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1. 发明授权

US4333874A Cationic triazinylamino azo dyestuffs 失效
标题翻译：阳离子三嗪基氨基偶氮染料
公开(公告)号：US4333874A
公开(公告)日：1982-06-08
申请号：US172506
申请日：1980-07-28
申请人： Horst Nickel , Friedhelm Muller , Peter Mummenhoff
发明人： Horst Nickel , Friedhelm Muller , Peter Mummenhoff
IPC分类号： C09B44/08 , C09B44/04 , C09B62/085 , C07C107/06 , C09B44/02
CPC分类号： C09B62/085 , C09B44/04
摘要： Cationic azo dyestuffs of the general formula ##STR1## wherein X.sup.(+) denotes an ammonium group,m denotes 0 or 1,R.sub.1 denotes hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,R.sub.2 and R.sub.3 independently of one another denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or acylamino,Z denotes halogen or a radical of the formula ##STR2## R.sub.4 and R.sub.5 independently of one another denote hydrogen, or C.sub.1 - to C.sub.4 -alkyl, cyclohexyl, phenyl, benzyl or phenylethyl, it being possible for these radicals to be substituted by hydroxyl, C.sub.1 - to C.sub.4 -alkoxy, chlorine or cyano and for the cyclohexyl, phenyl, benzyl and phenylethyl radical additionally to be substituted by C.sub.1 - to C.sub.4 -alkyl, orR.sub.4 and R.sub.5, together with the nitrogen atom to which they are bonded, denote a 5- or 6-membered ring,A denotes an aryl radical andAn.sup.(-) denotes an anion,are suitable for dyeing synthetic and natural materials.
摘要翻译：其中X（+）表示铵基，m表示0或1，R 1表示氢，C 1至C 4 - 烷基，C 1至C 4 - 烷氧基或卤素，R 2和R 3各自独立地表示 R 4和R 5彼此独立地表示氢或C 1至C 4 - 烷基，其中R 1和R 2彼此独立地表示氢，C 1 -C 4烷基，C 1 -C 4烷氧基或酰氨基，Z表示卤素或式，环己基，苯基，苄基或苯基乙基，这些基团可以被羟基，C 1 -C 4 - 烷氧基，氯或氰基取代，并且对于环己基，苯基，苄基和苯乙基，另外被C1- C4-烷基或R4和R5与它们所键合的氮原子一起表示5-或6-元环，A表示芳基，An（ - ）表示阴离子，适于染色合成和天然材料。

2. 发明授权

US4478681A Forgery-proof paper 失效
标题翻译：防伪纸
公开(公告)号：US4478681A
公开(公告)日：1984-10-23
申请号：US400834
申请日：1982-07-22
申请人： Friedhelm Muller , Horst Nickel
发明人： Friedhelm Muller , Horst Nickel
IPC分类号： D21H19/10 , B44F1/12 , D21H21/28 , D21H21/40 , D21H21/46 , D21H5/10
CPC分类号： D21H21/46 , Y10S428/916
摘要： Forgery-proof paper, which exhibits a distinct coloration when treated with an oxidizing agent and, if appropriate, a reducing agent, contains, as the reagent, a compound of the formula ##STR1## wherein A represents N or C,B represents NR, O or S,R represents hydrogen or alkyl,X and Y represent hydrogen or customary substituents andn and m represent the numbers 1 or 2.
摘要翻译：当用氧化剂和如果合适的话还原剂时，显示出明显的着色的防伪纸含有作为试剂的式Ⅰ化合物，其中A代表N或C，B代表NR ，O或S，R表示氢或烷基，X和Y表示氢或常规取代基，n和m表示数字1或2。

