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1. 发明申请

WO2006044819A3 STABLE, CATALYZED, HIGH TEMPERATURE COMBUSTION IN MICROCHANNEL, INTEGRATED COMBUSTION REACTORS, METHODS OF CONDUCTING CATALYTIC COMBUSTION IN A MULTIZONE REACTOR, AND METHOD OF MAKING A THERMALLY STABLE CATALYST SUPPORT 审中-公开
标题翻译：稳定，催化，微通道中的高温燃烧，综合燃烧反应器，多级反应器中催化燃烧的方法和制备稳定的催化剂支持的方法
公开(公告)号：WO2006044819A3
公开(公告)日：2006-10-05
申请号：PCT/US2005037290
申请日：2005-10-14
申请人： VELOCYS INC , CAO CHUNSHE , DALY FRANCIS P , WATSON JUNKO M , WANG YONG , HU JIANLI , LONG RICHARD , TAHA RACHID
发明人： DALY FRANCIS P , WATSON JUNKO M , WANG YONG , HU JIANLI , LONG RICHARD , TAHA RACHID
IPC分类号： B01J19/00
CPC分类号： B01J19/0093 , B01J23/42 , B01J23/63 , B01J23/6567 , B01J37/0201 , B01J37/0225 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/0086 , B01J2219/00873 , B01J2219/00889 , B01J2219/00891 , C01B3/384 , C01B3/386 , C01B3/40 , C01B2203/0233 , C01B2203/0261 , C01B2203/0844 , C01B2203/1011 , C01B2203/1023 , C01B2203/1029 , C01B2203/1035 , C01B2203/107 , C01B2203/1082 , C01B2203/1241 , C01B2203/141 , C01B2203/82 , Y02P20/52
摘要： Catalysts containing preferably 30 weight percent or more platinum have surprisingly been discovered to possess superior stability and activity for catalyzing combustion reactions. The addition of rhenium improves catalyst performance in fuel lean conditions but has undesirable effects in fuel rich conditions. The invention provides integrated combustion microreactors (10), chemical systems utilizing these integrated combustion microreactors (10), methods of combustion, and methods of providing heat to endothermic reactions (20) in integrated combustion microreactors (10). The invention also provides methods of combusting a fuel in a reactor that includes at least 3 zones each of which contains a solid catalyst (14). A method of making a thermally-stable alumina support from fumed alumina is also described.
摘要翻译：令人惊奇地发现含有优选30重量％或更多的铂的催化剂具有优异的催化燃烧反应的稳定性和活性。添加铼提高了燃料贫乏条件下的催化剂性能，但在富燃料条件下具有不良影响。本发明提供集成燃烧微反应器（10），利用这些综合燃烧微反应器（10）的化学系统，燃烧方法，以及向集成燃烧微反应器（10）中的吸热反应（20）提供热量的方法。本发明还提供在反应器中燃烧燃料的方法，其包括至少3个区，每个区含有固体催化剂（14）。还描述了由热解氧化铝制备热稳定氧化铝载体的方法。

2. 发明申请

WO2005075606B1 FISCHER-TROPSCH SYNTHESIS USING MICROCHANNEL TECHNOLOGY AND NOVEL CATALYST AND MICROCHANNEL REACTOR 审中-公开
标题翻译：使用微通道技术和新型催化剂和微通道反应器的FISCHER-TROPSCH合成
公开(公告)号：WO2005075606B1
公开(公告)日：2005-11-17
申请号：PCT/US2004042065
申请日：2004-12-15
申请人： VELOCYS INC , WANG YONG , TONKOVICH ANNA LEE , MAZANEC TERRY , DALY FRANCIS P , VANDERWIEL DAVE , HU JIANLI , CAO CHUNSHE , KIBBY CHARLES , LI XIAOHONG , BRISCOE MICHAEL D , GANO NATHAN , CHIN YA-HUEI
发明人： WANG YONG , TONKOVICH ANNA LEE , MAZANEC TERRY , DALY FRANCIS P , VANDERWIEL DAVE , HU JIANLI , CAO CHUNSHE , KIBBY CHARLES , LI XIAOHONG , BRISCOE MICHAEL D , GANO NATHAN , CHIN YA-HUEI
IPC分类号： B01J19/00 , B01J19/24 , B01J21/04 , B01J23/75 , B01J23/889 , B01J23/89 , B01J35/10 , B01J37/02 , C10G2/00
CPC分类号： C10G2/332 , B01J19/0093 , B01J21/04 , B01J23/75 , B01J23/8896 , B01J23/8913 , B01J35/0066 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J2219/00783 , B01J2219/00822 , B01J2219/00824 , B01J2219/00826 , B01J2219/00831 , B01J2219/00835 , B01J2219/00844 , B01J2219/0086 , B01J2219/00873 , C10G2/341 , C10G2300/301 , C10G2300/4018 , C10G2300/4025 , C10G2300/70 , C10G2400/04 , C10G2400/10 , Y02P20/582
摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and Co to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.
摘要翻译：所公开的发明涉及将包含H 2和Co的反应物组合物转化成包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

