerating agent being a polymer composed of linear or branched carbon chains, to which primary, secondary or tertiary amino and/or quaternary ammonium groups are bound directly or by side chains exhibits a thorough and rapid sizing effect, in particular in the better sizing of paper.
摘要翻译：一种施胶剂，其含有1至60重量份的定影和施胶促进剂和0至80重量份的常规助剂，每10重量份疏水性纤维素反应性施胶材料，固定和作为由直链或支链碳链构成的聚合物的定型促进剂，其中伯，仲或叔氨基和/或季铵基团直接或由侧链结合，表现出彻底和快速的施胶效果，特别是在更好的施胶的纸。

5. 发明授权

US4333874A Cationic triazinylamino azo dyestuffs 失效
标题翻译：阳离子三嗪基氨基偶氮染料
公开(公告)号：US4333874A
公开(公告)日：1982-06-08
申请号：US172506
申请日：1980-07-28
申请人： Horst Nickel , Friedhelm Muller , Peter Mummenhoff
发明人： Horst Nickel , Friedhelm Muller , Peter Mummenhoff
IPC分类号： C09B44/08 , C09B44/04 , C09B62/085 , C07C107/06 , C09B44/02
CPC分类号： C09B62/085 , C09B44/04
摘要： Cationic azo dyestuffs of the general formula ##STR1## wherein X.sup.(+) denotes an ammonium group,m denotes 0 or 1,R.sub.1 denotes hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,R.sub.2 and R.sub.3 independently of one another denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or acylamino,Z denotes halogen or a radical of the formula ##STR2## R.sub.4 and R.sub.5 independently of one another denote hydrogen, or C.sub.1 - to C.sub.4 -alkyl, cyclohexyl, phenyl, benzyl or phenylethyl, it being possible for these radicals to be substituted by hydroxyl, C.sub.1 - to C.sub.4 -alkoxy, chlorine or cyano and for the cyclohexyl, phenyl, benzyl and phenylethyl radical additionally to be substituted by C.sub.1 - to C.sub.4 -alkyl, orR.sub.4 and R.sub.5, together with the nitrogen atom to which they are bonded, denote a 5- or 6-membered ring,A denotes an aryl radical andAn.sup.(-) denotes an anion,are suitable for dyeing synthetic and natural materials.
摘要翻译：其中X（+）表示铵基，m表示0或1，R 1表示氢，C 1至C 4 - 烷基，C 1至C 4 - 烷氧基或卤素，R 2和R 3各自独立地表示 R 4和R 5彼此独立地表示氢或C 1至C 4 - 烷基，其中R 1和R 2彼此独立地表示氢，C 1 -C 4烷基，C 1 -C 4烷氧基或酰氨基，Z表示卤素或式，环己基，苯基，苄基或苯基乙基，这些基团可以被羟基，C 1 -C 4 - 烷氧基，氯或氰基取代，并且对于环己基，苯基，苄基和苯乙基，另外被C1- C4-烷基或R4和R5与它们所键合的氮原子一起表示5-或6-元环，A表示芳基，An（ - ）表示阴离子，适于染色合成和天然材料。

