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    • 2. 发明授权
    • Use of hydroxyaromatics as safeners
    • 使用羟基芳烃作为安全剂
    • US08138118B2
    • 2012-03-20
    • US10911706
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N43/72
    • A01N37/40A01N25/32A01N43/80A01N47/36A01N2300/00
    • Compounds of the formula (I) or salts thereof in which R1 is carboxyl or a derivative of a carboxyl group, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(═X)-Het, in which X is O, S or NRa or N—NRaRb, Y is O, S, NRc or NRc—NRdRe, R is H, a (subst.) hydrocarbon radical (HR) or acyl, and Het is an aliphatic nitrogen heterocycle, where each of the radicals Ra, Rb, Rc, Rd and Re is as defined for R or a radical of the formula —OR*, where R* is as defined for R, R2 is H or (subst.) HR or a heterocyclic radical, or, if Z═O or S, also an acyl radical, (R3)n are n radicals R3, as defined in claim 1, Z is a group of the formula O or S(O)x, where x=0, 1 or 2, and n is an integer 0, 1, 2, 3 or 4, as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides, such as herbicides, in these plants.
    • 式(I)的化合物或其盐,其中R 1是羧基或羧基的衍生物,优选式-CN,-C(= X)-Y-R或-C(= X) - Het,其中X是O,S或NRa或N-NRaRb,Y是O,S,NRc或NRc-NRdRe,R是H,a(取代)烃基(HR)或酰基,Het是脂族 氮杂环,其中每个基团R a,R b,R c,R d和R e如R所定义或式-OR *的基团,其中R *如对R所定义,R 2为H或(取代)HR 或杂环基,或者如果Z = O或S也是酰基,则(R3)n是如权利要求1所定义的n个基团R 3,Z是式O或S(O)x的基团,其中 x = 0,1或2,n为整数0,1,2,3或4,作为农作物或有用植物的安全剂,以防止农药的植物毒性作用,优选作为防止农药如除草剂的作用的安全剂, 在这些植物中。
    • 4. 发明授权
    • Safeners based on acrylic-aliphatic carboxylic acid derivatives
    • 基于丙烯酸 - 脂族羧酸衍生物的安全剂
    • US07838463B2
    • 2010-11-23
    • US10911669
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N37/36A01N47/40
    • A01N25/32A01N37/10A01N37/40A01N43/80A01N47/36A01N57/20A01N2300/00
    • Compounds of the formula (I) or salts thereof, which R1 is COOH or a derivative thereof, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(X′R′)(X″R″)—Y—R, in which R is H, a (subst.) hydrocarbon radical, a heterocyclic radical or acyl, Y is a direct bond or O, S, NRc or NRc—NRdRe, n is the integer 1, 2, 3, 4, 5 or 6 and R′, R″, X, X′, X″, Ra, Rb, Rc, Rd, Re, R2, R3 (R4)m are as defined in claim 1 are suitable as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides such as herbicides in these plants, where compounds of the formula (I) or salts thereof in which R1 is COOH, R2, R3 are each hydrogen, (R4)m is a hydroxyl radical (m=1) in any position or two radicals R4 (m=2) in any position, where in the latter case one radical is a hydroxyl group and the other radical is hydroxyl or methoxy, and n is the number 1, are used as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals other than glyphosate.
    • 式(I)化合物或其盐,其中R 1为COOH或其衍生物,优选式-CN,-C(= X)-Y-R或-C(X'R')(X “R”)-Y-R,其中R为H,(基)烃基,杂环基或酰基,Y为直接键或O,S,NRc或NRc-NRdRe,n为整数1 ,2,3,4,5或6,R',R“,X,X',X”,Ra,Rb,Rc,Rd,Re,R2,R3(R4)m如权利要求1中所定义, 作为防治农药的植物毒性作用的安全剂,优选作为防止农药如这些植物中除草剂作用的安全剂,其中R1为COOH,R2,R3的式(Ⅰ)化合物或其盐为 每个氢,(R4)m是在任何位置的任何位置或两个基团R 4(m = 2)的羟基(m = 1),其中在后一种情况下一个基团是羟基,另一个基团是羟基或 甲氧基,n为数1,用作作物作物或用途的安全剂 l植物除草甘膦以外的农药的植物毒性作用。
    • 5. 发明申请
    • Use of hydroxyaromatics as safeners
    • 使用羟基芳烃作为安全剂
    • US20050037922A1
    • 2005-02-17
    • US10911706
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N37/40A01N43/80A01N47/36
    • A01N37/40A01N25/32A01N43/80A01N47/36A01N2300/00
    • Compounds of the formula (I) or salts thereof in which R1 is carboxyl or a derivative of a carboxyl group, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(═X)-Het, in which X is O, S or NRa or N—NRaRb, Y is O, S, NRc or NRc—NRdRe, R is H, a (subst.) hydrocarbon radical (HR) or acyl, and Het is an aliphatic nitrogen heterocycle, where each of the radicals Ra, Rb, Rc, Rd and Re is as defined for R or a radical of the formula —OR*, where R* is as defined for R, R2 is H or (subst.) HR or a heterocyclic radical, or, if Z=O or S, also an acyl radical, (R3)n are n radicals R3, as defined in claim 1, Z is a group of the formula O or S(O)x, where x=0, 1 or 2, and n is an integer 0, 1, 2, 3 or 4, as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides, such as herbicides, in these plants.