3. 发明申请

WO2007075428A2 ALCOHOL SYNTHESIS FROM CO OR CO2 审中-公开
标题翻译：醇或二氧化碳合成醇
公开(公告)号：WO2007075428A2
公开(公告)日：2007-07-05
申请号：PCT/US2006047935
申请日：2006-12-16
申请人： BATTELLE MEMORIAL INSTITUTE , HU JIANLI , WANG YONG , DAGLE ROBERT A , CAO CHUNSHE , ELLIOTT DOUGLAS C , STEVENS DON J , WHITE JAMES F , HOLLADAY JAMELYN D
发明人： HU JIANLI , WANG YONG , DAGLE ROBERT A , CAO CHUNSHE , ELLIOTT DOUGLAS C , STEVENS DON J , WHITE JAMES F , HOLLADAY JAMELYN D
IPC分类号： C07C29/151 , B01J19/00 , C07C1/24 , C07C29/157 , C07C29/32
CPC分类号： C07C29/152 , B01J19/0093 , B01J2219/00835 , B01J2219/00873 , B01J2219/00961 , B01J2219/00984 , C07C29/157 , Y02P20/52 , C07C31/04 , C07C31/08 , C07C31/02
摘要： Methods for producing alcohols from CO or CO 2 and H 2 utilizing a palladium- zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C 2+ oxygenates can produced utilizing Rh-Mn or a Fisher-Tropsch catalyst.
摘要翻译：描述了使用氧化铝催化剂上的钯 - 锌从CO或CO 2 H 2和H 2 H生产醇的方法。还描述了在微通道中在各种催化剂上合成醇的方法。可以使用Rh-Mn或Fisher-Tropsch催化剂制备乙醇，高级醇和其它C 2 + N 2氧化物。

4. 发明申请

WO2007089527A3 METHOD OF FORMING A DIANHYDROSUGAR ALCOHOL 审中-公开
标题翻译：形成二氢化AR醇的方法
公开(公告)号：WO2007089527A3
公开(公告)日：2008-01-17
申请号：PCT/US2007001996
申请日：2007-01-25
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN , WERPY TODD A , HU JIANLI , WANG YONG , ZHANG XINJIE
发明人： HOLLADAY JOHNATHAN , WERPY TODD A , HU JIANLI , WANG YONG , ZHANG XINJIE
IPC分类号： C07D493/04
CPC分类号： C07D307/20 , C07D493/04 , Y02P20/127
摘要： The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
摘要翻译：本发明包括生产二脱水甘油糖的方法。多元醇在第一催化剂存在下反应形成单环糖。将单环糖转移到第二反应器中，在第二反应器中，在第二催化剂的存在下将其转化为二脱水甘油醇。本发明包括形成异山梨醇的方法。在固体酸催化剂存在下，在第一温度下进行初始反应。初始反应包括使山梨醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露聚糖和2,5-己烷。利用第二温度，将1,4-脱水山梨醇和3,6-脱水山梨醇转化为异山梨醇。本发明包括从含有异山梨醇和至少一种另外的组分的混合物中纯化异山梨醇的方法。第一蒸馏从混合物中除去第一部分的异山梨醇。然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分的异山梨醇。

5. 发明申请

WO2007089510A3 METHODS FOR DEHYDRATION OF SUGARS 审中-公开
标题翻译：蔗糖脱水方法
公开(公告)号：WO2007089510A3
公开(公告)日：2008-01-17
申请号：PCT/US2007001945
申请日：2007-01-24
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN E , HU JIANLI , ZHANG XINJIE , WANG YONG
发明人： HOLLADAY JOHNATHAN E , HU JIANLI , ZHANG XINJIE , WANG YONG
IPC分类号： C07D493/04 , C07H1/00 , C07H3/10 , C08G63/672
CPC分类号： C07D493/04
摘要： The invention includes a method of dehydration of a sugar using a dehydration catalyst and a co-catalyst within a reactor. A sugar is introduced and H 2 is flowed through the reactor at a pressure of less than or equal to about 300 psig to convert at least some of the sugar into an anhydrosugar product. The invention includes a process for producing isosorbide. A starting material comprising sorbitol is flowed into a reactor. H 2 is counter flowed through the reactor. The starting material is exposed to a catalyst in the presence of a co- catalyst which comprises at least one metal. The exposing is conducted at a hydrogen pressure of less than or equal to 300 psig within the reactor and the hydrogen removes at least some of any water present during the exposing and inhibits formation of colored byproducts.
摘要翻译：本发明包括使用反应器内的脱水催化剂和助催化剂使糖脱水的方法。引入糖，并且H 2 O 2以小于或等于约300psig的压力流过反应器，以将至少一些糖转化为脱水糖产物。本发明包括制备异山梨醇的方法。将含有山梨醇的原料流入反应器。 H 2反向流过反应器。在包含至少一种金属的助催化剂的存在下，将原料暴露于催化剂。暴露在反应器内在小于或等于300psig的氢气压力下进行，并且氢去除暴露期间存在的任何水中的至少一些，并且抑制着色副产物的形成。