6. 发明授权

US4434269A Cationic sizing agent for paper and a process for the preparation thereof 失效
标题翻译：用于纸张的阳离子上胶剂及其制备方法
公开(公告)号：US4434269A
公开(公告)日：1984-02-28
申请号：US344991
申请日：1982-02-02
申请人： Joachim Probst , G/u/ nter Kolb , Peter Mummenhoff , Heinz B/a/ umgen
发明人： Joachim Probst , G/u/ nter Kolb , Peter Mummenhoff , Heinz B/a/ umgen
IPC分类号： C08F20/00 , C08F2/24 , C08F2/28 , C08F20/34 , C08F20/44 , C08F220/06 , C08F220/42 , C08F257/02 , D21H17/34 , D21H17/35 , D21H17/37 , D21H17/43 , D21H17/45 , D21H19/20 , D21H21/16 , C08L79/00
CPC分类号： D21H17/455 , C08F2/28 , C08F220/06 , C08F220/42 , C08F257/02 , D21H17/35 , D21H17/37 , D21H17/43 , D21H21/16 , Y10T428/31906
摘要： Cationic sizing agents for paper in the form of an aqueous colloid-disperse solution having average particle diameters of from 15 to 200 nm are obtained by dissolving a water-soluble cationic, chemically uniformaly composed terpolymer compound of:(a) from 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate,(b) from 45 to 80% by weight of styrene, and(c) from 4 to 40% by weight of acrylonitrilein an aqueous medium, the total of components (a) to (c) always amounting to 100% by weight and at least 10% of the N,N-dimethylamino groups of the terpolymer being quaternized and the rest being protonated, and by emulsifying, in the presence of from 10 to 70% by weight, based on the following monomer mixture, of this emulsifier,(d) acrylonitrile or methacrylonitrile in quantities of from 5 to 95% by weight, with(e) C.sub.1 -C.sub.12 -alkyl esters of acrylic acid and/or of methacrylic acid in quantities of from 5 to 95% by weight,the total of components (d) and (e) amounting to 100% by weight, and by subjecting the emulsion thus obtained to a radically initiated emulsion polymerization process at temperatures of from 20.degree. to 150.degree. C.
摘要翻译：通过将（a）的水溶性阳离子化学均匀构成的三元共聚物化合物溶解为7〜40重量％，得到平均粒径为15〜200nm的水分胶体分散溶液形式的纸的阳离子上浆剂，重量的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸酯，（b）45-80％（重量）苯乙烯，和（c）4-40％重量的丙烯腈在水性介质中的组分（ a）至（c）总计为100重量％，并且至少10％的三元共聚物的N，N-二甲基氨基被季铵化，其余的被质子化，并且在10-70％（d）丙烯腈或甲基丙烯腈，其量为5-95重量％，（e）丙烯酸和/或甲基丙烯酸的C 12 -C 12烷基酯（d）和（e）的总量为1至5重量％ 00重量％，并且通过使所得乳液在20℃至150℃的温度下进行自由基引发的乳液聚合反应。

7. 发明授权

US4405751A Aqueous aminoplastic resin dispersions 失效
标题翻译：水性氨基塑料树脂分散体
公开(公告)号：US4405751A
公开(公告)日：1983-09-20
申请号：US355644
申请日：1982-03-08
申请人： Hanns P. Muller , Kuno Wagner , Peter Mummenhoff , Gottfried Wallpott , Karlheinz Scheuss
发明人： Hanns P. Muller , Kuno Wagner , Peter Mummenhoff , Gottfried Wallpott , Karlheinz Scheuss
IPC分类号： C08L61/00 , C08G12/00 , C08G12/02 , C08G12/40 , C08G12/46 , C08L61/20 , C08L61/32 , C09B67/46 , D06M13/02 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , D06M15/427 , D21H19/44 , D21H19/62 , C08L61/28
CPC分类号： C08G12/02 , C08G12/46 , C08L61/32 , D21H19/62 , Y10T428/31964
摘要： Aminoplastic resin dispersions which are stable to sedimentation are obtained by condensation of aldehydes with aminoplastic resin formers in an aqueous medium, in the presence of water-soluble compounds of the formulaR--X--(A--O).sub.m --B--NHCONH--Y].sub.nhaving the substituent meanings mentioned in the description. The condensation is preferably carried out in the presence of dyestuffs or optical brighteners which have groups capable of condensation. The dispersions obtained thereby are particularly suitable for whitening the coating compositions used in the paper industry, and for coating paper, wood, films and textile materials.
摘要翻译：在具有取代基含义的式RX-（AO）mB-NHCONH-Y] n的水溶性化合物的存在下，通过在水性介质中将醛与氨基塑料树脂形成物缩合获得对沉降稳定的氨基塑料树脂分散体在说明书中提到。缩合优选在具有能够缩合的基团的染料或荧光增白剂的存在下进行。由此获得的分散体特别适用于造纸工业中使用的涂料组合物的增白和用于涂布纸，木材，薄膜和纺织材料的涂料。

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