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1. 发明授权

US5486607A Dioxazine blue dye compound having vinylsulfone type fiber reactive groups 失效
标题翻译：具有乙烯基砜型纤维反应性基团的二恶嗪蓝染料化合物
公开(公告)号：US5486607A
公开(公告)日：1996-01-23
申请号：US379028
申请日：1995-01-27
申请人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
发明人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Naoki Harada , Yutaka Kayane , Takashi Omura
IPC分类号： C07D498/04 , C09B62/503 , D06P1/38
CPC分类号： C09B62/5033
摘要： A dioxazine compound represented by the following formula in the free acid form, ##STR1## wherein V is a direct linkage or ##STR2## in which R.sub.3 is hydrogen or alkyl, X is a direct linkage or an aliphatic, araliphatic or aromatic bridging group, Y is phenylene or naphthylene, Z is a so-called vinylsulfone type fiber reactive group, and R.sub.1 and R.sub.2 are each hydrogen or alkyl, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a blue color superior in fastness properties with superior build-up property.
摘要翻译：由游离酸形式的下式表示的二恶嗪化合物，其中V是直接键合或其中R 3是氢或烷基，X是直链或者脂族，芳脂族或芳族桥连基团，Y为亚苯基或亚萘基，Z为所谓的乙烯基砜型纤维反应性基团，R 1和R 2各自为氢或烷基，可用于染色或印花纤维材料染色或具有优异的牢固性能的蓝色的印刷产品具有优异的堆积性能。

2. 发明授权

US5272267A Asymmetric dioxazine compounds having a triazinyl bridging group and a method of production and use thereof 失效
标题翻译：具有三嗪基桥接基团的不对称二嗪类化合物及其制备方法
公开(公告)号：US5272267A
公开(公告)日：1993-12-21
申请号：US914637
申请日：1992-07-17
申请人： Tetsuya Miyamoto , Naoki Harada
发明人： Tetsuya Miyamoto , Naoki Harada
IPC分类号： C09B62/44 , C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/5033 , C09B62/4405
摘要： An asymmetric dioxazine compound of the following formula in the free acid form, ##STR1## wherein R is hydrogen, halogen, sulfo or alkoxy, R.sub.1, R.sub.2 and R.sub.3 are each hydrogen or alkyl, X.sub.1 and X.sub.2 are each hydrogen, halogen, alkyl, alkoxy or phenoxy, Y is alkylene, phenylene or naphthylene, Z is --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, V is hydrogen, alkyl, acyl or substituted triazinyl, and Q is halogen, alkoxy, amino or a group similar to that of ##STR2## provided that R is hydrogen, and Q is amino or a group similar to that of ##STR3## when V is substituted triazinyl, which is useful for dyeing or printing fiber materials to give dyed or printed products of a brilliant blue color superior in fastness properties, particularly those such as chlorine fastness with superior build-up property.
摘要翻译：游离酸形式的下式的不对称二恶嗪化合物，其中R是氢，卤素，磺基或烷氧基，R 1，R 2和R 3各自为氢或烷基，X 1和X 2各自为氢，卤素，烷基，烷氧基或苯氧基，Y是亚烷基，亚苯基或亚萘基，Z是-SO2CH = CH2，-SO2CH2CH2OSO3H等，V是氢，烷基，酰基或取代的三嗪基，Q是卤素，烷氧基，氨基或当V为取代三嗪基时，R为氢，Q为氨基或类似于“IMAGE”的基团，其可用于染色或印刷纤维材料以得到染色或印刷产品具有优异的耐牢度性能的亮蓝色，特别是具有优异聚集性能的耐氯牢度。

