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    • 3. 发明申请
    • Use of sulfonylureas
    • 磺酰脲类的使用
    • US20050233908A1
    • 2005-10-20
    • US11090424
    • 2005-03-25
    • Martin HillsHansjorg KrahmerChristian WaldraffHansjorg DietrichDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • Martin HillsHansjorg KrahmerChristian WaldraffHansjorg DietrichDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • A01N47/36A01N43/72A01N43/78
    • A01N47/36
    • The invention relates to the use of compounds of the formula (I) and salts thereof for the selective control of unwanted vegetation in leguminous plants or for the non-selective control of unwanted vegetation in which A is nitrogen or a CR11 grouping, where R11 is hydrogen, alkyl, halogen or haloalkyl, R1 is hydrogen optionally substituted radical from the group consisting of alkyl alkoxy, alkoxyalkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 hydrogen, halogen or is in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R3 is hydrogen, halogen or is in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R4—R7 independently of one another are hydrogen, halogen, cyano, thiocyanato or are in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, R8 is hydrogen, halogen, cyano, thiocyanato or is in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, where in the radicals mentioned above the alkyl and alkylene groups may each contain 1 to 6 carbon atoms, the alkenyl and alkynyl groups may each contain 2 to 6 carbon atoms the cycloalkyl groups may each contain 3 to 6 carbon atoms and the aryl groups may each contain 6 or 10 carbon atoms.
    • 本发明涉及式(I)化合物及其盐在豆科植物中选择性控制不想要的植物或非选择性控制不需要的植物的用途,其中A是氮或CR 11, 其中R 11是氢,烷基,卤素或卤代烷基,R 1是从烷基烷氧基,烷氧基烷基,链烯基,烷基, 炔基,环烷基,环烷基烷基,芳烷基和芳基,R 2 O,卤素或在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子, R 3是氢,卤素或在每种情况下任选是卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子,R 4为 -R 7彼此独立地是氢,卤素,氰基,氰硫基,或者在每种情况下都是卤素 取代烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,R 8为氢,卤素,氰基,氰硫基,或在每种情况下 任选的卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基氨基,烷基羰基,烷氧基羰基,烷基氨基羰基,各自为1至3个碳原子,其中在上述烷基和亚烷基基团中各自可含有1至6个碳原子 ,烯基和炔基各自可以含有2至6个碳原子,环烷基各自可以含有3至6个碳原子,芳基可以各自含有6或10个碳原子。
    • 5. 发明授权
    • Substituted sulfonylurea, processes for the production of these
compounds, as well as compositions containing the same and having
herbicidal and plant growth regulating activity
    • 取代的磺酰脲,这些化合物的生产方法,以及含有这些化合物的组合物,并具有除草和植物生长调节活性
    • US4601746A
    • 1986-07-22
    • US623134
    • 1984-06-18
    • Jurgen WestermannGerhard BoroschewskiUlrich EderFriedrich ArndtHansjorg KrahmerClemens Kotter
    • Jurgen WestermannGerhard BoroschewskiUlrich EderFriedrich ArndtHansjorg KrahmerClemens Kotter
    • C07D249/16A01N47/36A01P13/00C07C311/58C07D239/42C07D239/47C07D251/16C07D251/18C07D251/22C07D251/42C07D251/46C07D251/52C07D521/00C07D239/46
    • C07C311/65A01N47/36C07D521/00
    • New substituted sulfonyl urea are disclosed of the general formula ##STR1## in which R.sub.1 is chlorine, --COOR.sub.5, --S(O).sub.n --R.sub.6 or ##STR2## R.sub.2 is ##STR3## or --CH.sub.2 --C.tbd.C--R.sub.11, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, halogen, halogen-C.sub.1 -C.sub.4 -alkyl, halogen-C.sub.1 -C.sub.4 -alkoxy, Di-C.sub.1 -C.sub.3 -alkyl-amino, C.sub.1 -C.sub.3 -alkyl-amino or C.sub.1 -C.sub.3 -alkoxy-C.sub.1 -C.sub.3 -alkoxy,R.sub.4 is hydrogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, halogen, halogen-C.sub.1 -C.sub.4 -alkyl, halogen-C.sub.1 -C.sub.4 -alkoxy, Di-C.sub.1 -C.sub.3 -alkyl-amino, C.sub.1 -C.sub.3 -alkyl-amino, or C.sub.1 -C.sub.3 -alkoxy-C.sub.1 -C.sub.3 -alkoxy,Z is --CH.dbd. or --N.dbd.,R.sub.5 is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.3 -alkoxy-C.sub.1 -C.sub.3 -alkyl, phenyl, substituted phenyl, benzene or substituted benzene,R.sub.6 is C.sub.1 -C.sub.6 -alkyl or phenyl,R.sub.7 is C.sub.1 -C.sub.4 -alkyl,R.sub.8 is C.sub.1 -C.sub.4 -alkyl,R.sub.7 and R.sub.8 are independently C.sub.3 -C.sub.8 -cycloalkyl, morpholinyl, pyrrolidinyl, piperidyl or piperazinyl,R.sub.9 is hydrogen, chlorine, fluorine, or C.sub.1 -C.sub.3 -alkyl,R.sub.10 is hydrogen, chlorine, fluorine, trifluoromethyl or C.sub.1 -C.sub.3 -alkyl,R.sub.11 is hydrogen, chlorine, fluorine, cyano, C.sub.1 -C.sub.4 -alkyl or phenyl,X is oxygen or sulfur, andn is 0, 1 or 2, as well as processes for the preparation of these compounds and compositions having herbicidal and plant growth regulating effectiveness.
