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1. 发明授权

US5560870A Composition for forming an electrically conductive layer to be used in patterning 失效
标题翻译：用于形成用于图案化的导电层的组合物
公开(公告)号：US5560870A
公开(公告)日：1996-10-01
申请号：US445730
申请日：1995-05-22
申请人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
发明人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
IPC分类号： G03F7/004 , C08G73/02 , G03F7/11 , G03F7/26 , H01B1/12 , H01L21/265 , H05K3/10 , H01B1/00 , H01B1/18
CPC分类号： C08G73/0266 , H01B1/128 , H05K3/105 , Y10S430/143 , Y10S438/95
摘要： A composition for forming an electrically conductive layer which is used in patterning of a resist with electric charge beam, which comprises:(a) 0.1 to 20 parts by weight of sulfonated polyanilines with a sulfonic group content ranging from 20 to 80% based on the aromatic ring, the sulfonated polyaniline having a weight average molecular weight of 500 to 100,000 and a molecular weight dispersion of not more than 5,(b) 100 parts by weight of a solvent, and(c) 0.01 to 30 parts by weight of amines and/or quaternary ammonium salts,and if desired, it further comprises 0 to 200 parts by weight of the following substance(s) (A) and/or (B) as component (d):(A) a high molecular weight compound soluble in the aforesaid solvent (b),(B) a surface active agent.
摘要翻译：一种用于形成导电层的组合物，其用于使用电荷束的抗蚀剂图案化，其包括：（a）基于所述组合物的0.1〜20重量份的磺酸基含量为20〜80％的磺化聚苯胺芳族环，重均分子量为500〜100,000，分子量分布不大于5的磺化聚苯胺，（b）100重量份溶剂，（c）0.01〜30重量份的胺和/或季铵盐，如果需要，其还包含0至200重量份的作为组分（d）的下列物质（A）和/或（B））：（A）高分子量化合物溶于上述溶剂（b），（B）表面活性剂。

2. 发明授权

US5354816A Sulfonated aniline-type copolymer and process for production thereof 失效
标题翻译：磺化苯胺型共聚物及其制备方法
公开(公告)号：US5354816A
公开(公告)日：1994-10-11
申请号：US996786
申请日：1992-12-24
申请人： Shigeru Shimizu , Takashi Saitoh , Tomio Nakamura
发明人： Shigeru Shimizu , Takashi Saitoh , Tomio Nakamura
IPC分类号： C08G73/00 , C08G73/02 , C09D179/00 , C09K3/16 , H01B1/12 , C08L81/00
CPC分类号： C08G73/0266 , C09K3/16 , H01B1/128
摘要： Sulfonated aniline-type copolymer and a process for their preparation are disclosed.These products comprise a water soluble and alcohol soluble copolymer of a compound (A) selected from the group of aniline, N-alkylaniline and phenylenediamine, and aminobenzene sulfonic acid (B); said sulfonated product being a following compound of a general formulae I to V stated in the specification, or a mixture thereof.Also, process for the sulfonated aniline-type copolymer comprises the steps:copolymerizing a compound (A) selected from the group of aniline, N-alkyl aniline and phenylene diamine, and aminobenzene sulfonic acid (B) to obtain a copolymer; andsulfonating the thus obtained copolymer with a sulfonating agent.
摘要翻译：公开了磺化苯胺型共聚物及其制备方法。这些产品包含选自苯胺，N-烷基苯胺和苯二胺的化合物（A）和氨基苯磺酸（B）的水溶性和醇溶性共聚物。所述磺化产物是说明书中所述的通式I至V的下列化合物或其混合物。另外，磺化苯胺型共聚物的工序是将选自苯胺，N-烷基苯胺，苯二胺和氨基苯磺酸（B）的化合物（A）共聚合得到共聚物的工序; 并用磺化剂将由此得到的共聚物磺化。

3. 发明授权

US5721091A Composition for forming an electrically conductive layer to be used in patterning 失效
公开(公告)号：US5721091A
公开(公告)日：1998-02-24
申请号：US468829
申请日：1995-06-06
申请人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
发明人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh
IPC分类号： G03F7/004 , C08G73/02 , G03F7/11 , G03F7/26 , H01B1/12 , H01L21/265 , H05K3/10 , G03C5/00 , B44C1/22
CPC分类号： C08G73/0266 , H01B1/128 , H05K3/105 , Y10S430/143 , Y10S438/95
摘要： A composition for forming an electrically conductive layer which is used in patterning of a resist with electric charge beam, which comprises: (a) 0.1 to 20 parts by weight of sulfonated polyanilines with a sulfonic group content ranging from 20 to 80% based on the aromatic ring, the sulfonated polyaniline having a weight average molecular weight of 500 to 100,000 and a molecular weight dispersion of not more than 5, (b) 100 parts by weight of a solvent, and (c) 0.01 to 30 parts by weight of amines and/or quaternary ammonium salts, and if desired, it further comprises 0 to 200 parts by weight of the following substance(s) (A) and/or (B) as component (d): (A) a high molecular weight compound soluble in the aforesaid solvent (b), (B) a surface active agent.