3. 发明授权

US4880434A Method of obtaining dyed and finished cellulose fiber materials using reactive metallized formazan dye with no color change 失效
标题翻译：使用无颜色变化的反应性金属化甲an染料获得染色和成品纤维素纤维材料的方法
公开(公告)号：US4880434A
公开(公告)日：1989-11-14
申请号：US217631
申请日：1988-07-12
申请人： Naoki Harada , Tetsuya Miyamoto , Kunihiko Imada , Takashi Omura
发明人： Naoki Harada , Tetsuya Miyamoto , Kunihiko Imada , Takashi Omura
IPC分类号： C09B62/503 , D06P3/66 , D06P5/08
CPC分类号： D06P3/66 , C09B62/5036 , D06P5/08 , Y10S8/918
摘要： Dyed and finished products of cellulose fiber materials superior in fastness properties are obtained without change in color shade by finishing dyed products with a fixing agent or/and a finishing agent capable of bonding with cellulose through a bridge formation, the dyed products being obtained by dyeing cellulose fiber materials with a dye represented by the following formula in the free acid form, ##STR1## wherein A is phenylene or naphthylene, B is alkyl, alkenyl, phenyl, naphthyl or heterocyclic group, Me is metal ion, X is --O-- or ##STR2## Y is alkoxy, phenoxy or amino, Z is sulfo or the like water-solubility-imparting group, m and n are each 0 or an integer of 1 to 3, provided that the sum is 1 to 3, D is phenylene or naphthylene, Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 L in which L is splittable group by the action of an alkali and R is hydrogen or alkyl.
摘要翻译：通过用能够通过桥接形成与纤维素结合的固色剂或/和整理剂对染色产物进行染色，可以获得色牢度优异的纤维素纤维材料的染色和成品而不变色，染色产品通过染色具有游离酸形式的下式表示的染料的纤维素纤维材料，其中A是亚苯基或亚萘基，B是烷基，烯基，苯基，萘基或杂环基，Me是金属离子，X是 -O-或Y是烷氧基，苯氧基或氨基，Z是磺基等水溶性赋予基团，m和n各自为0或1〜3的整数，条件是总和为1〜3 ，D是亚苯基或亚萘基，Q是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 L，其中L是可分裂的基团，R是氢或烷基。

4. 发明授权

US4873321A Monazo compounds having a triozinyl bridging group and two vinylsulfone type fiber reactive groups 失效
标题翻译：具有三氯乙烯基桥连基团和两个乙烯基砜类纤维反应性基团的单偶氮化合物
公开(公告)号：US4873321A
公开(公告)日：1989-10-10
申请号：US102497
申请日：1987-09-29
申请人： Takashi Omura , Sadanobu Kikkawa , Toshihiko Morimitsu , Naoki Harada , Tetsuya Miyamoto
发明人： Takashi Omura , Sadanobu Kikkawa , Toshihiko Morimitsu , Naoki Harada , Tetsuya Miyamoto
IPC分类号： C09B62/51
CPC分类号： C09B62/51
摘要： A monoazo compound of the following formula, ##STR1## wherein A is phenyl or naphthyl, B.sub.1 and B.sub.2 are each phenylene or naphthylene, R.sub.1 is hydrogen, halogeno, alkyl, alkoxy, ureido or acylamino, R.sub.2 is hydrogen or takes together with R.sub.1 to form benzene, R.sub.3 is hydrogen, alkyl, alkoxy or sulfo, R.sub.4 and R.sub.5 are each hydrogen or alkyl, and Y.sub.1 and Y.sub.2 are each vinyl, sulfatoethyl or the like, which is useful for dyeing hydroxyl group-containing and amide-containing fiber materials to obtain dyed products of excellent fastness properties with excellent build-up property and reproducibility of dyeing irrespective of changes in dyeing temperatures, bath ratio or salt concentration in some degree.