3. 发明授权

US4888128A Paper-coating slips containing fluorescent brighteners 失效
标题翻译：含有荧光增白剂的纸涂层纸
公开(公告)号：US4888128A
公开(公告)日：1989-12-19
申请号：US131780
申请日：1987-12-11
申请人： Jochen Koll , Friedhelm Muller , Werner Bieber , Joachim Konig , Udo Eckstein , Hans Theidel
发明人： Jochen Koll , Friedhelm Muller , Werner Bieber , Joachim Konig , Udo Eckstein , Hans Theidel
IPC分类号： D21H19/44 , C07D251/50 , C07D251/52 , C07D251/68 , D21H21/30
CPC分类号： D21H21/30
摘要： Fluorescent brightener salts of the formula ##STR1## in which A denotes the anion of an anionic cellulose fluorescent brightener,R.sub.1 denotes alkyl, alkenyl, aralkyl, aryl or cycloalkyl,R.sub.2, R.sub.3 and R.sub.4 denote hydrogen or R.sub.1, or together, including the N atom, form a heterocyclic ring, andn denotes 1 or 2,are suitable for incorporation into paper-coating slips. The brightened coating slips are distinguished, inter alia, by the fact that the achievable greying limit is very high.
摘要翻译：其中A表示阴离子纤维素荧光增白剂的阴离子，R1表示烷基，烯基，芳烷基，芳基或环烷基，R2，R3和R4表示氢或R1，或一起包括N的荧光增白剂原子，形成杂环，n表示1或2，适用于掺入纸张涂布纸。明亮的涂层滑块尤其可以通过可实现的变灰极限非常高的事实来区分开来。

4. 发明授权

US4385000A Surface-active phosphonic acid esters 失效
标题翻译：表面活性膦酸酯
公开(公告)号：US4385000A
公开(公告)日：1983-05-24
申请号：US131525
申请日：1980-03-18
申请人： Klaus Walz , Wilfried Nolte , Friedhelm Muller
发明人： Klaus Walz , Wilfried Nolte , Friedhelm Muller
IPC分类号： B01F17/00 , C07F9/40 , C08F2/32 , C08G65/335 , C08G65/338 , C08G79/04 , B01J13/00
CPC分类号： C08G79/04 , B01F17/0064 , C07F9/4075 , C08F2/32 , C08G65/3355 , C08G65/338 , Y10S516/01 , Y10S516/06
摘要： New surface-active phosphonic acid esters, which are inter alia suitable as emulsifiers and dispersants, a process for their preparation and emulsions and dispersions of water soluble polymers containing the new phosphonic acid esters and having high stability on storage.
摘要翻译：新的表面活性膦酸酯，其特别适合作为乳化剂和分散剂，其制备方法以及含有新膦酸酯的水溶性聚合物的乳液和分散体，并且在储存时具有高稳定性。

5. 发明授权

US4250112A Polyalkylenepolyamines containing quaternary dialkylammonium groups 失效
标题翻译：含有二烷基季铵基团的聚亚烷基多胺
公开(公告)号：US4250112A
公开(公告)日：1981-02-10
申请号：US037007
申请日：1979-05-08
申请人： Wilfried Lobach , Wolfgang Lehmann , Friedhelm Muller
发明人： Wilfried Lobach , Wolfgang Lehmann , Friedhelm Muller
IPC分类号： C08G73/00 , C08G73/02 , D21H17/54 , D21H17/56 , C07C91/12
CPC分类号： D21H17/54 , C08G73/0206 , Y10S210/928
摘要： Water-soluble polyalkylenepolyamines which are not self-crosslinking and contain quaternary dialkylammonium groups, and which are obtained by reaction of polyalkylenepolyamines of the general formula ##STR1## in which R denotes hydrogen or methyl,y denotes the number 0 or 1 and the y's may be identical or different andx denotes a number from 2 to 15,with bifunctional compounds of the general formula ##STR2## in which z denotes a number from 1 to 6 andR.sub.1 and R.sub.2 denote lower alkyl or lower hydroxyalkyl, are suitable for use as auxiliaries in the manufacture of paper.
摘要翻译：不是自交联并含有季二烷基铵基团的水溶性聚亚烷基多胺，其通过通式（IMAGE）的聚亚烷基多胺反应得到，其中R表示氢或甲基，y表示数字0或1，y可以相同或不同，x表示2至15的数，具有通式“IMAGE”的双官能化合物，其中z表示1至6的数，R1和R2表示低级烷基或低级羟烷基，适用于助剂在纸的制造。