4. 发明授权

US5776659A Ionizing radiation exposure method utilizing water soluble aniline antistatic polymer layer 失效
标题翻译：电离辐射曝光方法利用水溶性苯胺抗静电聚合物层
公开(公告)号：US5776659A
公开(公告)日：1998-07-07
申请号：US762877
申请日：1996-12-12
申请人： Keiji Watanabe , Ei Yano , Takahisa Namiki , Keiko Yano , Takashi Maruyama , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Masami Ishikawa
发明人： Keiji Watanabe , Ei Yano , Takahisa Namiki , Keiko Yano , Takashi Maruyama , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Masami Ishikawa
IPC分类号： G03F7/004 , C08G73/00 , C08G73/02 , C08L79/00 , C08L79/08 , C09D5/00 , C09D179/00 , C09D179/08 , G03F7/09 , G03F7/11 , G03F7/20 , G03F7/26 , H01L21/027 , H01L21/265 , H01L21/266 , H01L21/66 , G03F7/30
CPC分类号： C08G73/0266 , G03F7/093 , Y10S430/143
摘要： A composition for irradiation with an ionizing radiation, characterized by comprising: (a) 0.01 to 30 parts by weight of a soluble aniline polymer which comprises one or both of the repeating units represented by the following general formulae (1) and (2), said repeating units being included at least 80% of the total repeating units, possesses a weight average molecular weight of not less than 10,000, and is solid at room temperature; and (b) 100 parts by weight of a solvent, ##STR1## wherein R.sup.1 to R.sup.4 represent an electron-donating group, Y.sup.1 to Y.sup.4 represent --SO.sub.3 -- or --COO--, and M.sup.1 to M.sup.4 represent a hydrogen ion, an ammonium ion, an a1kyl ammonium ion with 1 to 8 carbon atoms, an aromatic ammonium ion, or a quaternary ion of an aromatic heterocyclic ring.
摘要翻译：一种用于照射电离辐射的组合物，其特征在于包括：（a）0.01至30重量份的可溶性苯胺聚合物，其包含由以下通式（1）和（2）表示的一个或两个重复单元，所述重复单元包括总重复单元的至少80％，重均分子量不小于10,000，在室温下为固体; （b）100重量份溶剂，其中R1至R4表示给电子基团，Y1至Y4表示-SO3-或-COO-，M1至 M4表示氢离子，铵离子，碳原子数1〜8的烷基铵离子，芳香族铵离子或芳香族杂环的四价离子。

5. 发明授权

US5804354A Composition for forming conductivity imparting agent and pattern forming method 失效
标题翻译：用于形成导电性赋予剂的组合物和图案形成方法
公开(公告)号：US5804354A
公开(公告)日：1998-09-08
申请号：US876794
申请日：1997-06-16
申请人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Takahisa Namiki , Ei Yano , Miwa Igarashi , Yoko Kuramitsu
发明人： Keiji Watanabe , Yasuhiro Yoneda , Takashi Maruyama , Keiko Yano , Tomio Nakamura , Shigeru Shimizu , Takashi Saitoh , Takahisa Namiki , Ei Yano , Miwa Igarashi , Yoko Kuramitsu
IPC分类号： C08G73/02 , H01B1/12 , G03C5/00
CPC分类号： H01B1/128 , C08G73/0266 , Y10S430/143
摘要： A composition for forming a conductivity imparting agent comprising: (a) 0.1 to 20 parts by weight of sulfonated polyaniline having a content of a sulfonic acid group of 20 to 80% with respect to an aromatic ring of the sulfonated polyaniline; (b) 100 parts by weight of a solvent; (c) 0.01 to 10 parts by weight of an amine and/or quaternary ammonium salt; and (d) 0.001 to 100 parts by weight of at least one kind of a sulfonic acid group-containing component selected from the following (A) and (B); (A) compounds having a sulfonic acid group; and (B) polymers having a sulfonic acid group.
摘要翻译：一种用于形成导电性赋予剂的组合物，其包含：（a）相对于所述磺化聚苯胺的芳环，为0.1〜20重量份磺酸基含量为20〜80％的磺化聚苯胺; （b）100重量份溶剂; （c）0.01至10重量份的胺和/或季铵盐; 和（d）0.001至100重量份选自以下（A）和（B）的至少一种含磺酸基的组分; （A）具有磺酸基的化合物; 和（B）具有磺酸基的聚合物。

6. 发明授权

US5932144A Soluble aniline conducting polymers 失效
标题翻译：可溶性苯胺导电聚合物
公开(公告)号：US5932144A
公开(公告)日：1999-08-03
申请号：US916333
申请日：1997-08-22
申请人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
发明人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
IPC分类号： C08G73/02 , H01B1/12 , C08G65/38
CPC分类号： H01B1/128 , C08G73/0266 , Y10T428/2933
摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.
摘要翻译：一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）：在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。