5. 发明授权

US5438137A Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes 失效
标题翻译：纤维反应性不对称二嗪化合物及其作为纤维活性染料的用途
公开(公告)号：US5438137A
公开(公告)日：1995-08-01
申请号：US128725
申请日：1993-09-30
申请人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Shinei Ikeou , Takashi Omura , Naoki Harada
发明人： Tetsuya Miyamoto , Miyao Takahashi , Takahiko Fujisaki , Shinei Ikeou , Takashi Omura , Naoki Harada
IPC分类号： C09B62/44 , C09B62/503 , C07D498/04
CPC分类号： C09B62/5033 , C09B62/4405
摘要： An asymmetric dioxazine compound of the following formula in the free acid form, ##STR1## wherein R is hydrogen, halogen, sulfo or alkoxy, R.sub.1, R.sub.2 and R.sub.3 are each hydrogen or alkyl, X.sub.1 and X.sub.2 are each hydrogen, halogen, alkyl, alkoxy or phenoxy, Y is alkylene, phenylene or naphthylene, Z is --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, V is hydrogen, alkyl, acyl or substituted triazinyl, and Q is halogen, alkoxy, amino or a group similar to that of ##STR2## provided that R is hydrogen, and Q is amino or a group similar to that of ##STR3## when V is substituted triazinyl, which is useful for dyeing or printing fiber materials to give dyed or printed products of a brilliant blue color superior in fastness properties, particularly those such as chlorine fastness with superior build-up property.
摘要翻译：游离酸形式的下式的不对称二恶嗪化合物，其中R是氢，卤素，磺基或烷氧基，R 1，R 2和R 3各自为氢或烷基，X 1和X 2各自为氢，卤素，烷基，烷氧基或苯氧基，Y是亚烷基，亚苯基或亚萘基，Z是-SO2CH = CH2，-SO2CH2CH2OSO3H等，V是氢，烷基，酰基或取代的三嗪基，Q是卤素，烷氧基，氨基或类似的基团条件是R为氢，Q为氨基或V为与IMA相似的基团，当V为取代的三嗪基时，可用于染色或印刷纤维材料以得到亮蓝色的染色或印刷产品耐牢度特性优异，特别是具有优异聚集性能的耐氯牢度。

6. 发明授权

US5356441A Reactive dye composition and method for dyeing or printing fiber materials using the same 失效
标题翻译：活性染料组合物和使用其的染色或印花纤维材料的方法
公开(公告)号：US5356441A
公开(公告)日：1994-10-18
申请号：US118227
申请日：1993-09-09
申请人： Takemi Tokieda , Naoki Harada , Shuhei Hashizume , Koiti Ishii , Nobuaki Kawamura , Tetsuya Miyamoto , Hiroyuki Suzuki , Shigeru Kawabata
发明人： Takemi Tokieda , Naoki Harada , Shuhei Hashizume , Koiti Ishii , Nobuaki Kawamura , Tetsuya Miyamoto , Hiroyuki Suzuki , Shigeru Kawabata
IPC分类号： C09B67/24 , C09B62/016 , D06P1/38
CPC分类号： C09B67/0072
摘要： A reactive dye composition containing a reactive dye and a salt of polyoxyethylene substituted-phenyl ether ester produces excellent solubility in water and in an aqueous alkali solution and can be used to dye a fiber material uniformly.
摘要翻译：含有活性染料和聚氧乙烯取代的苯基醚酯的盐的活性染料组合物在水和碱水溶液中产生优异的溶解性，并可用于均匀地染色纤维材料。

7. 发明授权

US5116956A Polyazo dye compounds having vinylsulfone type and pyridinium type fiber reactive groups 失效
标题翻译：具有乙烯基砜型和吡啶类型纤维反应性基团的聚氨酯染料化合物
公开(公告)号：US5116956A
公开(公告)日：1992-05-26
申请号：US524743
申请日：1990-05-17
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/44
CPC分类号： C09B62/4415
摘要： A polyazo compound of the following formula, ##STR1## wherein X is ##STR2## --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5, in which R.sub.1 is hydrogen or alkyl, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, A is phenylene, naphthylene or alkylene, Z is a fiber-reactive group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, Y is pyridinio, and F is polyazo dye moiety carrying a fiber-reactive group like that represented by Z, which compound is useful for dyeing or printing fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

