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1. 发明授权

US5560870A Composition for forming an electrically conductive layer to be used in patterning 失效
标题翻译：用于形成用于图案化的导电层的组合物
公开(公告)号：US5560870A
公开(公告)日：1996-10-01
申请号：US445730
申请日：1995-05-22
申请人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
发明人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
IPC分类号： G03F7/004 , C08G73/02 , G03F7/11 , G03F7/26 , H01B1/12 , H01L21/265 , H05K3/10 , H01B1/00 , H01B1/18
CPC分类号： C08G73/0266 , H01B1/128 , H05K3/105 , Y10S430/143 , Y10S438/95
摘要： A composition for forming an electrically conductive layer which is used in patterning of a resist with electric charge beam, which comprises:(a) 0.1 to 20 parts by weight of sulfonated polyanilines with a sulfonic group content ranging from 20 to 80% based on the aromatic ring, the sulfonated polyaniline having a weight average molecular weight of 500 to 100,000 and a molecular weight dispersion of not more than 5,(b) 100 parts by weight of a solvent, and(c) 0.01 to 30 parts by weight of amines and/or quaternary ammonium salts,and if desired, it further comprises 0 to 200 parts by weight of the following substance(s) (A) and/or (B) as component (d):(A) a high molecular weight compound soluble in the aforesaid solvent (b),(B) a surface active agent.
摘要翻译：一种用于形成导电层的组合物，其用于使用电荷束的抗蚀剂图案化，其包括：（a）基于所述组合物的0.1〜20重量份的磺酸基含量为20〜80％的磺化聚苯胺芳族环，重均分子量为500〜100,000，分子量分布不大于5的磺化聚苯胺，（b）100重量份溶剂，（c）0.01〜30重量份的胺和/或季铵盐，如果需要，其还包含0至200重量份的作为组分（d）的下列物质（A）和/或（B））：（A）高分子量化合物溶于上述溶剂（b），（B）表面活性剂。

2. 发明授权

US5009811A Conducting varnish composition 失效
标题翻译：进行清漆组合
公开(公告)号：US5009811A
公开(公告)日：1991-04-23
申请号：US321284
申请日：1989-03-09
申请人： Tomio Nakamura , Shigeru Shimizu , Kikuko Takeuchi
发明人： Tomio Nakamura , Shigeru Shimizu , Kikuko Takeuchi
IPC分类号： C09D5/24 , H01B1/12
CPC分类号： C09D5/24 , H01B1/121
摘要： A conducting varnish composition consisting essentially of:(a) a tetracyanoquinodimethane complex salt;(b) a high molecular weight compound;(c)(i) at least one compound selected from the group consisting of acetals, orthoformic acid esters, orthoacetic acid esters, orthocarbonic acid esters, siloxanes, silyl ethers and orthosilicic acid esters; and/or(ii) a surfactant or a silicone oil; and(d) a solvent.the TCNQ complex salt is stable in a solution of the composition according to the present invention and the composition can be stored for a long period of time. Therefore, it provides a conducting material which exhibits a constant conductivity. Also, the composition of the present invention is excellent in the film-formability and moldability, and can be formed into a film or an article of good quality, that is, having no incomplete part.