6. 发明申请

WO2007089527B1 METHOD OF FORMING A DIANHYDROSUGAR ALCOHOL 审中-公开
标题翻译：形成二醛醇的方法
公开(公告)号：WO2007089527B1
公开(公告)日：2008-03-06
申请号：PCT/US2007001996
申请日：2007-01-25
申请人： BATTELLE MEMORIAL INSTITUTE , HOLLADAY JOHNATHAN , WERPY TODD A , HU JIANLI , WANG YONG , ZHANG XINJIE
发明人： HOLLADAY JOHNATHAN , WERPY TODD A , HU JIANLI , WANG YONG , ZHANG XINJIE
IPC分类号： C07D493/04
CPC分类号： C07D307/20 , C07D493/04 , Y02P20/127
摘要： The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.
摘要翻译：本发明包括生产二脱水糖的方法。多元醇在第一催化剂存在下反应形成单环糖。将单环糖转移到第二反应器中，在第二反应器中在第二催化剂的存在下将其转化成二水糖醇。本发明包括形成异山梨醇的方法。初始反应在固体酸催化剂存在下的第一温度下进行。最初的反应包括使山梨糖醇反应生成1,4-脱水山梨糖醇，3,6-脱水山梨糖醇，2,5-甘露糖醇和2,5-戊二酸。利用第二温度，1,4-脱水山梨糖醇和3,6-脱水山梨糖醇转化为异山梨醇。本发明包括从含有异山梨醇和至少一种附加组分的混合物中纯化异山梨醇的方法。第一次蒸馏从混合物中除去第一部分异山梨醇。然后在较高温度下进行第二次蒸馏以从混合物中除去第二部分异山梨醇。

7. 发明申请

WO2007075432A2 METHODS OF PRODUCING HYDROGEN VIA THE WATER-GAS SHIFT REACTION OVER A PD-ZN CATALYST 审中-公开
标题翻译：通过PD-ZN催化剂上的水煤气变换反应产生氢气的方法
公开(公告)号：WO2007075432A2
公开(公告)日：2007-07-05
申请号：PCT/US2006047939
申请日：2006-12-14
申请人： BATTELLE MEMORIAL INSTITUTE , DAGLE ROBERT A , WANG YONG , HU JIANLI
发明人： DAGLE ROBERT A , WANG YONG , HU JIANLI
IPC分类号： C01B3/16
CPC分类号： C01B3/16 , B01J19/0093 , B01J23/60 , B01J37/0201 , B01J2219/00783 , B01J2219/00788 , B01J2219/00826 , B01J2219/00835 , B01J2219/0086 , B01J2219/00867 , B01J2219/00873 , C01B2203/0283 , C01B2203/1029 , C01B2203/1035 , C01B2203/1064 , C01B2203/1076 , Y02P20/52
摘要： Methods for producing hydrogen via the water-gas shift reaction utilizing a palladium-zinc on alumina catalyst are described.
摘要翻译：描述了使用钯 - 氧化铝催化剂通过水煤气变换反应制备氢的方法。