8. 发明授权

US5112959A Polyazo dye compounds having plural vinylsulfone type fiber reactive groups in one molecule 失效
标题翻译：在一个分子中具有多种乙烯基纤维素类型的纤维反应组的聚氨基染料化合物
公开(公告)号：US5112959A
公开(公告)日：1992-05-12
申请号：US526708
申请日：1990-05-22
申请人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
发明人： Tetsuya Miyamoto , Kazufumi Yokogawa , Yutaka Kayane , Takashi Omura , Takeshi Washimi , Naoki Harada , Kingo Akahori
IPC分类号： C09B62/513
CPC分类号： C09B62/513
摘要： A polyazo compound of the following formula, ##STR1## wherein A is phenylene, naphthylene or alkylene, X is --NR.sub.2 R.sub.3, --OR.sub.4 or --SR.sub.5 in which R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, alkyl, phenyl, naphthylene or benzyl, Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z' in which Z' is a splittable group, R.sub.1 is hydrogen or alkyl, and F is polyazo dye moiety carrying a fiber reactive group like that represented by Z. This compound is useful for the dyeing or printing of fiber materials to obtain a product dyed or printed in a color superior in various fastness properties with superior build-up property.

9. 发明授权

US4684721A Fiber-reactive phthalocyanine compound having both vinylsulfone type and dihalogenotriazinyl groups 失效
标题翻译：具有乙烯基砜型和二卤代三嗪基的纤维反应性酞菁化合物
公开(公告)号：US4684721A
公开(公告)日：1987-08-04
申请号：US835788
申请日：1986-03-03
申请人： Tetsuya Miyamoto , Takashi Omura , Naoki Harada , Akira Takeshita
发明人： Tetsuya Miyamoto , Takashi Omura , Naoki Harada , Akira Takeshita
IPC分类号： C09B62/517 , C09B62/44 , D06P1/38 , C09B47/04
CPC分类号： C09B62/4418
摘要： A phthalocyanine compound represented by the following formula, ##STR1## wherein Pc is a metal-containing or metal-free phthalocyanine residue, R.sup.1 is a hydrogen atom or substituted or unsubstituted lower alkyl group, A is a substituted or unsubstituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a splittable group by the action of an alkali, W is a bridging group of the following formula, ##STR2## in which R.sup.2 and R.sup.3 are independently a hydrogen atom or a methyl or ethyl group, and n is an integer of from 2 through 6, X is a halogen atom, a is 0 or a number of not more than 2 (0.ltoreq.a.ltoreq.2), and b and c are independently a number of 1 through 3 (1.ltoreq.b.ltoreq.3, 1.ltoreq.c.ltoreq.3), provided that the total of a, b and c is not more than 4 (a+b+c.ltoreq.4), which is useful for dyeing or printing materials, particularly cellulose fiber materials, in a brilliant turquoise blue color excellent in various fastness properties.
摘要翻译：由下式表示的酞菁化合物其中Pc是含金属或不含金属的酞菁残基，R1是氢原子或取代或未取代的低级烷基，A是取代或未取代的亚苯基或亚萘基， Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是通过碱的作用可裂解的基团，W是下式的桥接基团，其中R 2和R 3独立地是氢原子或甲基或乙基，n为2〜6的整数，X为卤素原子，a为0或2以下的数（0

10. 发明授权

US4977261A Anthraquinone compound 失效
标题翻译：蒽醌化合物
公开(公告)号：US4977261A
公开(公告)日：1990-12-11
申请号：US141762
申请日：1988-01-11
申请人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
发明人： Yutaka Kayane , Takashi Omura , Naoki Harada , Yasuji Mori , Yosuke Yamamoto , Tetsuya Miyamoto , Takehiro Kusumoto
IPC分类号： C09B62/505
CPC分类号： C09B62/505
摘要： A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.

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