3. 发明授权

US5776659A Ionizing radiation exposure method utilizing water soluble aniline antistatic polymer layer 失效
标题翻译：电离辐射曝光方法利用水溶性苯胺抗静电聚合物层
公开(公告)号：US5776659A
公开(公告)日：1998-07-07
申请号：US762877
申请日：1996-12-12
申请人： Keiji Watanabe , Ei Yano , Takahisa Namiki , Keiko Yano , Takashi Maruyama , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Masami Ishikawa
发明人： Keiji Watanabe , Ei Yano , Takahisa Namiki , Keiko Yano , Takashi Maruyama , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Masami Ishikawa
IPC分类号： G03F7/004 , C08G73/00 , C08G73/02 , C08L79/00 , C08L79/08 , C09D5/00 , C09D179/00 , C09D179/08 , G03F7/09 , G03F7/11 , G03F7/20 , G03F7/26 , H01L21/027 , H01L21/265 , H01L21/266 , H01L21/66 , G03F7/30
CPC分类号： C08G73/0266 , G03F7/093 , Y10S430/143
摘要： A composition for irradiation with an ionizing radiation, characterized by comprising: (a) 0.01 to 30 parts by weight of a soluble aniline polymer which comprises one or both of the repeating units represented by the following general formulae (1) and (2), said repeating units being included at least 80% of the total repeating units, possesses a weight average molecular weight of not less than 10,000, and is solid at room temperature; and (b) 100 parts by weight of a solvent, ##STR1## wherein R.sup.1 to R.sup.4 represent an electron-donating group, Y.sup.1 to Y.sup.4 represent --SO.sub.3 -- or --COO--, and M.sup.1 to M.sup.4 represent a hydrogen ion, an ammonium ion, an a1kyl ammonium ion with 1 to 8 carbon atoms, an aromatic ammonium ion, or a quaternary ion of an aromatic heterocyclic ring.
摘要翻译：一种用于照射电离辐射的组合物，其特征在于包括：（a）0.01至30重量份的可溶性苯胺聚合物，其包含由以下通式（1）和（2）表示的一个或两个重复单元，所述重复单元包括总重复单元的至少80％，重均分子量不小于10,000，在室温下为固体; （b）100重量份溶剂，其中R1至R4表示给电子基团，Y1至Y4表示-SO3-或-COO-，M1至 M4表示氢离子，铵离子，碳原子数1〜8的烷基铵离子，芳香族铵离子或芳香族杂环的四价离子。

4. 发明授权

US4370279A Process for production of acrylonitrile 失效
公开(公告)号：US4370279A
公开(公告)日：1983-01-25
申请号：US941351
申请日：1978-09-11
申请人： Yutaka Sasaki , Tomio Nakamura , Yoshimi Nakamura , Kiyoshi Moriya , Hiroshi Utsumi , Shigeru Saito
发明人： Yutaka Sasaki , Tomio Nakamura , Yoshimi Nakamura , Kiyoshi Moriya , Hiroshi Utsumi , Shigeru Saito
IPC分类号： C07B61/00 , B01J23/00 , B01J23/88 , B01J27/00 , B01J27/057 , C07C67/00 , C07C253/00 , C07C255/08 , C07C120/14
CPC分类号： B01J23/8873 , B01J23/8872 , B01J23/8876 , B01J23/8877 , B01J27/0576 , C07C253/26 , B01J2523/00 , Y02P20/52
摘要： A process for producing acrylonitrile by the vapor-phase catalytic ammoxidation of propylene, which comprises(I) reacting propylene, a molecular oxygen-containing gas and ammonia in the presence of a catalyst expressed by the following empirical formulaFe.sub.a Sb.sub.b Mo.sub.c Me.sub.d Te.sub.e Q.sub.f Na.sub.g O.sub.h. (SIO).sub.iwherein Me is at least one element selected from the group consisting of V and W,Q is at least one element selected from the group consisting of Cu, Mg, Zn and Ni, andthe subscripts a, b, c, d, e, f, g, h and i each represents atomic ratios such that when a=10; b=13 to 28; c=0.1 to 2.5; d=0.05 to 1; e=0.2 to 5; f=0 to 4 (in which case b=13 to 20), or f=2 to 6 (in which case b=20 to 28); g=0 to 3; h=the number of oxygens corresponding to the oxide formed by the combination of the components, and i=25 to 200;in a fluidized bed catalytic reaction zone at a temperature of about 380 to about 500.degree. C. and a pressure of about 0.2 to about 3 kg/cm.sup.2 -G while adjusting the propylene/oxygen/ammonia molar ratio to about 1:about 1:about 0.8 to about 1:about 4:about 3;(II) the catalyst being prepared by(1) intimately mixing starting materials for the Fe, Mo, Me, Te and Q components in a form soluble in water or nitric acid, a starting material for the Sb component, and silica sol which may or may not contain an Na component, thereby to form a slurry containing these components and having a non-volatile solids content of about 10 to about 50% by weight;(2) so that the composition of the final catalyst is within the range expressed by the empirical formula above;(3) spray-drying the resulting slurry, and(4) calcining the resulting spray-dried particles at a temperature of about 600 to about 950.degree. C. thereby to form a catalyst with a composition within the above empirical formula and with all of the Mo, Me, and Te components substantially dissolved in an iron/antimony oxide compound (FeSbO.sub.4) in the form of a solid solution.