8. 发明申请

WO2009030092A1 CULTURE MEDIUM AND METHOD FOR IN VITRO CULTURING HUMAN ADULT PRIMARY MESENCHYMAL STEM CELLS ON A LARGE SCALE, PRIMARY MESENCHYMAL STEM CELLS OBTAINED BY THE METHOD, THE USES THEREOF 审中-公开
标题翻译：文化培养基和方法培养人类成年原代细胞干细胞在大规模，主要的细胞干细胞获得方法，其用途
公开(公告)号：WO2009030092A1
公开(公告)日：2009-03-12
申请号：PCT/CN2007070637
申请日：2007-09-05
申请人： INST BASIC MED SCIENCES PLA , ZHAO CHUNHUA , HAN QIN , LI JING , SUN ZHAO , HU JIANLI , ZHU YASHU , LU SHAN , BIAN CHUNJING
发明人： ZHAO CHUNHUA , HAN QIN , LI JING , SUN ZHAO , HU JIANLI , ZHU YASHU , LU SHAN , BIAN CHUNJING
IPC分类号： A61K35/28 , A61P35/00 , C12N5/0775
CPC分类号： C12N5/0663 , A61K35/28
摘要： A method for in vitro preparing human adult primary mesenchymal stem cells (pMSCs, which are positive for Flk1 marker and Nanog marker) derived from human adult tissues (marrow) on a large scale and the products obtained by the same are provided. Uses of the method and the products obtained by the same in inhibiting the proliferation of tumor cells are also provided. By modifying the key processes and parameters of the preparation of pMSCs, for example simplifying the process of magnetic cell sorting, using human serum culture medium instead of bovine serum culture medium, and using the culture condition at low concentration oxygen (2%), the aim of preparing pMSCs on a large scale is achieved. By using the property of expressing Nanog gene of pMSCs, the novel use of pMSCs in inhibiting the proliferation of tumor cells is invented.
摘要翻译：提供了一种从人成人组织（骨髓）大量产生的人成体原代间充质干细胞（pMSCs，对Flk1标记和Nanog标记物呈阳性）的体外制备方法。还提供了该方法及其获得的产品在抑制肿瘤细胞增殖方面的用途。通过修改pMSCs制备的关键过程和参数，例如简化磁性细胞分选过程，使用人血清培养基代替牛血清培养基，并使用低浓度氧气（2％）的培养条件，实现大规模制备pMSCs的目的。通过使用表达pMSCs的Nanog基因的性质，发明了pMSCs在抑制肿瘤细胞增殖中的新用途。

9. 发明申请

WO2008151269A3 PALLADIUM CATALYZED HYDROGENATION OF BIO-OILS AND ORGANIC COMPOUNDS 审中-公开
标题翻译：生物油和有机化合物的钯催化氢化
公开(公告)号：WO2008151269A3
公开(公告)日：2009-07-30
申请号：PCT/US2008065884
申请日：2008-06-05
申请人： BATTELLE MEMORIAL INSTITUTE , ELLIOTT DOUGLAS C , HU JIANLI , HART TODD R , NEUENSCHWANDER GARY G
发明人： ELLIOTT DOUGLAS C , HU JIANLI , HART TODD R , NEUENSCHWANDER GARY G
IPC分类号： C10G1/06 , C10B53/02 , C10G1/00 , C10G1/08 , C10G3/00
CPC分类号： C07C29/172 , B01J21/18 , B01J23/44 , B01J23/462 , B01J37/0201 , C07C29/149 , C07C2601/08 , C07C2601/14 , C07D307/06 , C10G1/00 , C10G1/06 , C10G1/086 , C10G3/47 , C10G3/48 , C10G3/50 , C10G2300/1014 , C10G2300/4018 , Y02E50/14 , Y02E50/32 , Y02P20/52 , Y02P30/20 , C07C35/14 , C07C35/08 , C07C31/04 , C07C31/08 , C07C31/20 , C07C31/125 , C07C35/06
摘要： The invention provides palladium-catalyzed hydro of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydro of organic compounds typically found in bio-oils.
摘要翻译：本发明提供钯催化的生物油和某些有机化合物的氢。实验结果显示了钯催化的通常在生物油中发现的有机化合物的氢气的意想不到的和优异的结果。

10. 发明申请

WO2008054804A3 HYDROXYMETHYL FURFURAL OXIDATION METHODS 审中-公开
标题翻译：羟丙基氧化氧化方法
公开(公告)号：WO2008054804A3
公开(公告)日：2008-09-18
申请号：PCT/US2007023063
申请日：2007-10-31
申请人： BATTELLE MEMORIAL INSTITUTE , LILGA MICHAEL A , HALLEN RICHARD T , HU JIANLI , WHITE JAMES F , GARY MICHEL J
发明人： LILGA MICHAEL A , HALLEN RICHARD T , HU JIANLI , WHITE JAMES F , GARY MICHEL J
IPC分类号： C07D307/44 , B01J23/00 , C07D307/48
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O 2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50°C to about 200°C A method of producing an oxidation catalyst where ZrO 2 is provided and is calcined. The ZrO 2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O 2 .
摘要翻译：氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中提供包含HMF的起始材料进入反应器。将空气和O 2 2中的至少一个提供到反应器中。使起始材料与载体材料上的Pt催化剂接触，在载体材料上进行接触，反应器温度为约50℃至约200℃，制备氧化催化剂的方法，其中ZrO 2 并被煅烧。将ZrO 2 2与乙酰丙酮铂（II）混合以形成混合物。将混合物进行旋转蒸发以形成产物。将产物在氢气下煅烧和还原以形成活化产物。活化产物在2％O 2 2的流下被钝化。

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