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    • 2. 发明授权
    • Use of hydroxyaromatics as safeners
    • 使用羟基芳烃作为安全剂
    • US08138118B2
    • 2012-03-20
    • US10911706
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N43/72
    • A01N37/40A01N25/32A01N43/80A01N47/36A01N2300/00
    • Compounds of the formula (I) or salts thereof in which R1 is carboxyl or a derivative of a carboxyl group, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(═X)-Het, in which X is O, S or NRa or N—NRaRb, Y is O, S, NRc or NRc—NRdRe, R is H, a (subst.) hydrocarbon radical (HR) or acyl, and Het is an aliphatic nitrogen heterocycle, where each of the radicals Ra, Rb, Rc, Rd and Re is as defined for R or a radical of the formula —OR*, where R* is as defined for R, R2 is H or (subst.) HR or a heterocyclic radical, or, if Z═O or S, also an acyl radical, (R3)n are n radicals R3, as defined in claim 1, Z is a group of the formula O or S(O)x, where x=0, 1 or 2, and n is an integer 0, 1, 2, 3 or 4, as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides, such as herbicides, in these plants.
    • 式(I)的化合物或其盐,其中R 1是羧基或羧基的衍生物,优选式-CN,-C(= X)-Y-R或-C(= X) - Het,其中X是O,S或NRa或N-NRaRb,Y是O,S,NRc或NRc-NRdRe,R是H,a(取代)烃基(HR)或酰基,Het是脂族 氮杂环,其中每个基团R a,R b,R c,R d和R e如R所定义或式-OR *的基团,其中R *如对R所定义,R 2为H或(取代)HR 或杂环基,或者如果Z = O或S也是酰基,则(R3)n是如权利要求1所定义的n个基团R 3,Z是式O或S(O)x的基团,其中 x = 0,1或2,n为整数0,1,2,3或4,作为农作物或有用植物的安全剂,以防止农药的植物毒性作用,优选作为防止农药如除草剂的作用的安全剂, 在这些植物中。
    • 4. 发明授权
    • Safeners based on acrylic-aliphatic carboxylic acid derivatives
    • 基于丙烯酸 - 脂族羧酸衍生物的安全剂
    • US07838463B2
    • 2010-11-23
    • US10911669
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N37/36A01N47/40
    • A01N25/32A01N37/10A01N37/40A01N43/80A01N47/36A01N57/20A01N2300/00
    • Compounds of the formula (I) or salts thereof, which R1 is COOH or a derivative thereof, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(X′R′)(X″R″)—Y—R, in which R is H, a (subst.) hydrocarbon radical, a heterocyclic radical or acyl, Y is a direct bond or O, S, NRc or NRc—NRdRe, n is the integer 1, 2, 3, 4, 5 or 6 and R′, R″, X, X′, X″, Ra, Rb, Rc, Rd, Re, R2, R3 (R4)m are as defined in claim 1 are suitable as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides such as herbicides in these plants, where compounds of the formula (I) or salts thereof in which R1 is COOH, R2, R3 are each hydrogen, (R4)m is a hydroxyl radical (m=1) in any position or two radicals R4 (m=2) in any position, where in the latter case one radical is a hydroxyl group and the other radical is hydroxyl or methoxy, and n is the number 1, are used as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals other than glyphosate.
    • 式(I)化合物或其盐,其中R 1为COOH或其衍生物,优选式-CN,-C(= X)-Y-R或-C(X'R')(X “R”)-Y-R,其中R为H,(基)烃基,杂环基或酰基,Y为直接键或O,S,NRc或NRc-NRdRe,n为整数1 ,2,3,4,5或6,R',R“,X,X',X”,Ra,Rb,Rc,Rd,Re,R2,R3(R4)m如权利要求1中所定义, 作为防治农药的植物毒性作用的安全剂,优选作为防止农药如这些植物中除草剂作用的安全剂,其中R1为COOH,R2,R3的式(Ⅰ)化合物或其盐为 每个氢,(R4)m是在任何位置的任何位置或两个基团R 4(m = 2)的羟基(m = 1),其中在后一种情况下一个基团是羟基,另一个基团是羟基或 甲氧基,n为数1,用作作物作物或用途的安全剂 l植物除草甘膦以外的农药的植物毒性作用。
    • 5. 发明申请
    • Use of hydroxyaromatics as safeners
    • 使用羟基芳烃作为安全剂
    • US20050037922A1
    • 2005-02-17
    • US10911706
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N37/40A01N43/80A01N47/36
    • A01N37/40A01N25/32A01N43/80A01N47/36A01N2300/00
    • Compounds of the formula (I) or salts thereof in which R1 is carboxyl or a derivative of a carboxyl group, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(═X)-Het, in which X is O, S or NRa or N—NRaRb, Y is O, S, NRc or NRc—NRdRe, R is H, a (subst.) hydrocarbon radical (HR) or acyl, and Het is an aliphatic nitrogen heterocycle, where each of the radicals Ra, Rb, Rc, Rd and Re is as defined for R or a radical of the formula —OR*, where R* is as defined for R, R2 is H or (subst.) HR or a heterocyclic radical, or, if Z=O or S, also an acyl radical, (R3)n are n radicals R3, as defined in claim 1, Z is a group of the formula O or S(O)x, where x=0, 1 or 2, and n is an integer 0, 1, 2, 3 or 4, as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides, such as herbicides, in these plants.