5. 发明授权

US5354816A Sulfonated aniline-type copolymer and process for production thereof 失效
标题翻译：磺化苯胺型共聚物及其制备方法
公开(公告)号：US5354816A
公开(公告)日：1994-10-11
申请号：US996786
申请日：1992-12-24
申请人： Shigeru Shimizu , Takashi Saitoh , Tomio Nakamura
发明人： Shigeru Shimizu , Takashi Saitoh , Tomio Nakamura
IPC分类号： C08G73/00 , C08G73/02 , C09D179/00 , C09K3/16 , H01B1/12 , C08L81/00
CPC分类号： C08G73/0266 , C09K3/16 , H01B1/128
摘要： Sulfonated aniline-type copolymer and a process for their preparation are disclosed.These products comprise a water soluble and alcohol soluble copolymer of a compound (A) selected from the group of aniline, N-alkylaniline and phenylenediamine, and aminobenzene sulfonic acid (B); said sulfonated product being a following compound of a general formulae I to V stated in the specification, or a mixture thereof.Also, process for the sulfonated aniline-type copolymer comprises the steps:copolymerizing a compound (A) selected from the group of aniline, N-alkyl aniline and phenylene diamine, and aminobenzene sulfonic acid (B) to obtain a copolymer; andsulfonating the thus obtained copolymer with a sulfonating agent.
摘要翻译：公开了磺化苯胺型共聚物及其制备方法。这些产品包含选自苯胺，N-烷基苯胺和苯二胺的化合物（A）和氨基苯磺酸（B）的水溶性和醇溶性共聚物。所述磺化产物是说明书中所述的通式I至V的下列化合物或其混合物。另外，磺化苯胺型共聚物的工序是将选自苯胺，N-烷基苯胺，苯二胺和氨基苯磺酸（B）的化合物（A）共聚合得到共聚物的工序; 并用磺化剂将由此得到的共聚物磺化。

6. 发明授权

US5091285A Method of forming pattern by using an electroconductive composition 失效
标题翻译：使用电磁组合物形成图案的方法
公开(公告)号：US5091285A
公开(公告)日：1992-02-25
申请号：US515444
申请日：1990-04-27
申请人： Keiji Watanabe , Yasuhiro Yoneda , Koichi Kobayashi , Keiko Yano , Tomio Nakamura , Shigeru Shimizu
发明人： Keiji Watanabe , Yasuhiro Yoneda , Koichi Kobayashi , Keiko Yano , Tomio Nakamura , Shigeru Shimizu
IPC分类号： G03F7/004 , G03F7/027 , G03F7/20 , G03F7/26 , H01L21/027 , H01L21/66
CPC分类号： G03F7/0047 , Y10S430/143
摘要： A pattern-forming method using an electroconductive composition comprising at least one TCNQ complex salt selected from the group consisting of isoquinolinium-TCNQ complex salts, quinolinium-TCNQ complex salts, alkyl pyridinium-TCNQ complex salts, and morpholinium-TCNQ complex salts, a specific polymer, and a solvent are disclosed. This composition gives an electroconductive film having a superior long-term storage stability and electroconductive characteristics.When this electroconductive composition is coated on a resist to form an electroconductive film, and a pattern is formed by an irradiation with charging beams, such as electron beams, an accumulation of charges (charge-up) is prevented and a fine resist pattern in which a misregistration is completely prevented is obtained.

7. 发明授权

US4947313A Direct current power supply 失效
标题翻译：直流电源
公开(公告)号：US4947313A
公开(公告)日：1990-08-07
申请号：US453161
申请日：1989-12-19
申请人： Tomio Nakamura
发明人： Tomio Nakamura
IPC分类号： G05F1/56 , G05F1/563
CPC分类号： G05F1/563
摘要： An inventive series-regulator-type direct current power supply includes a power transformer of which a secondary winding has a plurality of output terminals, a plurality of corresponding rectifier systems connected to the output terminals, an input voltage-detecting circuit detecting a predetermined level of an input alternating current voltage, and a switching circuit opening and closing a line of the rectifying circuit systems. The inventive system selectively switches the output terminals of the secondary winding of the power supply transformer and switches the rectifying circuit, in response to a change in the amplitude of a primary input voltage in order to suppress a variation of a direct current output voltage.
摘要翻译：本发明的串联稳压器型直流电源包括一个电源变压器，其次级绕组具有多个输出端子，多个对应的整流器系统连接到输出端子，输入电压检测电路检测预定电平输入交流电压，以及切换电路，其对整流电路系统的一行进行开闭。本发明的系统响应于初级输入电压的振幅的变化而选择性地切换电源变压器的次级绕组的输出端并切换整流电路，以便抑制直流输出电压的变化。