    • 公开了通式为I,其中R 1为氯,-COOR 5,-S(O)n -R 6或R 2为“或”-CH 2 -C 3 CON C-R 11“的新取代的磺酰脲, R 3是氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷硫基,卤素,卤素-C 1 -C 4烷基,卤素-C 1 -C 4 - 烷氧基,二-C 1 -C 3 - 烷基 - 氨基,C 1 -C 3烷基 - 氨基或C 1 -C 3 - 烷氧基-C 1 -C 3 - 烷氧基,R 4是C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,卤素,卤素-C 1 -C 4烷基,卤素-C 1 -C 4 - 烷氧基,二-C 1 -C 3 - 烷基 - 氨基,C 1 -C 3 - 烷基 - 氨基或C 1 -C 3 - 烷氧基-C 1 -C 3 - 烷氧基,Z是-CH =或-N =,R 5是C 1 -C 8 - 烷基,C 3 -C 8 - 环烷基,C 1 -C 3 - 烷氧基-C 1 -C 3 - 烷基,苯基,取代的苯基,苯或取代的苯,R 6是C 1 -C 6烷基或苯基,R 7是C 1 -C 4烷基,R 8是 C 1 -C 4 - 烷基,R 7和R 8独立地是C 3 -C 8 - 环烷基,吗啉基,吡咯烷基,哌啶基或哌嗪基,R 9是氢,氯,氟或C 1 -C 3烷基,R 10是氢,氯,氟,三氟甲基或 C 1 -C 3 - 烷基,R 11是氢,氯,氟,氰基,C 1 -C 4 - 烷基 或苯基,X是氧或硫,n是0,1或2,以及制备具有除草和植物生长调节效力的这些化合物和组合物的方法。
    • 6. 发明申请
    • Herbicide-safener combination
    • 除草剂 - 安全剂组合
    • US20050233904A1
    • 2005-10-20
    • US11090985
    • 2005-03-25
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • A01N47/36A01N43/78
    • A01N47/36A01N2300/00
    • The present invention relates to a herbicide-safener combination, comprising (A) one or more compounds of the formula (I) or salts thereof in which A is nitrogen or a CR11 grouping, where R11 is hydrogen, alkyl, halogen and haloalkyl, R1 is hydrogen or an optionally substituted radical from the group consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl, akynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R3 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R4—R7 independently of one another are hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, R8 is hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, where in the radicals mentioned above the alkyl and alkylene groups may in each case contain 1 to 6 carbon atoms, the alkenyl and alkynyl groups may in each case contain 2 to 6 carbon atoms, the cycloalkyl groups may in each case contain 3 to 6 carbon atoms and the aryl groups may in each case contain 6 or 10 carbon atoms; and (B) one or more safeners.
    • 本发明涉及一种除草剂 - 安全剂组合,其包含(A)一种或多种式(I)化合物或其盐,其中A是氮或CR 11组,其中R 0 R 11是氢,烷基,卤素和卤代烷基,R 1是氢或任选被取代的烷基,烷氧基,烷氧基烷基,烯基,炔基,环烷基,环烷基烷基, 芳烷基和芳基,R 2是氢,卤素或在每种情况下任选是卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子, 或者在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子,R 4为R 7, 氢,卤素,氰基,氰硫基,或在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基 氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,R 8为氢,卤素,氰基,氰硫基,或在每种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基, 烷基磺酰基,烷基氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,其中在上述烷基和亚烷基中的基团可以在每种情况下含有1至6个碳原子,烯基和炔基可以在每种情况下 含有2至6个碳原子,环烷基可以在每种情况下都含有3至6个碳原子,并且芳基各自可含有6或10个碳原子; 和(B)一个或多个安全剂。