6. 发明授权

US4481319A Low-foam surface sizing agents for paper which contain copolymeric _maleic anhydride semi-amides 失效
标题翻译：用于含有共聚马来酸酐半酰胺的纸的低泡表面施胶剂
公开(公告)号：US4481319A
公开(公告)日：1984-11-06
申请号：US410906
申请日：1982-08-24
申请人： Gunter Sackmann , Gunter Kolb , Joachim Probst , Friedhelm Muller , Heinz Baumgen
发明人： Gunter Sackmann , Gunter Kolb , Joachim Probst , Friedhelm Muller , Heinz Baumgen
IPC分类号： C08F8/32 , D21H17/35 , D21H17/43 , D21H17/45 , C08K5/21 , C08K5/05
CPC分类号： D21H17/45 , C08F8/32 , D21H17/35 , D21H17/43
摘要： Low-foam surface sizing agents for paper in the form of aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers containing carboxylic acid semi-amide groups obtainable by reacting copolymers of maleic acid anhydride and diisobutylene and/or terpolymers of maleic acid anhydride, diisobutylene and a vinyl monomer copolymerizing with maleic acid anhydride, with from 5 to 50 mole percent, based on maleic acid anhydride groups, of a primary aliphatic or aromatic monoamine. The solutions may optionally contain urea or derivatives of urea.
摘要翻译：水性或水性醇碱金属形式的纸的低泡表面施胶剂，含有羧酸半酰胺基团的共聚物的胺或铵盐溶液，可通过马来酸酐和二异丁烯的共聚物和/或马来酸三元共聚物与马来酸酐共聚的酸酐，二异丁烯和乙烯基单体，基于马来酸酐基团的5-50摩尔％的伯脂肪族或芳族单胺。溶液可以任选地含有脲或尿素衍生物。

7. 发明授权

US4282000A Dyestuff solutions, their preparation and their use for dyeing paper 失效
标题翻译：染料溶液，其制备及其用于染色纸的用途
公开(公告)号：US4282000A
公开(公告)日：1981-08-04
申请号：US115529
申请日：1980-01-25
申请人： Manfred Groll , Friedhelm Muller
发明人： Manfred Groll , Friedhelm Muller
IPC分类号： C09B69/00 , C09B47/26 , C09B67/26 , C09B69/04 , D21H21/28 , C09B47/08
CPC分类号： C09B69/04 , C09B47/26 , C09B67/0073 , D21H21/28 , Y10S8/919
摘要： Aqueous solutions of copper phthalocyanine-sulphonic acid salts of the formula ##STR1## in which Cu--Pc a copper phthalocyanine radical,m a number from 1.8 to 3.0,q a number from 1.0 to 2.0, with the proviso that the sum m+q is a number from 2.8 to 4.0, andM.sup..sym. a mixture of A.sub.n.sup..sym. and an ammonium ion of the formula ##STR2## wherein A.sup..sym. represents an alkali metal ion or NH.sub.4 ion,n represents a number from 0.8 to 2.0,m has the meaning indicated above,R.sub.1 and R.sub.2 designate hydrogen, C.sub.1 --C.sub.4 --alkyl or a radical --(CH.sub.2 --CH.sub.2 --O).sub.p --H andR.sub.3 designates the radical --(CH.sub.2 --CH.sub.2 --O).sub.p --H,whereinp is 1, 2, 3, 4, 5 or 6,process for the preparation of these solutions and their use for dyeing paper.
摘要翻译：铜酞菁磺酸盐的水溶液，其结构式为“IMAGE”，其中Cu-Pc为铜酞菁基，m为1.8至3。

8. 发明授权

US4250298A Polyamines containing amide groups 失效
标题翻译：含多胺的酰胺基
公开(公告)号：US4250298A
公开(公告)日：1981-02-10
申请号：US969820
申请日：1978-12-15
申请人： Wolfgang Lehmann , Friedhelm Muller , Wilfried Lobach , Gunther Cramm , Knut Hammerstrom
发明人： Wolfgang Lehmann , Friedhelm Muller , Wilfried Lobach , Gunther Cramm , Knut Hammerstrom
IPC分类号： C08G69/00 , C08G69/26 , C08G69/36 , C08G69/48 , C08G73/00 , C08G73/02 , D21H17/55 , D21H17/56
CPC分类号： C08G73/0206 , C08G69/48 , D21H17/55
摘要： Water-soluble amines which are not self-crosslinking and are obtainable by reacting(A) one or more water-soluble or water-dispersable amines containing amide groups, prepared by condensation of (a) 1 mol of dicarboxylic acid or functional derivatives thereof, (b) 0 to 30 mols of aminocarboxylic acids containing at least three C atoms, or lactams thereof, and (c) 1.4 to 30 mols of polyalkylenepolyamines of the general formula ##STR1## in which R denotes H or CH.sub.3,y is in each case the same or different and denotes the number 0 or 1 andx denotes a number from 4 to 15,and(B) compounds which are polyfunctional towards amino groups, are suitable as agents for increasing the retention of fibres, fillers and pigments, for accelerating drainage during the production of paper and for working up effluents from paper machines.
摘要翻译：不是自交联的水溶性胺，可通过使（A）一种或多种含有酰胺基团的水溶性或水分散性胺（a）1mol二羧酸或其官能衍生物（b）0至30摩尔含有至少3个C原子的氨基羧酸或其内酰胺，和（c）1.4至30摩尔的通式为“IMAGE”的聚亚烷基多胺，其中R表示H或CH3，y分别表示情况相同或不同，表示数字0或1，x表示4至15的数字，和（B）对氨基具有多官能团的化合物适合作为增加纤维，填料和颜料保留的试剂，用于在纸张生产过程中加速排水，并从造纸机处理废水。