8. 发明授权

US5804354A Composition for forming conductivity imparting agent and pattern forming method 失效
标题翻译：用于形成导电性赋予剂的组合物和图案形成方法
公开(公告)号：US5804354A
公开(公告)日：1998-09-08
申请号：US876794
申请日：1997-06-16
申请人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Takahisa Namiki , Ei Yano , Miwa Igarashi , Yoko Kuramitsu
发明人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Takahisa Namiki , Ei Yano , Miwa Igarashi , Yoko Kuramitsu
IPC分类号： C08G73/02 , H01B1/12 , G03C5/00
CPC分类号： H01B1/128 , C08G73/0266 , Y10S430/143
摘要： A composition for forming a conductivity imparting agent comprising: (a) 0.1 to 20 parts by weight of sulfonated polyaniline having a content of a sulfonic acid group of 20 to 80% with respect to an aromatic ring of the sulfonated polyaniline; (b) 100 parts by weight of a solvent; (c) 0.01 to 10 parts by weight of an amine and/or quaternary ammonium salt; and (d) 0.001 to 100 parts by weight of at least one kind of a sulfonic acid group-containing component selected from the following (A) and (B); (A) compounds having a sulfonic acid group; and (B) polymers having a sulfonic acid group.
摘要翻译：一种用于形成导电性赋予剂的组合物，其包含：（a）相对于所述磺化聚苯胺的芳环，为0.1〜20重量份磺酸基含量为20〜80％的磺化聚苯胺; （b）100重量份溶剂; （c）0.01至10重量份的胺和/或季铵盐; 和（d）0.001至100重量份选自以下（A）和（B）的至少一种含磺酸基的组分; （A）具有磺酸基的化合物; 和（B）具有磺酸基的聚合物。

9. 发明授权

US5220065A Method for producing n-methylolacrylamide 失效
标题翻译：生产N-甲基丙烯酰胺的方法
公开(公告)号：US5220065A
公开(公告)日：1993-06-15
申请号：US865270
申请日：1992-04-08
申请人： Yasuyuki Takayanagi , Kiyobmi Takahashi , Tomio Nakamura
发明人： Yasuyuki Takayanagi , Kiyobmi Takahashi , Tomio Nakamura
IPC分类号： C07C231/08 , C07C233/20
CPC分类号： C07C231/08 , C07C233/20
摘要： A method for producing N-methylolacrylamide which comprises reacting acrylamide with formaldehyde or paraformaldehyde in an aqueous solvent in the presence of (A) a basic compound and at least one member selected from the group consisting of a salt of Mo-containing acid and a salt of W-containing acid, or (B) a quaternary ammonium hydroxide compound, is provided by the present invention. According to the method of the present invention, N-methylolacrylamide having few by-products is obtained in high yields.

10. 发明授权

US4797184A Process for producing 7,7,8,8-tetracyanoquinodimethane 失效
标题翻译：制备7,7,8,8-四氰基醌二甲烷的方法
公开(公告)号：US4797184A
公开(公告)日：1989-01-10
申请号：US140562
申请日：1988-01-04
申请人： Tomio Nakamura , Katsuaki Kikuchi , Takeshi Inagaki
发明人： Tomio Nakamura , Katsuaki Kikuchi , Takeshi Inagaki
IPC分类号： C07C255/31 , C25B3/02 , H01B1/12
CPC分类号： C25B3/02
摘要： There is disclosed a process for producing 7,7,8,8-tetracyanoquinodimethane, which comprises subjecting 1,4-bis-(dicyanomethylene)-cyclohexane to anodic oxidation in a solvent.

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