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    • 1. 发明申请
    • Herbicide-safener combination
    • 除草剂 - 安全剂组合
    • US20050233904A1
    • 2005-10-20
    • US11090985
    • 2005-03-25
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • Martin HillsErwin HackerHansjorg KrahmerChris RosingerUdo BickersFrank ZiemerChristian WaldraffHansjorg DietrichLothar WillmsDieter FeuchtKlaus-Helmut MullerUlrich Philipp
    • A01N47/36A01N43/78
    • A01N47/36A01N2300/00
    • The present invention relates to a herbicide-safener combination, comprising (A) one or more compounds of the formula (I) or salts thereof in which A is nitrogen or a CR11 grouping, where R11 is hydrogen, alkyl, halogen and haloalkyl, R1 is hydrogen or an optionally substituted radical from the group consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl, akynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R2 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R3 is hydrogen, halogen or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having in each case 1 to 6 carbon atoms, R4—R7 independently of one another are hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, R8 is hydrogen, halogen, cyano, thiocyanato or in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having in each case 1 to 3 carbon atoms, where in the radicals mentioned above the alkyl and alkylene groups may in each case contain 1 to 6 carbon atoms, the alkenyl and alkynyl groups may in each case contain 2 to 6 carbon atoms, the cycloalkyl groups may in each case contain 3 to 6 carbon atoms and the aryl groups may in each case contain 6 or 10 carbon atoms; and (B) one or more safeners.
    • 本发明涉及一种除草剂 - 安全剂组合,其包含(A)一种或多种式(I)化合物或其盐,其中A是氮或CR 11组,其中R 0 R 11是氢,烷基,卤素和卤代烷基,R 1是氢或任选被取代的烷基,烷氧基,烷氧基烷基,烯基,炔基,环烷基,环烷基烷基, 芳烷基和芳基,R 2是氢,卤素或在每种情况下任选是卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子, 或者在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基氨基或二烷基氨基,其各自为1至6个碳原子,R 4为R 7, 氢,卤素,氰基,氰硫基,或在各种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,烷基 氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,R 8为氢,卤素,氰基,氰硫基,或在每种情况下任选为卤素取代的烷基,烷氧基,烷硫基,烷基亚磺酰基, 烷基磺酰基,烷基氨基,烷基羰基,烷氧基羰基,在每种情况下为1至3个碳原子的烷基氨基羰基,其中在上述烷基和亚烷基中的基团可以在每种情况下含有1至6个碳原子,烯基和炔基可以在每种情况下 含有2至6个碳原子,环烷基可以在每种情况下都含有3至6个碳原子,并且芳基各自可含有6或10个碳原子; 和(B)一个或多个安全剂。
    • 7. 发明申请
    • Phenylsulfonyl ureas, process for their preparation and their use as herbicides and plant growth regulators
    • US20060014644A1
    • 2006-01-19
    • US11224153
    • 2005-09-12
    • Hansjorg DietrichChristian WaldraffLothar WillmsHermann BieringerChristopher RosingerFelix ThurwachterThomas Auler
    • Hansjorg DietrichChristian WaldraffLothar WillmsHermann BieringerChristopher RosingerFelix ThurwachterThomas Auler
    • A01N47/36C07D403/02C07D239/46
    • C07D521/00A01N47/36C07C311/16C07C311/39C07D207/32C07D239/42C07D239/47C07D239/52C07D251/42C07D251/46C07D295/155C07D403/12
    • Compounds of the formula (I) or salts thereof in which R1 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R2 is a group of the formula R0-Q0- in which R0 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, and Q is a direct bond or a divalent group of the formula —O— or —N(R#)—, where R# is a hydrogen atom, an acyl radical or a hydrocarbon radical and where the last-mentioned radical is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R3 is a hydrogen atom, a hydrocarbon radical or a heterocyclyl radical, where each of the two last-mentioned radicals is unsubstituted or substituted and, including substituents, has from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, R4 independently of one another, are halogen, OH, SH, a nitrogen-containing radical which does not contain any carbon or a carbon-containing radical, is 0, 1, 2 or 3, preferably 0 or 1, R5 is a hydrogen atom or a C1-C10-hydrocarbon radical which is unsubstituted or substituted, such as (C1-C4)alkyl, preferably H or CH3), Q is O, S or NR*, R* is a hydrogen atom or a C1-C10-hydrocarbon radical which is unsubstituted or substituted such as (C1-C4)alkyl, (C3-C4)alkenyl or (C3-C4)alkynyl, where each of the three last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)alkoxy and (C1-C4)alkylthio, W is an oxygen or sulfur atom, X,Y independently of one another are a hydrogen atom, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alkylthio, where each of the 3 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)alkoxy and (C1-C4)alkylthio, or are mono- or di[(C1-C4)alkyl]amino, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C6)alkenyloxy or (C3-C6)alkynyloxy, and V, Z independently of one another are CH or N, are suitable for use as herbicides or plant growth regulators, for example for controlling harmful plants in crop plants, including transgenic crop plants. They can be prepared by the processes according to claim 6 via intermediates, some of which are novel (cf. compounds (II*) and (X*) and (VIII) as claimed in claims 12, 14 and 16).