    • 式(I)的化合物或其盐,其中R 1是羧基或羧基的衍生物,优选式-CN,-C(= X)-YR或-C(= X)的基团, -Het,其中X是O,S或NR,或N-NR a R b,Y是O,S,NR c或NR c -NR d R e >,R为H,(基)烃基(HR)或酰基,Het为脂族氮杂环,其中基团R a,R b,R c,R d, 并且R e如R定义或式-OR *的基团,其中R *如R所定义,R 2是H或(取代的)HR或杂环基,或如果 Z = O或S也是酰基,(R 3)n是如权利要求1中定义的n个基团R 3,Z是式O或S(O)x的基团,其中x = 0,1或2,以及n为整数0,1,2,3或4,作为农作物或有用植物的抗病毒剂,以防止农药的植物毒性作用,优选作为安全剂抵抗杀虫剂如除草剂的作用,在这些 植物。
    • 7. 发明申请
    • Safeners based on acrylic-aliphatic carboxylic acid derivatives
    • 基于丙烯酸 - 脂族羧酸衍生物的安全剂
    • US20050049145A1
    • 2005-03-03
    • US10911669
    • 2004-08-04
    • Udo BickersLothar WillmsChristopher Rosinger
    • Udo BickersLothar WillmsChristopher Rosinger
    • A01N25/32A01N33/04A01N35/02A01N35/10A01N37/06A01N37/10A01N37/12A01N37/18A01N37/20A01N37/26A01N37/40A01N37/52A01N43/80A01N47/36A01N47/42A01N47/46A01N57/20
    • A01N25/32A01N37/10A01N37/40A01N43/80A01N47/36A01N57/20A01N2300/00
    • Compounds of the formula (I) or salts thereof, which R1 is COOH or a derivative thereof, preferably a radical of the formula —CN, —C(═X)—Y—R or —C(X′R′)(X″R″)—Y—R, in which R is H, a (subst.) hydrocarbon radical, a heterocyclic radical or acyl, Y is a direct bond or O, S, NRc or NRc—NRdRe, n is the integer 1, 2, 3, 4, 5 or 6 and R′, R″, X, X′, X″, Ra, Rb, Rc, Rd, Re, R2, R3 (R4)m are as defined in claim 1 are suitable as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals, preferably as safeners against the action of pesticides such as herbicides in these plants, where compounds of the formula (I) or salts thereof in which R1 is COOH, R2, R3 are each hydrogen, (R4)m is a hydroxyl radical (m=1) in any position or two radicals R4 (m=2) in any position, where in the latter case one radical is a hydroxyl group and the other radical is hydroxyl or methoxy, and n is the number 1, are used as safeners for crop plants or useful plants against phytotoxic actions of agrochemicals other than glyphosate.
    • 式(I)化合物或其盐,其中R 1是COOH或其衍生物,优选式-CN,-C(= X)-YR或-C(X'R')( X'R“)-YR,其中R是H,(基)烃基,杂环基或酰基,Y是直接键或O,S,NR c或NR c - NR R e,n是整数1,2,3,4,5或6,R',R“,X,X',X”,R a,R b, R c,R d,R e,R 2,R 3(R 4)m如权利要求1中所定义适合作为作物植物或有用植物抗病毒植物的安全剂 其中R 1为COOH,R 2,R 3的式(I)化合物或其盐的化合物,其中R 1为COOH,R 2,R 3各自为农药的作用,优选作为防止农药如除草剂作用的安全剂 氢,(R 4)m是在任何位置的任何位置或两个基团R 4(m = 2)中的羟基(m = 1),其中在后一种情况下,一个基团是羟基, 其他基团是羟基或甲氧基,n是数字1,用作作物作物的安全剂 有用的植物防止除草甘膦以外的农药的植物毒性作用。