7. 发明授权

US5589108A Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers 失效
标题翻译：可溶性烷氧基取代氨基苯磺酸苯胺导电聚合物
公开(公告)号：US5589108A
公开(公告)日：1996-12-31
申请号：US361577
申请日：1994-12-22
申请人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
发明人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
IPC分类号： C08G73/02 , H01B1/12 , H01B1/00
CPC分类号： H01B1/128 , C08G73/0266 , Y10T428/2933
摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.
摘要翻译：一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）：在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。

8. 发明授权

US6024895A Cross-linkable, electrically conductive composition, electric conductor and process for forming the same 失效
标题翻译：可交联导电组合物，电导体及其形成方法
公开(公告)号：US6024895A
公开(公告)日：2000-02-15
申请号：US950791
申请日：1997-10-15
申请人： Shigeru Shimizu , Masashi Uzawa , Takashi Saitoh , Masami Yuasa , Yasuyuki Takayanagi , Naoki Sugama
发明人： Shigeru Shimizu , Masashi Uzawa , Takashi Saitoh , Masami Yuasa , Yasuyuki Takayanagi , Naoki Sugama
IPC分类号： C08G61/02 , C08G61/12 , C08L75/04 , C08L79/00 , C08L79/02 , C08L79/04 , C08L81/00 , C08L101/00 , C08L101/06 , C09D5/08 , C09D5/24 , C09D133/06 , H01B1/12 , H01B1/20
CPC分类号： H01B1/128 , C08G61/02 , C08G61/124 , C08G61/126 , C08L101/00 , C08L101/06 , C08L75/04 , C08L79/02 , C08L79/04 , C09D133/06 , C09D5/08 , C09D5/24 , H01B1/127 , C08L2201/04 , C08L79/00 , C08L81/00
摘要： A cross-linkable, electrically conductive composition comprising (a) a soluble, electrically conducting polymer having a sulfonic acid group and/or a carboxyl group and (b) a thermally cross-linkable or ultraviolet- or electron beam-cross-linkable resin or paint.
摘要翻译：一种可交联的导电组合物，其包含（a）具有磺酸基和/或羧基的可溶性导电聚合物和（b）可热交联或紫外或电子束可交联树脂或涂料。

9. 发明授权

US5980784A Method for producing soluble conductive polymer having acidic group 失效
标题翻译：制备具有酸性基团的可溶性导电聚合物的方法
公开(公告)号：US5980784A
公开(公告)日：1999-11-09
申请号：US941742
申请日：1997-10-01
申请人： Shigeru Shimizu , Masashi Uzawa , Takashi Saitoh , Shinichi Maeda
发明人： Shigeru Shimizu , Masashi Uzawa , Takashi Saitoh , Shinichi Maeda
IPC分类号： C08G61/12 , C08G73/02 , C08G75/06 , H01B1/12
CPC分类号： C08G61/122 , H01B1/127 , H01B1/128
摘要： A method for producing a soluble conductive polymer having acidic groups, which comprises subjecting to electrolytic polymerization (a) at least one compound selected from the group consisting of acidic group-substituted anilines, acidic group-substituted pyrroles, acidic group-substituted thiophenes, acidic group-substituted furans, acidic group-substituted selenophenes, acidic group-substituted tellurophenes, acidic group-substituted isothianaphthenes, acidic group-substituted isobenzofurans, acidic group-substituted isoindolines, acidic group-substituted isobenzoselenophenes, acidic group-substituted isobenzotellurophenes, and their metal salts, ammonium salts and substituted ammonium salts in a solution containing (b) a basic compound.
摘要翻译：一种制备具有酸性基团的可溶性导电聚合物的方法，包括进行电解聚合（a）至少一种选自酸性基团取代的苯胺，酸性取代的吡咯，酸性取代的噻吩，酸性的取代的噻吩，酸取代的异硫酚，酸性取代的异苯并呋喃，酸性取代的异吲哚啉，酸性取代的异苯并硒吩，酸性取代的异苯并间苯基四氟酚，及其金属盐，铵盐和取代的铵盐在含有（b）碱性化合物的溶液中。

10. 发明授权

US5700399A Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers 失效
标题翻译：可溶性烷氧基取代氨基苯磺酸苯胺导电聚合物
公开(公告)号：US5700399A
公开(公告)日：1997-12-23
申请号：US700994
申请日：1996-08-21
申请人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
发明人： Shigeru Shimizu , Takashi Saitoh , Masashi Uzawa , Yasuyuki Takayanagi
IPC分类号： C08G73/02 , H01B1/12 , H01B1/00 , B05D5/12 , D02G3/00
CPC分类号： H01B1/128 , C08G73/0266 , Y10T428/2933
摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.
摘要翻译：一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）：在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。

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