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    • 1. 发明申请
    • Production processes for alkylene oxide addition product and its derivatives
    • 烯化氧加成产物及其衍生物的生产方法
    • US20050080298A1
    • 2005-04-14
    • US10500554
    • 2003-05-02
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • C08F299/02C08G65/26C08G65/28C08G65/332C07C67/26C08G59/14
    • C08G65/2609C08G65/2696C08G65/3322
    • The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
    • 本发明提供:一种环氧烷加成物的制造方法,通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物,同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。 本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于:使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤 含有饱和化合物,得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤,使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。
    • 3. 发明授权
    • Production processes for alkylene oxide addition product and its derivatives
    • 烯化氧加成产物及其衍生物的生产方法
    • US07402644B2
    • 2008-07-22
    • US10500554
    • 2003-05-02
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • Toru InaokaYoshiyuki OndaHiromichi TanakaTsuyoshi Hirata
    • C08F20/26C07C69/52C07C43/00
    • C08G65/2609C08G65/2696C08G65/3322
    • The present invention provides: a production process for an alkylene oxide addition product, by which a high-molecular alkylene oxide addition product can be obtained with ordinary production facilities while the formation of by-products is suppressed; and production processes for derivatives from the alkylene oxide addition product. The present invention production process for an alkylene oxide addition product comprises the step of carrying out an addition reaction of an alkylene oxide to a hydroxyl-group-containing saturated compound in order to obtain the alkylene oxide addition product; with the production process being characterized by further comprising: the initial step of causing the alkylene oxide to add to the hydroxyl-group-containing saturated compound in an amount of not larger than 20 mols on average of the alkylene oxide per 1 mol of the hydroxyl-group-containing saturated compound to thereby obtain an alkylene oxide low-mol-addition product; and the molar-degree-of-polyaddition-adjusting step of causing the alkylene oxide to further add to the alkylene oxide low-mol-addition product as obtained in the initial step; wherein a portion of the entirety of the alkylene oxide low-mol-addition product as obtained in the initial step is used in the molar-degree-of-polyaddition-adjusting step.
    • 本发明提供:一种环氧烷加成物的制造方法,通过该方法可以获得具有普通生产设备的高分子量烯化氧加成产物,同时抑制副产物的形成; 以及来自烯化氧加成产物的衍生物的制备方法。 本发明的烯化氧加成产物的制备方法包括进行烯化氧与含羟基的饱和化合物的加成反应以获得环氧烷烃加成产物的步骤; 其制备方法的特征还在于:使每1摩尔羟基的烯化氧的平均相对于含有羟基的饱和化合物不少于20摩尔的环氧烷加成的初始步骤 含有饱和化合物,得到环氧烷低摩尔加成产物; 和加成摩尔加聚度调整步骤,使得氧化烯进一步添加到初始步骤中获得的环氧烷低摩尔加成产物; 其中在初始步骤中获得的全部烯化氧低摩尔加成产物的一部分用于加聚度加聚步骤。
    • 9. 发明授权
    • Cement admixture and cement composition
    • 水泥外加剂和水泥组成
    • US06911494B2
    • 2005-06-28
    • US10253425
    • 2002-09-25
    • Akihiko YamashitaHiromichi TanakaTsuyoshi HirataToru UnoYoshiyuki Onda
    • Akihiko YamashitaHiromichi TanakaTsuyoshi HirataToru UnoYoshiyuki Onda
    • C04B24/26C04B24/32C08G65/26C08G65/332C08L71/02C08L31/02
    • C04B24/2647C04B2103/308C04B2103/32C08G65/2609C08G65/3322C08L71/02C08L2205/05C08L2666/04
    • It is an object of the present invention to provide a cement admixture which can show not only a high dispersing ability and a slump loss preventing effect but also a viscosity reducing effect and can show these characteristics even in the high water reduction ratio range, and a cement composition in which this admixture is used.A cement admixture comprising, as three essential constituents, a copolymer (A), an unsaturated (poly)alkylene glycol ether monomer (a) and an unpolymerizable (poly)alkylene glycol (B) not containing an alkenyl group, wherein the content of the unsaturated (poly)alkylene glycol ether monomer (a) is 1 to 100% by mass relative to the copolymer (A) and the content of the unpolymerizable (poly)alkylene glycol (B) not containing an alkenyl group is 1 to 50% by mass relative to the copolymer (A), the copolymer (A) comprising, as essential constituent units, a constituent unit (I) derived from the unsaturated (poly)alkylene glycol ether monomer (a) and a constituent unit (II) derived from an unsaturated carboxylic acid monomer (b), with the constituent unit (I) and constituent unit (II) each accounting for not less than 1% by mass based on all the constituent units, and the unsaturated carboxylic acid monomer (b) being an unsaturated monocarboxylic acid monomer.
    • 本发明的目的是提供一种能够显示出高的分散能力和防止坍落度损失的作用的水泥混合物,而且还能够降低粘度,并且即使在高的减水率范围内也能够显示出这些特性, 使用该混合物的水泥组合物。 一种水泥外加剂,其包含不含烯基的共聚物(A),不饱和(聚)亚烷基二醇醚单体(a)和不可聚合(聚)亚烷基二醇(B)作为三种必需成分,其中, 不饱和(聚)亚烷基二醇醚单体(a)相对于共聚物(A)为1〜100质量%,不含烯基的不可聚合(聚)亚烷基二醇(B)的含量为1〜50% 相对于共聚物(A)的共聚物(A),作为必要构成单元的共聚物(A),由不饱和(聚)亚烷基二醇醚单体(a)得到的构成单元(I)和由 不饱和羧酸单体(b)与构成单元(I)和构成单元(II)各自占所有构成单元不少于1质量%,不饱和羧酸单体(b)为 不饱和一元羧酸单体。