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    • 5. 发明授权
    • Oxide etch process using hexafluorobutadiene and related unsaturated hydrofluorocarbons
    • 使用六氟丁二烯和相关不饱和氢氟烃的氧化物蚀刻工艺
    • US06174451B1
    • 2001-01-16
    • US09193056
    • 1998-11-16
    • Raymond HungJoseph P. CaulfieldHongching ShanRuiping WangGerald Z. Yin
    • Raymond HungJoseph P. CaulfieldHongching ShanRuiping WangGerald Z. Yin
    • H01L2131
    • H01L21/31116
    • An oxide etching process, particular useful for selectively etching oxide over a feature having a non-oxide composition, such as silicon nitride and especially when that feature has a corner that is prone to faceting during the oxide etch. The invention uses one of three unsaturated 3- and 4-carbon fluorocarbons, specifically hexafluorobutadiene (C4F6), pentafluoropropylene (C3HF5), and trifluoropropyne (C3HF3), all of which have boiling points below 10° C. and are commercially available. The unsaturated hydrofluorocarbon together with argon is excited into a high-density plasma in a reactor which inductively couples plasma source power into the chamber and RF biases the pedestal electrode supporting the wafer. Preferably, a two-step etch is used process is used in which the above etching gas is used in the main step to provide a good vertical profile and a more strongly polymerizing fluorocarbon such as difluoromethane (CH2F2) is added in the over etch to protect the nitride corner.
    • 一种氧化物蚀刻工艺,特别用于在具有非氧化物组成的特征(例如氮化硅)上选择性地蚀刻氧化物,特别是当该特征具有在氧化物蚀刻期间易于刻面的拐角时。 本发明使用沸点低于10℃的三种不饱和3-和4-碳碳氟化合物,特别是六氟丁二烯(C 4 F 6),五氟丙烯(C 3 HF 5)和三氟丙炔(C 3 H 3 F 3)中的一种,并且可商购。 将不饱和氢氟烃与氩一起激发成反应器中的高密度等离子体,其将等离子体源功率感应耦合到室中,并且RF偏置支撑晶片的基座电极。 优选地,使用两步蚀刻方法,其中在主要步骤中使用上述蚀刻气体以提供良好的垂直分布,并且在过蚀刻中加入更强的聚合碳氟化合物如二氟甲烷(CH 2 F 2)以保护 氮化物角。
    • 6. 发明授权
    • Highly selective oxide etch process using hexafluorobutadiene
    • 使用六氟丁二烯的高选择性氧化物蚀刻工艺
    • US06613691B1
    • 2003-09-02
    • US09675360
    • 2000-09-29
    • Raymond HungJoseph P. CaulfieldHongching ShanRuiping WangGerald Z. Yin
    • Raymond HungJoseph P. CaulfieldHongching ShanRuiping WangGerald Z. Yin
    • H01L21475
    • H01L21/31116
    • An oxide etching process, particular useful for selectively etching oxide over a feature having a non-oxide composition, such as silicon nitride and especially when that feature has a corner that is prone to faceting during the oxide etch. The invention preferably uses the unsaturated 4-carbon fluorocarbons, specifically hexafluorobutadiene (C4F6), which has a below 10°C. and is commercially available. The hexafluorobutadiene together with argon is excited into a high-density plasma in a reactor which inductively couples plasma source power into the chamber and RF biases the pedestal electrode supporting the wafer. Preferably, a two-step etch is used process is used in which the above etching gas is used in the main step to provide a good vertical profile and a more strongly polymerizing fluorocarbon such as difluoromethane (CH2F2) is added in the over etch to protect the nitride corner.
    • 一种氧化物蚀刻工艺,特别用于在具有非氧化物组成的特征(例如氮化硅)上选择性地蚀刻氧化物,特别是当该特征具有在氧化物蚀刻期间易于刻面的拐角时。 本发明优选使用低于10℃的不饱和4-碳碳氟化合物,特别是六氟丁二烯(C 4 F 6)。 并且是可商购的。 将六氟丁二烯与氩一起激发成反应器中的高密度等离子体,其将等离子体源功率感应耦合到室中,并且RF偏置支撑晶片的基座电极。 优选地,使用两步蚀刻方法,其中在主要步骤中使用上述蚀刻气体以提供良好的垂直分布,并且在过蚀刻中加入更强的聚合碳氟化合物如二氟甲烷(CH 2 F 2)以保护 氮化物角。