9. 发明授权

US4166002A Polyamines containing acid groups that are useful in papermaking 失效
标题翻译：含有酸性基团的多胺可用于造纸
公开(公告)号：US4166002A
公开(公告)日：1979-08-28
申请号：US528324
申请日：1974-11-29
申请人： Wolfgang Lehmann , Gerhard Troemel , Kurt Ley , Friedhelm Muller
发明人： Wolfgang Lehmann , Gerhard Troemel , Kurt Ley , Friedhelm Muller
IPC分类号： C08G69/48 , C08G73/02 , D21H17/54 , D21H3/58
CPC分类号： D21H17/54 , C08G69/48 , C08G73/0206 , C08G73/028
摘要： Water-soluble polyamines which (a) have an average molecular weight of above 1,000, (b) contain at least one grouping of the formula-- R -- Zin whichZ denotes a --COOH or --SO.sub.3 H group andR represents an alkylene radical, possessing 1 to 7 C atoms, which is optionally substituted and/or interrupted by a carbonamido group,Bonded to a basic nitrogen atom, and which (c) are obtainable either by reaction of water-soluble low molecular polyamines with compounds which introduce acid groups and with compounds which are polyfunctional towards amino groups, or by reaction of water-soluble higher-molecular polyamines, having an amine equivalent of 43 to 700, in which a hydrogen atom is bonded to at least every twentieth basic nitrogen atom, with compounds which introduce acid groups and optionally with compounds which are polyfunctional towards amino groups; a process for their manufacture and their use as agents for increasing the retention of fibres, fillers and pigments in the manufacture of paper and for working-up papermaking machine effluents by filtration, sedimentation and flotation.
摘要翻译：（a）平均分子量大于1000的水溶性多胺，（b）含有至少一个式-R Z的基团，其中Z表示-COOH或-SO 3 H基团，R代表亚烷基，具有1至7个C原子，其任选被碳酰氨基取代和/或中断，与碱性氮原子键合，并且（C）可通过与可溶性低分子量聚氨酯反应而获得，所述化合物与引入酸性基团的化合物以及具有氨基官能团的化合物，或通过反应可溶于高分子量聚氨酯的化合物，其具有43至700的胺等价物，其中氢原子连接至少至少两个基本氮原子，其化合物引用酸性组合和可选择性地与多官能团组合的氨基酸组成; 其制造方法及其作为代理人的用途，用于增加纸张制造中的纤维，填料和颜料的保留以及通过过滤，沉淀和漂浮的加工造纸机的工作。

10. 发明授权

US4152312A Paper-sizing agents 失效
标题翻译：造纸代理
公开(公告)号：US4152312A
公开(公告)日：1979-05-01
申请号：US529695
申请日：1974-12-05
申请人： Gunter Sackmann , Wulf VON Bonin , Friedhelm Muller , Gunter Kolb
发明人： Gunter Sackmann , Wulf VON Bonin , Friedhelm Muller , Gunter Kolb
IPC分类号： D21H19/20 , C08F8/00 , C08F10/00 , C08F22/04 , D21H17/35 , D21H17/43 , C08L33/02
CPC分类号： D21H17/43 , C08F10/00 , C08F22/04 , C08F8/00
摘要： Anionic sizes for paper or a paper-like material. Substantially equimolecular copolymers of maleic acid anhydride and diisobutylene are esterified to form the corresponding semi-esters. From 10 to 100 mol-% of the anhydride groups are reacted with an aliphatic or cycloaliphatic alcohol. At least 50 mol-% of the formed carboxylic groups are neutralized with alkali, ammonia or aliphatic amines.

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