    • 式(I)的化合物或其盐,其中R 1是羧基或羧基的衍生物,优选式-CN,-C(= X)-YR或-C(= X)的基团, -Het,其中X是O,S或NR,或N-NR a R b,Y是O,S,NR c或NR c -NR d R e >,R为H,(基)烃基(HR)或酰基,Het为脂族氮杂环,其中基团R a,R b,R c,R d, 并且R e如R定义或式-OR *的基团,其中R *如R所定义,R 2是H或(取代的)HR或杂环基,或如果 Z = O或S也是酰基,(R 3)n是如权利要求1中定义的n个基团R 3,Z是式O或S(O)x的基团,其中x = 0,1或2,以及n为整数0,1,2,3或4,作为农作物或有用植物的抗病毒剂,以防止农药的植物毒性作用,优选作为安全剂抵抗杀虫剂如除草剂的作用,在这些 植物。
    • 7. 发明申请
    • Safeners based on acrylic-aliphatic carboxylic acid derivatives
    • 基于丙烯酸 - 脂族羧酸衍生物的安全剂
    • US20050049145A1
    • 2005-03-03
    • US10911669
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N33/04A01N35/02A01N35/10A01N37/06A01N37/10A01N37/12A01N37/18A01N37/20A01N37/26A01N37/40A01N37/52A01N43/80A01N47/36A01N47/42A01N47/46A01N57/20
    • A01N25/32A01N37/10A01N37/40A01N43/80A01N47/36A01N57/20A01N2300/00
    • Compounds of the formula (I) or salts thereof, which R1 is COOH or a derivative thereof, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(X′R′)(X″R″)—Y—R, in which R is H, a (subst.) hydrocarbon radical, a heterocyclic radical or acyl, Y is a direct bond or O, S, NRc or NRc—NRdRe, n is the integer 1, 2, 3, 4, 5 or 6 and R′, R″, X, X′, X″, Ra, Rb, Rc, Rd, Re, R2, R3 (R4)m are as defined in claim 1 are suitable as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides such as herbicides in these plants, where compounds of the formula (I) or salts thereof in which R1 is COOH, R2, R3 are each hydrogen, (R4)m is a hydroxyl radical (m=1) in any position or two radicals R4 (m=2) in any position, where in the latter case one radical is a hydroxyl group and the other radical is hydroxyl or methoxy, and n is the number 1, are used as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals other than glyphosate.
    • 式(I)化合物或其盐,其中R 1是COOH或其衍生物,优选式-CN,-C(= X)-YR或-C(X'R')( X'R“)-YR,其中R是H,(基)烃基,杂环基或酰基,Y是直接键或O,S,NR c或NR c - NR R e,n是整数1,2,3,4,5或6,R',R“,X,X',X”,R a,R b, R c,R d,R e,R 2,R 3(R 4)m如权利要求1中所定义适合作为作物植物或有用植物抗病毒植物的安全剂 其中R 1为COOH,R 2,R 3的式(I)化合物或其盐的化合物,其中R 1为COOH,R 2,R 3各自为农药的作用,优选作为防止农药如除草剂作用的安全剂 氢,(R 4)m是在任何位置的任何位置或两个基团R 4(m = 2)中的羟基(m = 1),其中在后一种情况下,一个基团是羟基, 其他基团是羟基或甲氧基,n是数字1,用作作物作物的安全剂 有用的植物防止除草甘膦以外的农药的植物毒性作用。
    • 9. 发明申请
    • Herbicide-safener combination
    • 除草剂 - 安全剂组合
    • US20050233904A1
    • 2005-10-20
    • US11090985
    • 2005-03-25
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • A01N47/36A01N43/78
    • A01N47/36A01N2300/00
    • The present invention relates to a herbicide-safener combination, comprising (A) one or more compounds of the formula (I) or salts thereof in which A is nitrogen or a CR11 grouping, where R11 is hydrogen, alkyl, halogen and haloalkyl, R1 is hydrogen or an optionally substituted radical from the group consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl, akynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R3 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R4—R7 independently of one another are hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, R8 is hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, where in the radicals mentioned above the alkyl and alkylene groups may in each case contain 1 to 6 carbon atoms, the alkenyl and alkynyl groups may in each case contain 2 to 6 carbon atoms, the cycloalkyl groups may in each case contain 3 to 6 carbon atoms and the aryl groups may in each case contain 6 or 10 carbon atoms; and (B) one or more safeners.
    • 本发明涉及一种除草剂 - 安全剂组合,其包含(A)一种或多种式(I)化合物或其盐,其中A是氮或CR 11组,其中R 0 R 11是氢,烷基,卤素和卤代烷基,R 1是氢或任选被取代的烷基,烷氧基,烷氧基烷基,烯基,炔基,环烷基,环烷基烷基, 芳烷基和芳基,R 2是氢,卤素或在每种情况下任选是卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子, 或者在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子,R 4为R 7, 氢,卤素,氰基,氰硫基,或在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基 氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,R 8为氢,卤素,氰基,氰硫基,或在每种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基, 烷基磺酰基,烷基氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,其中在上述烷基和亚烷基中的基团可以在每种情况下含有1至6个碳原子,烯基和炔基可以在每种情况下 含有2至6个碳原子,环烷基可以在每种情况下都含有3至6个碳原子,并且芳基各自可含有6或10个碳原子; 和(B)一个或多个安全剂。