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    • 1. 发明授权
    • (Poly)alkylene glycol higher alkyl ether derivative composition and detergent, lubricant, and dermatologic medicine for external use containing the composition
    • (聚)亚烷基二醇高级烷基醚衍生物组合物和洗涤剂,润滑剂和皮肤外用药物,含有组合物
    • US06278007B1
    • 2001-08-21
    • US09309011
    • 1999-05-10
    • Toru InaokaKenji RakutaniYukio KadonoYoshiyuki Onda
    • Toru InaokaKenji RakutaniYukio KadonoYoshiyuki Onda
    • C07B3508
    • C10M105/18C07C43/11C07C69/003C07C69/24C08G65/2615C08G65/3312C10M105/40C10M107/34C10M2207/04C10M2207/289C10M2209/104C10M2209/105C10M2209/106C10M2209/109C11D1/72C11D1/721C11D1/74
    • A (poly)alkylene glycol higher alkyl ether derivative composition characterized by comprising 30-90 mol. % of (B1) (poly)alkylene glycol higher alkyl ether derivative and 70-10 mol. % of (B2) (poly)alkylene glycol higher alkyl ether derivative, respectively having a methyl group for R1 and an alkyl group of not less than two carbon atoms for R1 in the general formula (1) representing the derivatives: (wherein R1 and R2 represent alkyl groups whose total number of carbon atoms is in the range of 7-29, the number of carbon atoms of R2 is larger than the number of carbon atoms of R1, A represents a lower alkylene group, n represents a real number in the range of 1-300 on average, x represents 0 or 1, y represents a real number in the range of 1-10 on average, and R3 represents an optionally substituted organic residue of 1-60 carbon atoms [excluding the carbon atoms of the substituent]) and a deterging agent, a lubricating agent, or a dermatological medicine for external use containing the (poly)alkylene glycol higher alkyl ether derivative composition. The composition possesses such characteristic features as containing no oil-soluble component of low molecular weight, emitting odor sparingly, exhibiting a low stimulating property, having no foaming property, abounding in penetrating force, allowing thorough separation of the foam from a deterged article, and enjoying such low viscosity as to allow great ease of handling.
    • (聚)亚烷基二醇高级烷基醚衍生物组合物,其特征在于包含30-90mol。 (B1)(聚)亚烷基二醇高级烷基醚衍生物的百分比和70-10摩尔。 %的(B2)(聚)亚烷基二醇高级烷基醚衍生物,在通式(1)中分别具有R1的甲基和不少于2个碳原子的烷基,其中R1和 R2表示碳原子数为7〜29的烷基,R2的碳原子数大于R1的碳原子数,A表示低级亚烷基,n表示实数 平均1-300的范围,x表示0或1,y表示平均1-10个范围内的实数,R3表示1-60个碳原子的任选取代的有机残基[不包括 取代基])和含有(聚)亚烷基二醇高级烷基醚衍生物组合物的洗涤剂,润滑剂或外用皮肤病学药剂。 该组合物具有如下特征:不含低分子量油溶性成分,少量发臭,表现出低刺激性,无起泡性,渗透力大,允许泡沫与洗涤物品彻底分离, 享受这样的低粘度以使得易于处理。
    • 4. 发明授权
    • Production processes for alkylene oxide addition product and its derivatives
    • 烯化氧加成产物及其衍生物的生产方法
    • US07402644B2
    • 2008-07-22
    • US10500554
    • 2003-05-02
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • C08F20/26C07C69/52C07C43/00
    • C08G65/2609C08G65/2696C08G65/3322
    • The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
    • 本发明提供:一种环氧烷加成物的制造方法,通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物,同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。 本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于:使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤 含有饱和化合物,得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤,使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。
    • 6. 发明申请
    • Production processes for alkylene oxide addition product and its derivatives
    • 烯化氧加成产物及其衍生物的生产方法
    • US20050080298A1
    • 2005-04-14
    • US10500554
    • 2003-05-02
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • C08F299/02C08G65/26C08G65/28C08G65/332C07C67/26C08G59/14
    • C08G65/2609C08G65/2696C08G65/3322
    • The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
    • 本发明提供:一种环氧烷加成物的制造方法,通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物,同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。 本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于:使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤 含有饱和化合物,得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤,使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。