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    • 7. 发明申请
    • SEMICONDUCTOR MEMORY DEVICE WITH VARIABLE RESISTANCE ELEMENT
    • 具有可变电阻元件的半导体存储器件
    • US20090102598A1
    • 2009-04-23
    • US11995876
    • 2006-07-05
    • Shinobu YamazakiTakuya Otabe
    • Shinobu YamazakiTakuya Otabe
    • H01C7/10
    • H01L45/04H01L27/2436H01L45/12H01L45/1233H01L45/146H01L45/147H01L45/1625H01L45/1675
    • A semiconductor memory device comprising a variable resistance element having a variable resistor between a first electrode and a second electrode, in which electric resistance is changed by applying a voltage pulse between the electrodes comprises at least one reaction preventing film made of a material having an action of blocking the permeation of a reduction species promoting a reduction reaction of the variable resistor and an oxidation species promoting an oxidation reaction of the variable resistor. This prevents the resistance value of the variable resistance element from fluctuating due to a reduction reaction or an oxidation reaction of the variable resistor caused by hydrogen or oxygen existing in the manufacturing steps, so that a semiconductor memory device having a small variation of the resistance value and having a good controllability can be realized with good repeatability.
    • 一种半导体存储器件,包括具有在第一电极和第二电极之间的可变电阻器的可变电阻元件,其中通过在电极之间施加电压脉冲来改变电阻,包括至少一个由具有动作的材料制成的防反射膜 阻止促进可变电阻的还原反应的还原物质的渗透和促进可变电阻器的氧化反应的氧化物质。 这样可以防止可变电阻元件的电阻值由于在制造步骤中存在的氢或氧气引起的可变电阻的还原反应或氧化反应而波动,使得电阻值变化小的半导体存储器件 并且可以以良好的重复性实现良好的可控性。
    • 8. 发明授权
    • Method for fabricating semiconductor memory having good electrical characteristics and high reliability
    • 具有良好的电气特性和高可靠性的半导体存储器的制造方法
    • US06225185B1
    • 2001-05-01
    • US09427941
    • 1999-10-27
    • Shinobu YamazakiKazuya Ishihara
    • Shinobu YamazakiKazuya Ishihara
    • H01L2120
    • H01L28/55
    • After forming a capacitor of a stack type ferroelectric memory device by sequentially patterning an upper electrode, a ferroelectric film and a lower electrode formed above an interlayer insulator film, the capacitor is covered with an oxidation barrier layer. After forming the oxidation barrier layer, the in-process memory device is heat treated at a high temperature in an oxygen-containing atmosphere. The oxidation barrier layer prevents the lower electrode of the capacitor and a barrier metal film between the capacitor and the interlayer insulator film from oxidation during heat treatment. Thus, the occurrence of peelings and hillocks in the lower electrode and the barrier metal film is avoided so that a semiconductor memory has good electrical characteristics and high reliability.
    • 在层叠型铁电体存储器件的电容器形成之后,通过顺序构图上层电极,铁电体膜和形成在层间绝缘膜上方的下电极,电容器被氧化阻挡层覆盖。 在形成氧化阻挡层之后,在含氧气氛中在高温下热处理过程中的记忆装置。 氧化阻挡层防止电容器的下电极和电容器与层间绝缘膜之间的阻挡金属膜在热处理期间氧化。 因此,避免了在下电极和阻挡金属膜中产生剥离和小丘,使得半导体存储器具有良好的电特性和高可靠性。
    • 9. 发明授权
    • Semiconductor memory device
    • 半导体存储器件
    • US08514607B2
    • 2013-08-20
    • US13212457
    • 2011-08-18
    • Mitsuru NakuraKazuya IshiharaShinobu YamazakiSuguru Kawabata
    • Mitsuru NakuraKazuya IshiharaShinobu YamazakiSuguru Kawabata
    • G11C11/00
    • G11C13/0007G11C13/0064G11C13/0069G11C2213/32G11C2213/79
    • Provided is a semiconductor memory device that is capable of stably programming with desirable controllability to a desired electric resistance state in a random access programming action and is provided with a variable resistance element. Regardless of a resistance state of a variable resistance element of a memory cell that is a target of a writing action (erasing and programming actions), an erasing voltage pulse for bringing the resistance state of the variable resistance element to an erased state having a lowest resistance value is applied. Thereafter, a programming voltage pulse for bringing the resistance state of the variable resistance element to a desired programmed state is applied to the variable resistance element of the programming action target memory cell. By always applying the programming voltage pulse after having applied the erasing voltage pulse, a plurality of programming voltage pulses being sequentially applied can be avoided.
    • 提供一种半导体存储器件,其能够在随机存取编程动作中以期望的可控制性稳定地编程到期望的电阻状态,并且具有可变电阻元件。 无论作为写入动作(擦除和编程动作)的目标的存储单元的可变电阻元件的电阻状态,将可变电阻元件的电阻状态变为最低的擦除状态的擦除电压脉冲 电阻值被应用。 此后,将用于使可变电阻元件的电阻状态变为期望编程状态的编程电压脉冲被施加到编程动作目标存储单元的可变电阻元件。 通过在施加擦除电压脉冲之后始终应用编程电压脉冲,可以避免顺序施加的多个编程电压脉冲。