    • 8. 发明授权
    • Herbicide/safener combintions
    • 除草剂/安全剂组合
    • US08748343B2
    • 2014-06-10
    • US13601247
    • 2012-08-31
    • Frank ZiemerLothar WillmsHermann BieringerErwin Hacker
    • Frank ZiemerLothar WillmsHermann BieringerErwin Hacker
    • A01N25/26A01N25/32A01N43/36A01N43/80A01N37/10
    • A01N37/42A01N25/32A01N35/06A01N43/56A01N43/80A01N47/36A01N47/30A01N41/08A01N2300/00
    • There are described herbicidal compositions which comprise at least one herbicidally active compound of the formula (I) and at least one crop-plant-protecting compound as safener. In this formula (I), V is an optionally substituted radical selected from the group consisting of isoxazol-4-yl, pyrazol-4-yl, cyclohexane-1,3-dion-2-yl and 3-oxopropionitril-2-yl and R9 is nitro, amino, halogen or a carbon-containing radical. The group of the safeners contains, for example, 2,4-D, cyometrinil, dicamba, dymron, fenclorim, flurazole, fluxofenim, lactidichlor, MCPA, mecoprop, MG-191, oxabetrinil, methyl diphenylmethoxyacetate, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea, 1,8-naphthalaic anhydride, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea, 1-[4-(N-4,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea, 1-[4-(N-naphthoylsulfamoyl)phenyl]-3,3-dimethylurea, (4-chlorophenoxy)acetic acid, 4-(2,4-dichlorophenoxy)butyric acid, 4-(4-chloro-o-tolyloxy)butyric acid, 4-(4-chlorophenoxy)butyric acid, in each case their acids and esters, N-acylsulfonamides, N-acylsulfamoylbenzamides, in each case, if appropriate, also in salt form and in each case optionally substituted 1-phenylpyrazoline, 1-phenylpyrazole, 1-phenyltriazole, 5-phenylisoxazoline and 5-phenylmethylisoxazoline-3-carboxylic esters and 2-(8-quinolinyloxy)acetic acid derivatives.
    • 描述了除草组合物,其包含至少一种除草活性的式(I)化合物和至少一种作物保护化合物作为安全剂。 在该式(I)中,V是任选取代的基团,其选自异恶唑-4-基,吡唑-4-基,环己烷-1,3-二酮-2-基和3-氧代丙酰基-2-基 并且R 9为硝基,氨基,卤素或含碳基团。 安全剂组包含例如2,4-D,cyometrinil,麦草畏,dymron,fenclorim,氟尿嘧啶,氟吡芬,乳酸二氯,MCPA,mecoprop,MG-191,恶嗪胺,甲基二苯基甲氧基乙酸酯,1- [4-(N -2-甲氧基苯甲酰基氨磺酰基)苯基] -3-甲基脲,1,8-萘酸酐,1- [4-(N-2-甲氧基苯甲酰基氨磺酰基)苯基] -3,3-二甲基脲,1- [4-(N-4, 5-甲基苯甲酰基氨磺酰基)苯基] -3-甲基脲,1- [4-(N-萘酰基氨磺酰基)苯基] -3,3-二甲基脲,(4-氯苯氧基)乙酸,4-(2,4-二氯苯氧基) 4-(4-氯 - 邻甲苯氧基)丁酸,4-(4-氯苯氧基)丁酸,在各种情况下都是它们的酸和酯,N-酰基磺酰胺,N-酰基氨磺酰苯甲酰胺,如果合适,也适用于盐 形式,并且在每种情况下均为任选取代的1-苯基吡唑啉,1-苯基吡唑,1-苯基三唑,5-苯基异恶唑啉和5-苯基甲基异恶唑啉-3-羧酸酯和2-(8-喹啉基氧基)乙酸衍生物。